• Title/Summary/Keyword: NOx Formation

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An Experimental Study on the Combustion Characteristics of a Low NOx Burner Using Reburning Technology

  • Ahn, Koon-Young;Kim, Han-Seok;Son, Min-Gyu;Kim, Ho-Keun;Kim, Yong-Mo
    • Journal of Mechanical Science and Technology
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    • v.16 no.7
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    • pp.950-958
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    • 2002
  • The combustion characteristics of a low NOx burner using reburning technology have been experimentally studied. The return burner usually has three distinct reaction zones which include the primary combustion zone, the reburn zone and the burnout zone by provided secondary air. NOx is mainly produced in a primary combustion zone and a certain portion of NOx can be converted to nitrogen in the rebury zone. In the burnout zone, the unburned mixtures are completely oxidated by supplying secondary air. Liquefied Petroleum Gas (LPG) was used as main and reburn fuels. The experimental parameters investigated involve the main/reburn fuel ratio, the primary/secondary air ratio, and the injection location of rebury fuel and secondary air. When the amount of return fuel reaches to the 20-30% of the total fuel used, the overall NO reduction of 50% is achieved. The secondary air is injected by two different ways including vertical and parallel injection. The injector of secondary air is located at the downstream region of furnace for a vertical-injection mode, which is also placed at the inlet primary-air injection region for a parallel-injection mode. In case of the vertical injection of the secondary air flow, the NOx formation of stoichiometric condition at a primary combustion zone is nearly independent of the rebury conditions (locations, fuel/air ratios) while the NOx emission of the fuel-lean condition is considerably influenced by the reburn conditions. In case of the parallel injection of the secondary air, the NOx emission is sensitive to the air ratio rather than the fuel ratio and the reburning process often coupled with the multiple air-staging and fuel-staging combustion processes.

Experimental Study on the Flame Behavior and the NOx Emission Characteristics of Low Calorific Value Gas Fuel (저 발열량 가스 연료의 화염거동 및 NOx 발생 특성에 관한 실험적 연구)

  • Kim, Yong-Chul;Lee, Chan
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.89-93
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

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Numerical Investigation of Low-pollution Combustion with applying Flue Gas Recirculation in Counterflow Flames: Part II. Analysis of NOx formation mechanism (대향류 화염에서 FGR이 적용된 저공해 연소의 수치적 해석: Part II. NOx 생성기구 분석)

  • Cho, Seo-Hee;Kim, Gyeong-Mo;Lee, Kee-Man
    • Journal of the Korean Institute of Gas
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    • v.24 no.4
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    • pp.39-47
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    • 2020
  • Flue gas recirculation(FGR) is an effective combustion technique for reducing nitrogen oxides(NOx) and is applied in various fields of low-pollution combustion. Continuing the previous study, a numerical analysis was conducted to identify changes of flame characteristics and NOx formation mechanism with applying FGR technique in CH4/air premixed counterflow flames. NOx emitted was divided into four main reaction paths(thermal NO, prompt NO, N2H and N2O), showing relatively the production rate of NO with the recirculation ratio. As a result, thermal NO contributed greatly to the overall NO whereas the effect of N2H was minimal. In addition, emission index of NO was compared as the recirculation ratio increased by modifying the UC San Diego mechanism to examine the contribution of thermal NO.

Numerical analysis of NOx formation characteristics in CH$_{4}$-air jet diffusion flame (CH$_{4}$-공기 분류 확산화염의 NOx 생성특성에 관한 수치해석)

  • O, Chang-Bo;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.2
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    • pp.193-204
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    • 1998
  • Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymmetric 2-D CH$_{4}$ jet diffusion flame. Calculations were carried out twice with the $C_{2}$-Thermal Mechanism including $C_{2}$ and thermal NO reactions and the $C_{2}$-Full Mechanism including prompt NO reactions in addition to the above $C_{2}$-Thermal NO mechanism. The results show that the flame structures such as flame temperature, major and minor species concentration are indifferent to respective mechanisms. The production path of Thermal NO is dominant comparing with that of Prompt NO in total NO production of pure CH$_{4}$ jet diffusion flame. This is because thermal NO mechanism mainly contributes to positive formation of NO in the whole flame region, but Prompt NO mechanism contributes to negative formation in the fuel rich region. In addition, 0$_{2}$ penetration near the nozzle outlet affects the flame structures, especially N0$_{2}$ formation characteristics.

An Experimental Study on the NOx Formation of Fuel Staged Combustor (연료다단 연소기의 NOx 발생특성에 관한 실험적 연구)

  • 정진도;안국영;한지웅
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.6
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    • pp.73-79
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    • 2003
  • The characteristics of NOx emission in multi fuel/air staged combustor have been experimentally studied. The design concept of multi fuel/air staged combustor is creation of two separate flame, a primary flame is act as a pilot flame for the secondary combustion stage combustion zone, where most of fuel burns. Experiments were performed on a semi-industrial scale (thermal input 0.233 ㎿) in a laboratory furnace and Liquefied Petroleum Gas(LPG) was used as primary and secondary fuels. The study included parametric study to identify the optimum operating conditions which are primary/secondary fuel ratio, primary/secondary air ratio, primary swirl intensity and secondary swirl intensity for reducing NOx emission. The test demonstrated that NOx emission can be reduced by >70% in accordance with operating conditions.

A Study on Effect of EGR upon Fuel Consumption Rate and NOx Emission in Diesel Engines (디젤기관의 연료소비율 및 질소산화물 배출물에 미치는 EGR의 영향에 관한 연구)

  • Bae, M.W.;Lim, J.K.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.1
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    • pp.76-88
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    • 1995
  • The effects of exhaust gas recirculation(EGR) on the characteristics of NOx emissions and specific fuel consumption rate have been investigated using an eight-cylinder. four cycle. direct injection diesel engine operating at several loads and speeds. The theoretical NO formation concentration is calculated with the equivalence ratio as a parameter of flame temperature to study the effect of EGR on NOx emissions in the diesel combustion. The experiments in this study are conducted on the fixed fuel injection timing of $38^{\circ}$ BTDC regardless of experimental conditions. It is found that the specific fuel consumption rate is slightly increased with EGR rate. and NOx emissions are markedly reduced owing to the drop of the incoming oxygen concentratio and the increase of equivalence ratio as the EGR rate increases.

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Reduction of NOx Emissions in Turbulent Hydrogen Diffusion Flame using Acoustic Excitation (음파가진에 의한 동축공기 수소 확산화염의 NOx 배출저감연구)

  • Kim, Mun-Ki;Han, Jeong-Jae;Yoon, Sang-Wook;Yoon, Young-Bin
    • Journal of the Korean Society of Combustion
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    • v.10 no.1
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    • pp.13-19
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    • 2005
  • Measurements of flame length and NOx emissions have been conducted to investigate the effects of acoustic excitation on flame structure in turbulent hydrogen diffusion flames with coaxial air. When the acoustic excitation of a specific frequency is applied to coaxial air stream, flame length is dramatically reduced, resulting in reduction of flame residence time. Consequently, EINOx could decrease up to 35 % and this shows that acoustic excitation is effective in reducing NOx emissions. Mie scattering technique has been used to visualize the vortex structure induced by acoustic excitation and vortex formation, development and destruction were observed quantitatively. As a result, vortex entrains coflow air into fuel stream and mixing rate between fuel and air is significantly enhanced, which may contribute to reduction of NOx emissions.

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The experimental study on the NOx formation of fuel staged combustor (연료다단 연소기의 NOx 발생특성에 관한 실험적 연구)

  • Han, Ji-Woong;Ahn, Kook-Young;Kim, Han-Seok;Chung, Jin-Do
    • 한국연소학회:학술대회논문집
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    • 2001.06a
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    • pp.163-171
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    • 2001
  • The characteristics of NOx emission in multi fuel/air staged combustor have been experimentally studied. The design concept of multi fuel/air staged combustor is creation of two separate flame, a primary flame is act as a pilot Dame for the secondary combustion stage combustion zone, where most of fuel bums. Experiments were performed on a semi-industrial scale (thermal input 0.233 MW) in a laboratory furnace and Liquefied Petroleum Gas(LPG) was used as primary and secondary fuels. The study included parametric study to identify the optimum operating conditions which are primary/secondary fuel ratio, primary/secondary air ratio, primary swirl intensity and secondary swirl intensity for reducing NOx emission. The test demonstrated that NOx emission can be reduced by ${>}$70% in accordance with operating conditions.

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The Effect of Pulverized Coal Burner Design Parameters on NOx Emission (미분탄 버너의 설계인자가 NOx 생성에 미치는 영향)

  • Kim, Sang-Hyeun;Song, Si-Hong;Lee, Gun-Myung;Kim, Hyuk-Je;Lee, Ik-Hyung
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.102-105
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    • 2001
  • Numerical simulations of coal combustion were carried out to identify what kind of burner design parameters are affecting the NOx emission. Where used burner design parameters are primary air velocity, secondary air velocity, $2^{nd}/3^{rd}$ air ratio, tertiary air velocity, and tertiary air injection location. Taguchi method was used to find the effective burner design parameters related to NOx formation. The results of numerical simulations showed that secondary air velocity and $2^{nd}/3^{rd}$ air ratio was the key parameters reducing the NOx emission. The total number of simulation cases was reduced by Taguchi method.

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Reduction of NOx emission from fuel nitrogen in new staged fuelling system(1)(Characteristics of NOx formation & reduction)

  • Chun, Young-Nam;Shin, Dae-Yewn
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.E
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    • pp.303-310
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    • 1994
  • The effects of NOx reduction by new staged fuelling system in a small scale combustor (6.6 ㎾$_{T}$) have been investigated using propane gas flames laden with ammonia as fuel-nitrogen. The variables which had the greatest influence on NOx reduction were temperature, reducing stoichiometry( related to main combustion zone stoichiometry, air fraction and returning fuel fraction ) and residence time. The best NOx reduction was observed at the reburning zone stoichiometry of 0.85. In terms of residence time of the reburning zone, NOx reduction was effective when burnout air was injected at the Point where the reburning zone has been already established.d.

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