• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제52권9호
• /
• pp.407-411
• /
• 2003

The purpose of this paper is to study the removal of nitrogen oxide(NOx) using a wire-plate type plasma reactor with magnet attached for indoor air purification. In order to produce a more effective reactor, we conducted magnetic field simulations. The results of the magnetic field simulations show that NOx can be removed more effectively. The results from the magnetic field simulation show that when 7 magnets were applied to the reactor, the magnetic flux density was at its highest amount than when using 0, 3, or 5 magnets. From the data obtained by the simulation results a plasma reactor was made and thus, several experiments were conducted. The best removal efficiency was obtained with 14 W AC power to the reactor with 5 magnets.

• 한국구조물진단유지관리공학회 논문집
• /
• 제26권6호
• /
• pp.120-127
• /
• 2022

질소산화물(NOx)은 대기오염의 주요 인자로 일산화질소와 이산화질소의 형태로 존재하며 인체에 유해하다. 최근 대기 중 NOx를 제거하기 위한 많은 연구가 진행되고 있으며, 이러한 노력은 건설재료 분야에서도 동일하다. NOx는 광촉매 반응을 이용하여 효율적으로 제거할 수 있는 것으로 알려져 있다. 본 연구에서는 활성탄(AC)과 이산화타이타늄(TiO₂)을 이용한 폼 복합재의 NOx 제거성능을 조사하였다. AC는 폼 복합체의 비표면적을 증가시켜 TiO₂의 광촉매 반응 효율을 향상시켰다. 본 연구에서는 AC의 혼합율을 주요 변수로 하여 폼 복합체를 제조하였다. 제조된 시험체를 이용하여 ISO-22197-1에 제시된 시험방법에 따라 NOx 제거성능을 평가하였다. 폼 복합체의 비표면적은 AC 함량에 따라 증가하는 경향을 나타내었으나 15% 이상에서는 감소하였다. 또한 AC 혼입률이 15%일 때 NOx 제거 효율이 가장 높았다.

• 공업화학
• /
• 제21권3호
• /
• pp.243-251
• /
• 2010

연소배가스에 존재하는 질소산화물의 제거를 위해서는 촉매 환원, 흡수, 흡착 등 화학적 기술이 적용되고 있는데, 장기적으로는 환경친화적이고 에너지 소모가 적은 생물학적 공정의 개발 및 이용이 필요하다. 본 논문에서는 연소 배가스에 존재하는 질소산화물을 제거하기 위한 생물학적 공정의 기술동향을 살펴보고 각각의 장단점을 고찰하였다. 질산화와 탈질 기작을 이용하는 박테리아 시스템과 광합성 미세조류를 이용하는 시스템으로 구분하여 기술의 원리와 현재의 기술 수준을 논하였다. 두 경우 모두 처리속도를 높이기 위해서는 불용성의 일산화질소를 일단 적절한 흡수제에 고농도로 포집시킨 후 미생물에 의하여 분해 또는 고정하는 방향이 바람직하며, 배가스 중 $CO_2$와 NOx를 동시에 고정이 가능하고 별도의 탄소원이 요구되지 않는 미세조류의 활용이 기대된다.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
• /
• pp.295-300
• /
• 2003

In Korea, the emission standards for air pollutants will be more tighten from Jan. 2005. Especially, the new emission standards is focused on the nitrogen oxide. From this trend of standards, nitrogen oxide emission is hot issue in energy fields. Also, we have a new environmental problem, the carbon dioxide emission, which are related to the global warming. To solve the environmental problems, we must define the situation of clean-up technologies level in Korea and decide the direction of R&D for flue gas cleaning technologies. Now, this paper discus briefly on the De-NOx R&D activities and the large scale testing facility for flue gas clean-up technologies in Korea Institute of Energy Research. These discussions are contribute to the increasing of the R&D activities for flue gas clean-up technologies in Korea.

• 한국분무공학회지
• /
• 제24권4호
• /
• pp.178-184
• /
• 2019

Diesel engines have the advantages of higher thermal efficiency and lower CO2 emissions than gasoline engines, but have the disadvantages that particulate matter (PM) and nitrogen oxides (NOx) emissions are greater than those of gasoline engines. In particular, nitrogen oxides (NOx) emitted from diesel engines generates secondary ultrafine dust (PM2.5) through photochemical reactions in the atmosphere, which is fatal to humans. In order to reduce nitrogen oxides (NOx), pre-treatment systems such as EGR, post-treatment systems such as LNT and Urea SCR have been actively studied. The Urea SCR consists of an injection device injecting urea agent and a catalytic device for reducing nitrogen oxides (NOx). The nitrogen oxide (NOx) reduction performance varies greatly depending on the urea uniformity in the exhaust pipe. In this study, spray characteristics according to the spray hole structure were confirmed, and the influence of spray uniformity on spray characteristics was studied through engine evaluation.

• 한국전기전자재료학회논문지
• /
• 제15권7호
• /
• pp.640-648
• /
• 2002

This study is to develop electromagnetic-catalyst application plasma reactors for indoor air purification. Nitrogen Oxide(NOx) removal characteristics are measured in the electromagnetic catalyst application plasma reactors with various parameters and the effect of catalyst or/and magnetic field are investigated on the NOx removal. And AC or DC high voltage is applied for corona discharge, flow rates are 150~1500 $\ell/min$ and NO initial concentration is about 10 ppm. $Mn0_2$ and $TiO_2$ catalysts to increase NOx removal rate are used. In the results, NOx removal rate by AC power is about 10 % higher than that by DC power under the experimental condition of 700 $\ell/min$, 5 magnets, $MnO_2$ and $Ti)_2$ catalysts. When magnet is applied to the reactor, NOx removal rate increased. Also, the reactor with $MnO_2$ and $Ti)_2$ catalyst and magnet have the best removal rate.

• 한국연소학회지
• /
• 제9권1호
• /
• pp.11-17
• /
• 2004

The purposes of this study are to analyze nitrogen oxides(NOx) formation mechanism and to reduce abnormal NOx emissions in gas turbines. Industrial gas turbines emissions have potential to negative affect to the atmosphere in many different ways such as photochemical smog, acid rain and global warming. In conventional gas turbine combustors, one of the main pollutants such as nitrogen oxide(NOx) species, are principally formed from combustion process of fuel with oxygen in the primary combustion zone, and their emission levels are highly depend on peak temperatures in the combustor. In order to examine the characteristics and the effect of NOx formation, we used gas turbine of which commercial operating in Korea. From the examination, it has been found that NOx emissions are relatively high at low load(output) and during combustion mode change. Also, the effect of Air/Fuel ratio was considered. As the Air/Fuel ratio was increased in Lean-Lean mode, the NOx emission was decreased. The results of this study indicated that NOx emission levels are highly depend on peak temperature and pressure of combustion process in the combustor.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
• /
• pp.128-133
• /
• 2006

Influence of changing combustor pressure on flame stabilization and nitrogen oxide (NOx) emission in the swirl-stabilized flame with secondary fuel injection was investigated. The combustor pressure was controlled by suction at combustor exit. Pressure index ($P{\ast}=P_{abs}/P_{atm}$), where $P_{abs}$ and $P_{atm}$ indicated the absolute pressure and atmosphere pressure, was controlled in the range of $0.7{\sim}1.3$ for each equivalence ratio conditions. The flammable limits of swirl flames were largely influenced by changing combustor pressure and they showed different tendency compared with laminar flames. Emission index showed maximum value near atmospheric condition and decreased with decreasing pressure index for overall equivalence ratio conditions. R.m.s of pressure fluctuations also showed similar tendency with nitric oxide emission. By injecting secondary fuel into flame zone, the flammable limits were extended significantly. Emission index of nitric oxide and r.m.s. of pressure fluctuations were also controlled by injecting secondary fuel. The swirl flames were somewhat lifted by secondary fuel with high momentum, hence low nitric oxide emission. This NOx reduction technology is applicable to industrial furnaces and air conditioning system by adopting secondary fuel injection.

• 해양환경안전학회지
• /
• 제28권7호
• /
• pp.1209-1215
• /
• 2022

선택적 촉매 환원법(SCR)은 질소산화물(NO_x)을 저감하는 매우 효율적인 방법으로 알려져 있으며 발생된 질소산화물(NO_x)을 질소(N₂)와 수증기(H₂O)로 환원시키는데 촉매 작용을 한다. 질소산화물(NO_x) 저감 성능을 결정하는 요소 중 하나인 촉매는 셀 밀도가 증가하면 촉매효율이 증가하는 것으로 알려져 있다. 본 연구에서는 실습선 세계로호에 설치되어 있는 발전 기관의 배기가스 조건을 모사한 실험장치를 통하여 100CPSI(60Cell)촉매의 부하에 따른 질소산화물(NO_x) 저감 성능을 확인하고 세계로호에 설치되어 있는 25.8CPSI(30Cell) 촉매의 기존 연구 자료와의 비교를 통해, 셀 밀도가 질소산화물(NO_x)의 저감에 미치는 영향에 대하여 고찰하였다. 실험용 촉매는 셀 밀도만 변화를 주었고 형태는 벌집형(honeycomb), 조성물질은 V₂O₅-WO₃-TiO₂를 동일하게 사용하여 제작하였다. 실험결과 100CPSI(60Cell) 촉매의 질소산화물(NO_x) 농도 저감율은 평균적으로 88.5%이며 IMO specific NOx 배출량은 0.99g/kwh로 IMO Tier III NOx 배출기준을 만족하였다. 25.8CPSI(30Cell) 촉매의 경우, 질소산화물(NO_x) 농도 저감율은 78%, IMO specific NOx 배출량은 2.00g/kwh 이었다 두 촉매의 NOx 농도 저감율과 IMO specific NOx 배출량을 비교하였을 때, 100CPSI(60Cell)촉매가 25.8CPSI(30Cell) 촉매보다, NOx 농도 저감율은 10.5% 높고 IMO specific NOx 배출량은 약 2배 적은 것을 확인하였다. 따라서 촉매의 셀 밀도를 높임으로써 효율적인 탈질효과를 기대할 수 있으며 향후 실선 테스트를 통하여 검증한다면 촉매의 부피 저감을 통한 제작 비용을 줄이고 협소한 선박 기관실을 효율적으로 사용하기 위한 실용적인 자료로서 기대된다.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2002년도 학술대회 논문집 전문대학교육위원
• /
• pp.64-66
• /
• 2002

This study is to develop electromagnetic plasma reactors for indoor air purification, Removal effect of nitrogen oxide using magnetic field are investigated. And AC or DC high voltage is applied for corona discharge, flow rates are 150${\sim}$1500${\ell}$/min and NO initial concentration is about 10 ppm. In the results, NOx removal rate by AC power is about 10 % higher than that by DC power under the experimental condition of 700 ${\ell}$/min, 5 magnets. When magnet is applied to the reactor, NOx removal rate increased.