• Title/Summary/Keyword: NO 분자

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Comparison of FDDO and DSMC Methods in the Analysis of Expanding Rarefied Flows (팽창희박류의 분석에 있어서 FDDO와 직접모사법의 비교)

  • Chung C. H.
    • Journal of computational fluids engineering
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    • v.1 no.1
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    • pp.142-149
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    • 1996
  • 이차원 노즐을 통하여 저밀도 환경으로 팽창하는 희박류의 분석에 있어서 불연속좌표법과 결합된 유한차분법(finite-difference method coupled with the discrete-ordinate method, FDDO)과 직접모사법(direct-simulation Monte-Carlo method, DSMC)이 비교되었다. FDDO를 이용한 분석에서는 충돌적분모델을 도입하여 간단해진 볼츠만식(Boltzmann equation)이 불연속좌표법을 이용하여 물리적 공간에서는 연속이나 분자속도 공간에서는 불연속좌표로 표시되는 편미분방정식군으로 변환되어 유한차분법에의하여 수치해석 되었다. 직접모사법에서는 분자모델로 가변강구모델(variable hard sphere model, VHS)이, 충돌샘플링모델로는 비시계수법(no time counter method, NTC)이 채택되었다. 전혀 다른 두 가지 방법에 의한 노즐 내부에서의 유체흐름 해석결과는 매우 잘 일치하였으며, 노즐 외부의 plume 영역에서는 FDDO에 의한 해석결과가 직접모사법에 의한 해석결과에 비하여 약간 느린 팽창을 보였다.

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Molecular size distribution of NOM after ozonation and its effect on adsorption with activated carbon (NOM의 오존처리에 따른 분자크기분포변화가 활성탄 흡착에 미치는 영향)

  • Lee, Hyung-Jik;Hong, Seong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.6
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    • pp.805-813
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    • 2013
  • In this study, molecular size distribution of natural organic matter (NOM) after ozonation was measured and its effect on adsorption capacity of activated carbon was investigated. According to the results, the molecular size of NOM was limitedly changed. Specifically, the molecular size of NOM between 5,000 to 10,000 Da were slightly decreased with increasing ozone doses. The adsorption capacity after ozonation was evaluated using Freundlich isotherm with ideal adsorbed solution theory (IAST) which simulated the multi components adsorption. Further, mini-column test was conducted. The Freundlich constant, K was reduced after ozonation and the non-adsorbable fraction was increased with ozonation. However, no correlation between K and ozone doses was found. The present study also agreed with the correlation between adsorption capacity and pore size characteristics of activated carbon.

Rheological Properties of High Molecular Weight (HMW) Syndiotactic poly(vinyl alcohol) (PVA)/HMW Atactic PVA Blend Solutions (고분자량 교대배열 폴리비닐알코올/고분자량 혼성배열 폴리비닐알코올 블렌드 용액의 유변학적 특성)

  • Yeum, Jeong-Hyun;Ji, Byung-Chul;Lyoo, Won-Seok
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.74-75
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    • 2003
  • Recently, people are gradually concerned about environmental issue, bionics, environmental-friendly or biocompatible materials. Poly(vinyl alcohol) (PVA) is suitable for these materials, because it is typically water-soluble polymer that have linear-flexible chains, a material of no toxicity for human, and biodegradable polymer[1]. One of the most effective factors that dominate the properties of PVAs is tacticity. (omitted)

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Study on the Characteristics of the AlAS/GaAs Epitaxial Layers Grown by Molecular Beam Epitaxy (분자선에피택시성장법으로 성장한 AlAS/GaAs 에피택셜층의 특성)

  • No, Dong-Wan;Kim, Gyeong-Ok;Lee, Hae-Gwon
    • Korean Journal of Materials Research
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    • v.7 no.12
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    • pp.1041-1046
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    • 1997
  • 본 연구에서는 분자선 에피택시 방법으로 비대칭 AIAs/GaAs(001)이중 장벽, 삼중장벽구조를 성장한 수 이를 이용하여 2단자 소자를 제작하여 전기적 특성을 분석하였다. 에피층은 쌍결정 X-ray회절 분석과 단면투과 전자현미경을 이용하여 결정성 및 격자 정합성을 확인하였다. 전기적 성능을 보다 향상시키기 위해 n-GaAs에 대한 오믹 접촉등의 소자 제작 공정을 최적화하였다. 삼중장벽 구조를 이용하여 제작한 소자의 전기적 특성 연구 결과 두개의 주요 공진 터널링 전류 피크 사이에 X-valley에 의한 구조를 확인할 수 있었으며, 이중 장벽구조에 제2의 양자우물 구조를 첨가함으로써 낮은 전압위치에서 전류 피크가 향상하는 결과를 얻었다.

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Proteomic characterization of differentially expressed proteins associated with no stress in retinal ganglion cells

  • Kim, Jum-Ji;Kim, Yeon-Hyang;Lee, Mi-Young
    • BMB Reports
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    • v.42 no.7
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    • pp.456-461
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    • 2009
  • Proteomic analyses of differentially expressed proteins in rat retinal ganglion cells (RGC-5) following S-nitrosoglutathione (GSNO), an NO donor, treatment were conducted. Of the approximately 314 protein spots that were detected, 19 were differentially expressed in response to treatment with GSNO. Of these, 14 proteins were up-regulated and 5 were down- regulated. Notably, an increase in GAPDH expression following GSNO treatment was detected in RGC-5 cells through Western blotting as well as proteomics. The increased GAPDH expression in response to GSNO treatment was accompanied by an increase in Herc6 protein, an E3 ubiquitin ligase. Moreover, GSNO treatment resulted in the translocation of GADPH from the cytosol to the nucleus and its subsequent accumulation. These results suggest that NO stress-induced apoptosis may be associated with the nuclear translocation and accumulation of GAPDH in RGC-5 cells.

An electrochemical functional assay for the sensing of nitric oxide release induced by angiogenic factors

  • Trouillon, Raphael;O'Hare, Danny;Chang, Soo-Ik
    • BMB Reports
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    • v.44 no.11
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    • pp.699-704
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    • 2011
  • Nitric oxide (NO) is a critical biological mediator involved in numerous diseases. However, the short lifetime of this molecule in biological conditions can make its study in situ complicated. Here, we review some recent results on the role of NO in angiogenesis, obtained using a biocompatible microelectrode array. This simple system allowed for the quick and easy quantification of NO released from cells grown directly on the surface of the sensor. We have used this technology to demonstrate that angiogenin induces NO release, and to partially elucidate its intracellular transduction pathway.

Measurement of Atmospheric Nitrous Acid(HONO) using DNPH/HPLC in Seoul (DNPH/HPLC에 의한 서울시 대기 중의 Nitrous Acid 측정)

  • 정용국;홍상범;이재훈
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.325-326
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    • 2001
  • 오존은 태양광선의 존재 하에 질소산화물과 VOCs가 관련하여 발생하는 생성물이다. 대기중의 VOCs 는 히드록실 라디칼(hydroxyl radical, OHㆍ)과 같은 자유 라디칼(free radical)과 반응하여 하이드로퍼옥시 라디칼(hydroperoxy radical, HO$_2$ㆍ)과 알킬 퍼옥시 라디칼(alkyl peroxy radical, RO$_2$ㆍ)을 생성해 낸다. 이 퍼옥시 라디칼들은 NO를 NO$_2$ㆍ로 산화시키며 또한 히드록실 라디칼을 재생하며 이 히드록실 라디칼은 다시 VOCs와 반응한다. 그리고, 이때 산화된 NO$_2$는 햇빛에 의해 NO와 자유산소원자(free oxygen atom)로 광분해 되는데, 여기서 생성된 자유산소인자는 산소분자와 반응하여 오존을 생성한다. (중략)

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NEAR-INFRARED OBSERVATIONS OF A STAR FORMING REGION IN THE GALACTIC CENTER (우리은하 중심의 별탄생영역 근적외선 관측)

  • Pak, Soo-Jong;Lee, Sung-Ho
    • Bulletin of the Korean Space Science Society
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    • 2006.10a
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    • pp.177-180
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    • 2006
  • We observed $2.1218{\mu}m$ $H_2$ 1-0 S(1) emission from H II region A, which is located just next to Sgr A East and one of the nearest star forming regions to the Gatactic center. Cooled Grating Spectrometer 4 (CGS4) at the 3.8 m United Kingdom Infrared Telescope (UKIRT) was used with aa echelle grating at a velocity resolution of ${\sim}$ 18km s^{-1}$ and an angular resolution of ${\sim}$ 2 arcsec. Comparing the distributions and kinematics of the observed $H_2$ emission with radio continuum and $NH_3$ emission, we find no evidence that this H II region is interacting with Sgr A East. This conclusion supports that the star formation in this region has not been stimulated by the blast wave of Sgr A East.

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Molecular weight Control of Polyhydroxybutyrate (PHB) in Recombinant Escherichia coli (재조합 대장균에서의 Polyhydroxybutyrate (PHB)의 분자량 조절)

  • 심상준;안토니신스키
    • KSBB Journal
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    • v.13 no.1
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    • pp.96-100
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    • 1998
  • Two promoters (trc and P$\rho$) were inserted in PHA operon derived from Alcaligenes eutrophus to obtain high chain molecules of polyhydroxybutyrate (PHB) in recombinant Escherichia coli. Newly designed PHA operon was used to control the gene expressions of hydroxybutyric CoA and PHA polymerization, separately. Plasmids containing new synthetic operon was transformed into E. coli DH5$\alpha$ and analyzed for PHB production. Without induction of the PHA biosynthetic operon, PHA synthase which has low activity might supply low concentration of initiator during the polymerization reaction, resulting very high molecular weight of polymer. An increase of PHB average molecular weight was observed with decreased IPTG (isopropyl $\beta$ -Dithiogalactosidase) concentration. When no IPTG was added to the culture of E. coli DH5$\alpha$ /$\rho$ SJS1 which contained two promoters in PHA operon, high chain polymer having an average molecular weight of $2.5{\times}10^7$ was achieved. Analysis of the enzyme activities of PHA biosynthetic enzymes suggests that PHA synthase, the enzyme responsible for polymerizing 3-hydroxybutyric CoA, controls the molecular weight of PHB produced in vivo.

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The effect of relative humidity on the performance of DNPH-cartridge sampling for odorous aldehydes (악취성 Carbonyl 화합물의 카트리지 채취 분석: 습도가 채취효율에 미치는 영향)

  • Lee, Min-Hee;Kim, Ki-Hyun
    • Analytical Science and Technology
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    • v.25 no.1
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    • pp.50-59
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    • 2012
  • In this study, the effect of humidity change on DNPH cartridge sampling efficiency for carbonyl compounds (CCs) has been investigated. For this analysis, gaseous standard of 6 different CCs (formaldehyde (FA), acetaldehyde (AA), propionaldehyde (PA), butyraldehyde (BA), isovaleraldehyde (IA), and valeraldehyde (VA)) was calibrated after derivatization with three types of DNPH cartridge products. Their calibration results derived at RH values between 0 and 80% were then compared against liquid phase standards. If the results of our analysis are compared by the RH values between 20 and 80%, the effect of RH can be distinguished between light and heavy CCs. For lighter CCs (like FA and AA), there was no significant change. However, for the ones heavier than PA, there was fairly noticeable increase in relative recovery ratio in RH value between 20 and 80%. Such patterns are seen consistently from all three DNPH products tested for comparison. The results of our analysis suggest that proper correction for RH change may be needed for heavier CCs by the cartridge method.