• Bulletin of the Korean Chemical Society
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• v.23 no.5
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• pp.715-720
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• 2002

Kinetic studies of the reaction of Z-aryl cyclobutanecarboxylates with X-pyridines in acetonitrile at $55.0^{\circ}C$ have been carried out. The reaction proceeds by a stepwise mechanism in which the rate-determining step is the breakdown of the zwitterion ic tetrahedral intermediate, T $\pm$ . These mechanistic conclusions are drawn based on (i) the large magnitude of ${\rho}X$ and $\rhoZ$, (ⅱ) the positive sign of ${\rho}XZ$ and the larger magnitude of $\rhoXZ$ than normal SN2 processes, (ⅲ) a small positive enthalpy of activation, ${\Delta}H{\neq}$, and a large negative, ${\Delta}S{\neq}$, and lastly (iv) adherence to the reactivity-selectivity principle (RSP) in all cases.

• Korean Journal of Mathematics
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• v.20 no.4
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• pp.371-379
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• 2012

Let D be an integral domain, $\bar{D}$ be the integral closure of D, * be a star operation of finite character on D, $*_w$ be the so-called $*_w$-operation on D induced by *, X be an indeterminate over D, $N_*=\{f{\in}D[X]{\mid}c(f)^*=D\}$, and $Kr(D,*)=\{0\}{\cup}\{\frac{f}{g}{\mid}0{\neq}f,\;g{\in}D[X]$ and there is an $0{\neq}h{\in}D[X]$ such that $(c(f)c(h))^*{\subseteq}(c(g)c(h))^*$}. In this paper, we show that D is a *-quasi-Pr$\ddot{u}$fer domain if and only if $\bar{D}[X]_{N_*}=Kr(D,*_w)$. As a corollary, we recover Fontana-Jara-Santos's result that D is a Pr$\ddot{u}$fer *-multiplication domain if and only if $D[X]_{N_*} = Kr(D,*_w)$.

• Korean Journal of Mathematics
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• v.21 no.4
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• pp.463-471
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• 2013

Let R be a ring with identity 1, $I(R){\neq}\{0\}$ be the set of all nonunit idempotents in R, and M(R) be the set of all primitive idempotents and 0 of R. We say that I(R) is additive if for all e, $f{\in}I(R)$ ($e{\neq}f$), $e+f{\in}I(R)$. In this paper, the following are shown: (1) I(R) is a finite additive set if and only if $M(R){\backslash}\{0\}$ is a complete set of primitive central idempotents, char(R) = 2 and every nonzero idempotent of R can be expressed as a sum of orthogonal primitive idempotents of R; (2) for a regular ring R such that I(R) is a finite additive set, if the multiplicative group of all units of R is abelian (resp. cyclic), then R is a commutative ring (resp. R is a finite direct product of finite field).

• Journal of the Korean Chemical Society
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• v.15 no.4
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• pp.205-209
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• 1971

The thermodynamic parameters for the solvolysis of the p-chlorobenzyl chloride taking place in the various aqueous mixtures were determined. From the application of these data to the formula ${\delta}_M{\Delta}H^{\neq}=a'Y+b{\delta}_M{\Delta}S^{\neq}$ the following conclusion was obtained: That the substrate constant a' differs in different aqueous solvent was found, and using each a' value the solvolysis mechanism of p-chlorobenzyl chloride in each aqueous mixture can be determined.

• Bulletin of the Korean Mathematical Society
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• v.27 no.2
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• pp.127-131
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• 1990

Let f:R.rarw.R be a continuous function on the real line R, and denote the n-th iterate of f by f$^{n}$ :f$^{1}$=f and f$^{n}$ =f.f$^{n-1}$ for n>1. A point x.mem.R is a periodic point of f of period k>0 if f$^{k}$ (x)=x but f$^{i}$ (x).neq.x for all 01, then it must also have a fixed point, by the intermediate Theorem. Also the question has an intriguing answer which was found by ths Russian mathematician Sharkovky [6] in 1964.

• Bulletin of the Korean Mathematical Society
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• v.40 no.1
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• pp.17-28
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• 2003

Let X be a closed, oriented, Riemannian 4-manifold with ${{b_2}^+}(x)\;>\;1$ and of simple type. Suppose that ${\sigma}\;:\;X\;{\rightarrow}\;X$ is an involution preserving orientation with an oriented, connected, compact 2-dimensional submanifold $\Sigma$ as a fixed point set with ${\Sigma\cdot\Sigma}\;{\geq}\;0\;and\;[\Sigma]\;{\neq}\;0\;{\in}\;H_2(X;\mathbb{Z})$. We show that if _X(\Sigma)\;+\;{\Sigma\cdots\Sigma}\;{\neq}\;0$ then the $Spin^{C}$ bundle $\={P}$ is not $\mathbb{Z}_2-equivariant$, where det $\={P}\;=\;L$ is a basic class with $c_1(L)[\Sigma]\;=\;0$.

• Bulletin of the Korean Mathematical Society
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• v.53 no.5
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• pp.1373-1384
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• 2016

In this paper, we research the normality of sequences of meromorphic functions concerning the sequence of omitted functions. The main result is listed below. Let {$f_n(z)$} be a sequence of functions meromorphic in D, the multiplicities of whose poles and zeros are no less than k + 2, $k{\in}\mathbb{N}$. Let {$b_n(z)$} be a sequence of functions meromorphic in D, the multiplicities of whose poles are no less than k + 1, such that $b_n(z)\overset{\chi}{\Rightarrow}b(z)$, where $b(z({\neq}0)$ is meromorphic in D. If $f^{(k)}_n(z){\neq}b_n(z)$, then {$f_n(z)$} is normal in D. And we give some examples to indicate that there are essential differences between the normal family concerning the sequence of omitted functions and the normal family concerning the omitted function. Moreover, the conditions in our paper are best possible.

• Kyungpook Mathematical Journal
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• v.55 no.1
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• pp.137-147
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• 2015

Let f be a transcendental meromorphic function of finite order in the plane such that $f^{(m)}$ has finitely many zeros for some positive integer $m{\geq}2$. Suppose that $f^{(k)}$ and f share a CM, where $k{\geq}1$ is a positive integer, $a{\neq}0$ is a finite complex value. Then f is an entire function such that $f^{(k)}-a=c(f-a)$, where $c{\neq}0$ is a nonzero constant. The results in this paper are concerning a conjecture of Bruck [5]. An example is provided to show that the results in this paper, in a sense, are the best possible.

• Kyungpook Mathematical Journal
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• v.52 no.1
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• pp.91-97
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• 2012

Let $R$ be a commutative semiring. We define a proper ideal $I$ of $R$ to be 2-absorbing (resp., weakly 2-absorbing) if $abc{\in}I$ (resp., $0{\neq}abc{\in}I$) implies $ab{\in}I$ or $ac{\in}I$ or $bc{\in}I$. We show that a weakly 2-absorbing ideal $I$ with $I^3{\neq}0$ is 2-absorbing. We give a number of results concerning 2-absorbing and weakly 2-absorbing ideals and examples of weakly 2-absorbing ideals. Finally we de ne the concept of 0 - (1-, 2-, 3-)2-absorbing ideals of $R$ and study the relationship among these classes of ideals of $R$.

• Journal of the Korean Chemical Society
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• v.13 no.4
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• pp.297-302
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• 1969

The activation parameters for the nucleophilic addition reactions of n-propyl-, n-butyl-, n-amyl-and n-hexyl-mercaptan to 3, 4-methylene-dioxy-${\beta}$-nitrostyrene were determined at pH 5.8 and pH 2.0, and also the isokinetic temperature of the reactions at pH 5.8 was obtained numerically 262${\circ}$K, and at pH 2.0, 17.1${\circ}$K. From the values obtained above, the fact that the mercaptan having the longer carbon chain has the greater nucleophilicity of it in the addition reactions has been discussed by the extrathermodynamic analysis of ${\Delta}H^{\neq}$and ${\Delta}S^{\neq}$.