• Title/Summary/Keyword: N.D.C method

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Structure Determination of D-Asparagine by Modified Pseudospectral Hartree-Fock Gradient Method

  • Lee, Jung-Goo
    • Bulletin of the Korean Chemical Society
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    • v.15 no.11
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    • pp.953-957
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    • 1994
  • Pseudospectral Hartree-Fock(PSHF) gradient calculations with $6-31G^{**}$ basis set have been carried out to determine the structure of D-Asparagine molecule $(C_4N_2O_3H_8)$ with improved grids and with the BFGS method. The modified PSHF method, despite partial optimization of the gradient code, turned out to be still faster than the conventional ab initio method, GAUSSIAN 90 program by more than twice. The optimum geometry of D-Asparagine obtained by the PSHF method is in good agreement with those calculated by the GAUSSIAN 90 program (within 0.0036 ${\AA}$ for bond lengths, 0.8 degrees for bond angles, and 1.6 degrees for torsional angles) except for three torsional angles. Here, rather large discrepancy of these three torsional angles (5-6 degrees) is attributed to the small differences in the optimum bond lengths and angles between the PSHF and GAUSSIAN 90 calculations.

A STUDY ON THE PROBABILISTIC PRODUCTION COST SIMULATION BY THE MIXTURE OF CUMULANTS APPROXIMATION (MIXTURE OF CUMULANTS APPROXIMATION 법에 의한 발전시뮬레이션에 관한 연구)

  • Song, K.Y.;Kim, Y.H.;Cha, J.M.
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.154-157
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    • 1990
  • This paper describes a new method of calculating expected energy generation and loss of load probability (L.O.L.P) for electric power system operation and expansion planning. The method represents an equivalent load duration curve (E.L.D.C) as a mixture of cumulants approximation (M.O.C.A), which is the general case of mixture of normals approximation (M.O.N.A). By regarding a load distribution as many normal distributions-rather than one normal distribution-and representing each of them in terms of Gram-Charller expansion, we could improve the accuracy of results. We developed an algorithm which automatically determines the number of distribution and demarcation points. In modelling of a supply system, we made subsets of generators according to the number of generator outage: since the calculation of each subset's moment needs to be processed rapidly, we futher developed specific recursive formulae. The method is applied to the test systems and the results are compared with those of cumulant, M.O.N.A and Booth-Baleriaux method. It is verified that the M.O.C.A method is faster and more accurate than any other methods.

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An Experimental Study on Reinforcing Efficiency of H-Shaped Steel Beams with a Rectangular Web Opening (유공 H 형강보의 보강효율에 관한 실험적 연구)

  • Kim, Jin-Mu;Cho, Chul-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.3 no.1
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    • pp.171-178
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    • 1999
  • Despite of decrease in shear and moment strengths, most steel structural designers use web openings in beams because of economical benefit and requirement. The purpose of this study is to suggest the method of reinforcement of H-shape steel beams with a rectangular web opening. If shear predominates over bending, it is necessary to consider all possible combinations of shear force and bending moment acting at the opening. In this paper, the ultimate strength and behavior of perforated beams have been investigated according to parameters (ratio of M/V, opening width within opening height ratio D/h, various reinforcing types A/B/C/D/M/N/W). The results of this study are as follows ; 1. Deformation of H-shape steel beams with a rectangular web opening was greatly affected by not only bending but also shear. 2. SB1-2/3 series have little difference in the reinforced efficiency, but SB1-2E/3E series have difference in the reinforced efficiency according to the reinforcement type. 3. Efficiency of SB1-2E/3E series is determined by reinforcing types, which RB1-2E-B/M/C and RB1-3E-M/D/C specimens have good efficient. Reinforcing type of perforated beams chooses efficient method according to ratio of M/V and D/h.

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Diamond Film Deposition on Ceramic Substrates by Hot-Filament CVD and Evaluation of the Adhesion (HF-CVD법에 의한 세라믹스 기판에의 다이아몬드박막 합성과 그 밀착성 평가)

  • Sin, Sun-Gi;Matsubara, Hideaki
    • Korean Journal of Materials Research
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    • v.10 no.8
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    • pp.575-580
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    • 2000
  • Diamond thin films were deposited on $Si_3N_4$, SiC, TiC and $Al_2O_3$, substrates by the CVD method using Ta(TaC)Filament, and the appearance of the diamond films and their adhesion properties were examined by SEM, optical microscopy, indentation test and compression topple test. Diamond films were deposited at lower $CH_4$ concentration than 5%$CH_4$ for all kinds of the substrate material, but graphitic(amorphous)carbon was observed at 10%$CH_4$. The diamond film of about $12\mu\textrm{m}$ thickness on WC substrate partly peeled off, but the film on $Si_3N_4$ substrate held good adhesion. The indentation test showed that roughly ground surface was very effective for adhesion of diamond films to substrate. The topple test revealed that film thickness was an important factor governing the adhesion of the diamond film.

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Identification and Association of SNPs in TBC1D1 Gene with Growth Traits in Two Rabbit Breeds

  • Yang, Zhi-Juan;Fu, Lu;Zhang, Gong-Wei;Yang, Yu;Chen, Shi-Yi;Wang, Jie;Lai, Song-Jia
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.11
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    • pp.1529-1535
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    • 2013
  • The TBC1D1 plays a key role in body energy homeostasis by regulating the insulin-stimulated glucose uptake in skeletal muscle. The present study aimed to identify the association between genetic polymorphisms of TBC1D1 and body weight (BW) in rabbits. Among the total of 12 SNPs detected in all 20 exons, only one SNP was non-synonymous (c.214G>A. p.G72R) located in exon 1. c.214G>A was subsequently genotyped among 491 individuals from two rabbit breeds by the high-resolution melting method. Allele A was the predominant allele with frequencies of 0.7780 and 0.6678 in European white rabbit (EWR, n = 205) and New Zealand White rabbit (NZW, n = 286), respectively. The moderate polymorphism information content (0.250.05). Our results implied that the c.214G>A of TBC1D1 gene might be one of the candidate loci affecting the trait of 35 d BW in the rabbit.

Low resistivity ohmic Pt/Si/Ti contacts to p-type 4H-SiC (Pt/Si/Ti P형 4H-SiC 오옴성 접합에서 낮은 접촉 저항에 관한 연구)

  • Yang, S.J.;Lee, J.H.;Nho, I.H.;Kim, C.G.;Cho, N.I.;Jung, K.H.;Kim, E.D.;Kim, N.K.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.521-524
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    • 2001
  • In this letter. we report on the investigation of Ti. Pt/Si/Ti Ohmic contacts to p-type 4H-SiC. The contacts were formed by a 2-step vacuum annealing at $500^{\circ}C$ for 1h. $950^{\circ}C$ for 10 min respectively. The contact resistances were measured using the transmission line model method. which resulted in specific contact resistivities in the $3.5{\times}10^{-3}$ and $6.2{\times}10^{-4}ohm/cm^{2}$, and the physical properties of the contacts were examined using x-ray diffraction. microscopy. AES(auger electron spectroscopy). AES analysis has shown that, at this anneal temperature, there was a intermixing of the Ti and Si. migration of into SiC. Overlayer of Pt had the effect of decreasing the specific contact resistivity and improving the surface morphology of the annealed contact.

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Flavonol Glycosides from the Aerial Parts of Aceriphyllum rossii and Their Antioxidant Activities

  • Han Jae-Taek;Bang Myun-Ho;Chun Ock-Kyoung;Kim Dae-Ok;Lee Chang-Yong;Baek Nam-In
    • Archives of Pharmacal Research
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    • v.27 no.4
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    • pp.390-395
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    • 2004
  • The methanol extract obtained from the aerial parts of Aceriphyllum rossii (Saxifragaceae) was fractionated into ethyl acetate (EtOAc), n-BuOH and $H_2O$ layers through solvent fractionation. Repeated silica gel column chromatography of EtOAc and n-BuOH layers afforded six flavonol glycosides. They were identified as kaempferol 3-O-$\beta$-D-glucopyranoside (astragalin, 1), quercetin 3-O-$\beta$-D-glucopyranoside (isoquercitrin, 2), kaempferol 3-O-$\alpha$-L-rhamnopyranosyl $(1{\to}6)-\beta$-D-glucopyranoside (3), quercetin 3-O$\alpha$-L-rharnnopyranosyl $(1{\to}6)-\beta$-D-qlucopyrano-side (rutin, 4), kaempferol 3-O-[$\alpha$-L-rharnnopyranosyl $(1{\to}4)-\alpha$-L-rhamnopyranosyl $(1{\to}6)-\beta$-D-glucopyranoside] (5) and quercetin 3-O-[$\alpha$-L-rhamnopyranosyl $(1{\to}4)\alpha$-L-rhamnopyranosyl $(1{\to}6)\beta$-D-glucopyranoside] (6) on the basis of several spectral data. The antioxidant activity of the six compounds was investigated using two free radicals such as the ABTS free radical and superoxide anion radical. Compound 1 exhibited the highest antioxidant activity in the ABTS $\{2,2-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid)\}$ radical scavenging method. 100 mg/L of compound 1 was equivalent to $72.1\pm1.4\;mg/L$ of vitamin C, and those of compounds 3 and 5 were equivalent to $62.7\pm0.5\;mg/L$ and $54.3\pm1.3\;mg/L$ of vitamin C, respectively. And in the superoxide anion radical scavenging method, compound 5 exhibited the highest activity with an $IC_{50}$ value of $17.6{\pm}0.3{\mu}M$. In addition, some physical and spectral data of the flavonoids were confirmed.

Characterization of PMW-PZT Thick Films Prepared by Screen Printing Method (스크린 인쇄법에 의해 제조한 PMW-PZT 후막의 특성)

  • Son, Jin-Ho;Kim, Yong-Bum;Cheon, Chae-Il;Yoo, Kwang-Soo;Kim, Tae-Song
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.30-35
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    • 2004
  • PMW-PZT thick films of about $30{\mu}m$ thickness were fabricated on Pt/$TiO_2$/$SiN_x$Si substrate by the hybrid method of screen printing and PZT sol application. With the increase of the number of the sol application times, the sintered density and electrical properties of PMW-PZT thick films were evidently increased. For the PMW-PZT thick film with PZT sol application of 10-times, the dielectric constant ($\varepsilon_r$) was 745 at the frequency of 100 KHz and thepiezoelectric coefficient ($d_33$) was 155 pC/N at the applied pressure of 1 atm.

Effect of plasma polythiophene as a buffer layer inserted on OLEDs (버퍼층으로서 플라즈마 polythiopheneol 유기EL소자에 미치는 영향)

  • Park, S.M.;Lee, B.J.;Kim, H.G.;Lim, K.B.;Kim, J.T.;Park, S.H.;Lim, E.C.;Lee, E.H.;Lee, D.C.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.177-180
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    • 2002
  • The purpose of this thesis is to develope buffer materials by the plasma polymerization method. In this article the buffer materials, plasma poly thiophene(PPTh) is used to study the interface of eter/organic in organic light emitting diodes(OLED). The interface of meter/organic materials is the important and critical objectives in development of OLED. The hole transport layer was N,N'-dipheneyl-N, N'bis-(3-methypheneyl)-1,1'dipheneyl-4,4'-diamine (TPD); the host material of mission layer was 8-tris-hydroxyquinoline aluminium (Alq3). When PPTh was inserted between ITO and TPD, emission efficiency increased.

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Fatigue Strength Assessment of the Cruciform Fillet Welded Joint Considering Stress Concentration at Weld Toe (응력집중을 고려한 십자형 필렛 용접재의 피로강도 평가)

  • Kim D. J.;Seck C. S.;Koo J. M.;Park J. S.;Seo J. W.;Goo B. C.
    • Proceedings of the KSR Conference
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    • 2004.10a
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    • pp.222-227
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    • 2004
  • Under cyclic loading, the fatigue failures of welded joints occur at weld toes which induce stress concentration by weld shape. So we need to obtain the peak stress and the S-N curve to assess the fatigue strength of welded joints. However the measurement of peak stress is of high uncertainty and low reproducibility, so we use nominal stress instead in fatigue tests of welded joints. In this study, fatigue tests to obtain S-N curves and FE analyses to obtain stress concentration factors were conducted for the two types of cruciform fillet welded joints, that is, load-carrying and non load-carrying types. Then we changed the obtained S-N curves to that based on peak stress using the hot-spot stress concept. From the analyses of the S-N curves obtained, we have concluded that there is a need to develop a new method to evaluate the fatigue life.

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