• Bulletin of the Korean Chemical Society
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• 제17권4호
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• pp.331-334
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• 1996

New copper(Ⅱ) complex of the pentaaza non-macrocyclic ligand 1-(2-aminoethyl)-3-(N-{2-aminoethyl}aminomethyl)-1,3-diazacyclohexane (2) and a dinuclear copper(Ⅱ) compex of the bis(macrocyclic) ligand 3, in which two 1,5,8,10,12,15-hexaazabicyclo[11.3.11.5]heptadecane subunits are linked together by an ethylene chain through the uncoordinated nitrogen (N10) atoms, have been prepared selectively by the reaction of the metal ion, 1,4,8-triazaoctane, ethylenediamine, and formaldehyde. The dinuclear complex [Cu2(3)]4+ has been also prepared by the reaction of [Cu(2)]2+ with ethylenediamine and formaldehyde. The reaction products largely depend on the molar ratio of the reactants employed. The mononuclear complex or each macrocyclic subunit of the dinuclear complex contains one 1,3-diazacyclohexane ring and has a square-planar geometry with a 5-6-5 or 5-6-5-6 chelate ring sequence. In acidic solution, the copper(Ⅱ) complex of 2 dissociates more slowly than those of other related non-cyclic polyamines.

• 한국융합학회논문지
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• 제12권2호
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• pp.233-246
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• 2021

본 연구에서는 외상 유형(단순 외상과 복합 외상)에 따라 PTSD 증상의 심각도와 자기 및 타인개념에 차이가 있는지를 확인하고자 하였다. 총 166명의 대학생 및 대학원생들 중 단순 외상(n=31)과 복합 외상(n=30)으로 분류된 참여자들의 자료를 최종 분석에 포함하였다. 참여자들은 생활사건 체크리스트(LEC), 개정된 사건 충격 척도(IES-R)와 E-prime으로 제작된 정서 스트룹 과제를 수행하였다. 결과는 다음과 같다. 첫째, 단순 외상 집단보다 복합 외상 집단에서 더 높은 수준의 PTSD 증상이 나타났다. 둘째, 스트룹 과제에서 부정적인 자기개념을 반영하는 단어를 2초 제시한 조건에서 복합 외상 집단이 단순 외상 집단보다 반응시간이 더 길었다. 이러한 결과는 복합 외상 집단과 단순 외상 집단이 적어도 PTSD 증상 및 자기개념에 다른 특성을 가지고 있다는 것을 제안한다. 마지막으로, 본 연구의 의의와 한계점에 대해 논의하였다.

• 한국산업융합학회 논문집
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• 제1권1호
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• pp.43-49
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• 1998

The SS-phpm 4HCl(N,N'-bis-[2(S)-pyrrolidinylmethyl]phenylene-l,2-diamine-4-Hydrochloride) ligand having stereospecificity has been prepared and reacted with trans-[$Co(pyridine)_4Cl_2]$Cl. The resultants are purple crystals, which are identified to be ${\Delta}$-cis-${\beta}$-[$Co(SS-phpm)Cl_2$]Cl by elemental analysis and UV/Vis- and CD-absorption spectra, The conformation of SS-phpm in ${\Delta}$-cis-${\beta}$ complex is ${\delta}$ ${\varepsilon}$ ${\lambda}$ (SSSS) for each of the five-membered chelated ring. Futhermore, according to orientation of secondary amine, total strain energy on each isomers was calculated by molecular mechanics(MM) to verify structural characterization and spectral data. As the result, the most stabilized isomer was ${\Delta}$-cis-${\beta}$(SSSS). The value of total strain energy(U) of ${\Delta}$-cis-${\beta}$(SSSS) isomer was 63.21 kcal/mol, respectively.

• 한국자기공명학회논문지
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• 제18권2호
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• pp.74-81
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• 2014

The $N_2O_2$ tetradentate Schiff base ligand, N,N'-bis(salicylidene)pentane-1,3-diamine (Salpn), coupled with 1:2 concentration ratio of 1,3-diaminopentane and salicylaldehyde was used to produce a series of macrocyclic Nikel(II) complexes. In the metal complexation, it was observed that Salpn macrocyclic ligand can adopt more than a metal ion giving an unique multinuclear metal complexes including Ni(II)Salpn and $Ni(II)_3(Salpn)_2$. Characteristic IR ${\upsilon}(M-O)$ peaks for Ni(II)Salpn and $Ni(II)_3(Salpn)_2$ were observed to be $1028cm^{-1}$ and $1024cm^{-1}$, respectively. Characteristic UV-Vis absorption ${\lambda}_{max}$ peaks for $Ni(II)_3(Salpn)_2$ were observed to be 241nm and 401 nm. Structural characterization of $Ni(II)_3(Salpn)_2$ by NMR exhibits that the salicylidene ring moiety has two different resonance signals originated from the magnetically asymmetric diligand and trinuclear bis complex. Complete NMR signal assignments and characterizations elucidating structural features of $Ni(II)_3(Salpn)_2$ were described in detail.

• 대한화학회지
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• 제50권2호
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• pp.107-115
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• 2006

[X=ortho (L1), meta(L2) 및 para(L3)]리간드를 갖는 주석(II) 화합물들을 합성하고, 그 특성을 원소분석, 적외선 분광광도법, 자외선/가시광선 분광광도법 및 열분석법을 이용하여 확인하였다. 자외선 분광광도법을 통하여, 주어진 ONNO 주게 리간드들의 이민(imine) 및 카보닐기의 배위 모드가 C2v 대칭성을 갖는 것으로 나타났다. 또한 열분석 결과, Sn(L3) 화합물이 가장 높은 활성화 에너지를 가지는 반면, Sn(L2) 화합물이 가장 낮은 활성화 에너지를 가짐을 알 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3173-3179
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• 2010

New complex $[Mn(II)H_{1.5}L]_2[Mn(II)H_3L]_2(ClO_4)_5{\cdot}3H_2O$ (1), where $H_3L$ is tris {2-(4-imidazolyl)methyliminoethyl} amine (imtren), has been prepared by reacting manganese(II) perchlorate hexahydrate with the imtren ligand in methanol. X-ray crystallographic study revealed that the imtren ligand hexadentately binds to Mn(II) ion through the three Schiff-base imine N atoms and three imidazole N atoms with a distorted octahedral geometry, and the apical tertiary amine N atom of the ligand pseudo-coordinates to Mn(II), forming overall a pseudo-seven coordination environment. The hydrogen-bonds between imidazole and imidazolate of $[Mn(II)H_{1.5}L]^{0.5+}$ complex ions are extended to build a 2D puckered network with trigonal voids. $[Mn(II)H_3L]^{2+}$ complex ions constitutes another extended 2D puckered layer without hydrogen bonds. Two layers are wedged each other to constitute overall stack of the crystal. Peroxidase activity of complex 1 was examined by observing the oxidation of 2,2'-azinobis(3-ethylbenzothiazoline)-6-sulfonic acid (ABTS) with hydrogen peroxide in the presence of complex 1. Generation of $ABTS^{+{\cdot}}$ was observed by UV-vis and EPR spectroscopies, indicating that the complex 1, a fully-coordinated mononuclear Mn(II) complex with nitrogen-only ligand, has a heme-independent peroxidase activity.

• Kyungpook Mathematical Journal
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• 제45권2호
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• pp.191-198
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• 2005

In this paper, we introduce a length function for elements of the imprimitive complex reflection group G(m, 1, n) and study its properties. Furthermore, we show that every conjugacy class of G(m, 1, n) can be represented by an admissible diagram. The corresponding results for Weyl groups are well known.

• 호남수학학술지
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• 제18권1호
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• pp.59-77
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• 1996

In this paper, we study how the second coefficient in the power series expansion of functions in $P_n$(a; b, M), $F_n$(a; b, M) and $G_n$(a; b, M) influences certain properties like distortion, ${\gamma}-spiral$ radius and radius of starlikeness of these classes.

• 호남수학학술지
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• 제26권2호
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• pp.155-161
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• 2004

The shape operator or second fundamental tensor of a real hypersurface in $M_n(c)$ will be denoted by A, and the induced almost contact metric structure of the real hypersurface by (${\phi}$, <, >,${\xi}$, ${\eta}$). The purpose of this paper is to prove that is no ruled real hypersurface M in a complex space form $M_n(c)$, $c{\neq}0$, $n{\geq}3$, who satisfies $R_{\xi}{\phi}={\phi}R_{\xi}$ on M.

• 호남수학학술지
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• 제28권4호
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• pp.573-589
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• 2006

Let M be a real hypersurface with almost contact metric structure $({\phi},{\xi},{\eta},g)$ in a non flat complex space form $M_n(c)$. In this paper, we prove that if the structure Jacobi operator $R_{\xi}$ is ${\xi}$-parallel and the Ricci tensor S commutes with the structure operator $\phi$, then a real hypersurface in $M_n(c)$ is a Hopf hypersurface. Further, we characterize such Hopf hypersurface in $M_n(c)$.