• Bulletin of the Korean Chemical Society
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• v.20 no.3
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• pp.297-300
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• 1999

The protonation constants of the macrocyclic ligands, 1,4-dioxa-7,10,13,16-tetraaza-cyclooctadecane-N,N',N",N"'-tetra(acetic acid) [N-ac4[18]aneN402] and 1,4-dioxa-7,10,13,16-tetraazacyclooctadecane-1,4-dioxa-7,10,13,16-N,N',N",N"'-tetra(methylacetic acid) [N-meac4[18]aneN4O2] have been determined by using potentiometric method. The protonation constants of the N-ac4[18]aneN4O2 were 9.31 for logK1H, 8.94 for logK2H, 7.82 for logK3H, 4.48 for logK4H and 2.94 for logK5H. And the protonation constants of the N-meac4[18]aneN4O2 were 9.34 for logK1H, 9.13 for logK2H, 8.05 for logK3H, 5.86 for logK4H, and 3.55 for logK5H. The stability constants of complexes on the divalent transition ions (Co2+, Ni2+, Cu2+, and Zn2+) and tiivalent metal ions (Ce3+, Eu3+, Gd3+, and Yb3+) with ligands N-ac4[18]-aneN4O2 and N-meac4[18]aneN4O2 have been obtained from the potentiometric data with the aid of the BEST program. The three higher values of the protonation constants for synthesized macrocyclic ligands correspond to the protonation of nitrogen atoms, and the fourth and fifth values correspond to the protonation of the carboxylate groups for the N-ac4[18]aneN4O2 and N-meac4[18]aneN4O2. The meatal ion affinities of the two tetra-azamacrocyclic ligands with four pendant acetate donor groups or methylacetate donor groups are compared. The effects of the metal ions on the stabilities are discussed, and the trends in stability constants resulting from changing the macrocyclic ring with pendant donor groups and acidity of the metal ions.

• Journal of Industrial Convergence
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• v.19 no.4
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• pp.23-28
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• 2021

This paper finds the regular pattern of n = [3, ∞] for Euler square game related with n = 6(6×6=36) thirty-six officer problem that is still unsolved problem. The solution of this problem is exists for n = [3, 10] without n = 6. Also, previous researchers finds the random assigned solution for specific number using computer programming. Therefore, the solution of n = [11, ∞] Euler squares are unsolved problem because of anything but easy. This paper attempts to find generalized patterns for domains that have been extended to n = [3, ∞], while existing studies have been limited to n = [3, 10]. This paper classify the n = [3, ∞] into n = odd, 4k even, 4k+2 even of three classes. Then we find the simple regular pattern solution for n = odd and 4k even(n/2 = even). But we can't find the regular pattern for 4k+2 even(n/2 = odd).

• Toxicological Research
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• v.14 no.2
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• pp.177-181
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• 1998

Dithiocarbamate and mixed disulfide containing allyl functions were designed and synthesized as putative chemopreventive agents, i.e. N,N-diallyldithiocarbamate (DATC) and S-(N,N-diallyldithiocarbamoyl)-N-acetylcysteine (AC-DATC). DATC and AC-DATC were administered and the activities of cytosolic glutathione S-transferase (GST), glutathione reductase (GR) and microsomal N-nitrosodiethylamine (NDEA) deethylase were assayed in order to test the effects of these organosulfur com-pounds on the detoxification and metabolic activation system of NDEA. The amounts of hepatic glutathione (GSH and GSSG) was also determined. The administration of DATC to rats led to an increase in the activity of GR and to an inhibition of CYP2E1-mediated NDEA deethylation. AC-DATC induced the activity of GR and GST, increased the hepatic GSH content and inhibited the rate of NDEA deethylation. The level of GSSG was decreased as a consequence of the increased activity of GR. These effects may contribute to possible antimutagenic and anticarcinogenic action of the dithiocarbamates investigated.

• Honam Mathematical Journal
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• v.34 no.4
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• pp.519-531
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• 2012

Let ${\sigma}_s(N)={\sum}_{d{\mid}N}d^s$. Next, the convolution sums ${\sum}_{k<N/3}{\sigma}_1(3^mk){\sigma}_1(2^n(N-3k))$, ${\sum}_{<N/3}{\sigma}_1(2^mk){\sigma}_1(3^n(N-3k))$, etc., are evaluated for all $N{\in}\mathbb{N}$ with $m$, $n{\in}\mathbb{N}{\cup}\{0\}$.

• Proceedings of the Korean Institute of Intelligent Systems Conference
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• 2004.10a
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• pp.345-350
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• 2004

In this paper we study the controllability for the nonlinear fuzzy integro-differential equations on E$_{N}$$^{n}$ by using the concept of fuzzy number of dimension n whose values are normal, convex, upper semicontinuous and compactly supported surface in R$^n$. E$_{N}$$^{n}$ be the set of all fuzzy numbers in R$^n$ with edges having bases parallel to axis X$_1$, X$_2$, …, X$_{n}$ .X> .

• Archives of Pharmacal Research
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• v.9 no.1
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• pp.15-18
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• 1986

Various naturally occuring methylated amino acid derivatives were resolved on high performance liquid chromatography (HPLC), using o-phthadialdehyde as a fluorogenic reagent. We separated .$\varepsilon$-N-monomethyllysine, $\varepsilon$-N- dimethyllysine, and $\varepsilon$-N-acetyllysine from lysine derivatives. $N^{G}$-Monomethylarginine and $N^{G}$-dimethylarginine were separated from arginine derivatives. However, $\varepsilon$-N-monomethyllsine and $\varepsilon$-N-trimethyllysine, $N^{G}$, $N^{G}$-dimethylarginine and $N^{G}$, $N^{G}$-dimethylarginine were not resolved under the conditions employed. S-Methylmethionine, S-methylcysteine, and 1-N-methylhistidine or 3-N-methylhistidine were clearly separated from their reference amino acids, even though 1-N-methyl-and 3-N-methylhistidine coul not be separated.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.04b
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• pp.97-100
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• 2004

We have grown GaN layers with in-situ SiN mask by metal organic chemical vapor deposition (MOCVD) and study the characteristic of the GaN layer. We have changed the deposition time of SiN mask from 45s to 5min and obtain th optimum condition in 45s. The PL intensity of GaN with SiN mask improved 2 times to that without SiN mask and the carrier concentraion increased from $3.5{\times}10^{16}cm^{-3}$ to $1.8{\times}10^{17}cm^{-3}$. We have thus shown that the SiN mask improved significantly the optical properties of the GaN layer.

• Journal of applied mathematics & informatics
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• v.28 no.3_4
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• pp.1025-1034
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• 2010

Let {$X_n$, $n\;{\in}\;\mathbb{Z}_+^d$} be a field of identically distributed and negatively associated random variables with mean zero and set $S_n\;=\;{\sum}_{k{\leq}n}\;X_k$, $n\;{\in}\;\mathbb{Z}_+^d$, $d\;{\geq}\;2$. We investigate precise asymptotics for ${\sum}_n|n|^{r/p-2}P(|S_n|\;{\geq}\;{\epsilon}|n|^{1/p}$ and ${\sum}_n\;\frac{(\log\;|n|)^{\delta}}{|n|}P(|S_n|\;{\geq}\;{\epsilon}\;\sqrt{|n|\log|n|)}$, ($0\;{\leq}\;{\delta}\;{\leq}\;1$) as ${\epsilon}{\searrow}0$.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.12
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• pp.972-978
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• 2001

Some effects of Al/N ratio on microstructure of AlN films grown on Si(111) substrates by PAMBE were investigated. Al/N ratio was controlled by rf power of N$_2$ plasma source system. Al excess or N excess conditions were obtained below or above 350 W rf power, respectively. Surface roughness and morphology of AlN film grown at Al/N=1.0 showed the best result. Under Al excess condition, it was suggested that excess Al atoms which did not contribute to the growth of AlN film prevent the normal crystal growth and make abnormal growth of some columns. However, under N excess condition, it was explained that some of the excess active N source turned into gas state and then desorbed out from substrate.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1996.11a
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• pp.75-78
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• 1996

The deposition condition Gf TiN films as electrode was studied by sheet resistance, TiN depositon Thickness X-ray diffraction. TiN was made by reactively DC magnetron sputtering with varying $N_2$/Ar mixture gas and substrate temperature. After finding The deposition condition of TiN films, The samples with the structure of Cu/Ta$_2$O$_{5}$, TiN/Ta$_2$O$_{5}$Si, Cu/TiN/Ta$_2$O$_{5}$ Si were prepared and were measured I-V, C-V. As a results, it was found that when TiN was deposited in an $N_2$a results, it was found that when TiN was deposited in an $N_2$atmosphere its Sheet resistance is lower n than n V$_2$Ar mixtureixture