• Title/Summary/Keyword: Multi-plasma

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Evaluation of MWCNT Exposure and the Wear Characteristics of MWCNT-containing PC/ABS Composites (다중벽 탄소나노튜브를 함유한 PC/ABS 복합재의 마모 특성 및 다중벽 탄소나노튜브의 유출 평가)

  • Lee, Hyun-Woo;Kim, Kyung-Shik;Lee, Jae-Hyeok;Kim, Hyo-Sop;Kim, Jae-Ho;Oh, Dong-Hoon;Ryu, Sang-Hyo;Jang, Young-Chan;Kim, Jae-Hyun;Lee, Hak-Joo;Kim, Kwang-Seop
    • Tribology and Lubricants
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    • v.30 no.5
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    • pp.278-283
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    • 2014
  • Carbon nanotubes (CNTs) are used in various composite materials to enhance electrical, thermal and mechanical properties of composite materials. In this study, we investigate the wear characteristics of polycarbonate/acrylonitrile-butadiene-styrene (PC/ABS) blends containing multi-walled carbon nanotubes (MWCNTs). PC/ABS blends are commonly used in many industrial applications such as cellular phones and display cases and MWCNTs have been added to the PC/ABS blends to improve their electromagnetic interference shielding (EMS). We performed wear tests on PC/ABS blends containing MWCNTs under reciprocating linear sliding conditions with chrome steel balls as a counterpart material. The normal loads were 10, 30, 50, 70, 100 N, the sliding speed was 10 mm/s, the stroke length was 15 mm, and the tests lasted 900 s. The MWCNTs included in the PC/ABS blends lower the wear volume and friction coefficient of the composites. We analyzed the wear debris collected from the composites during the tests in terms of the MWCNT concentration using inductively coupled plasma optical emission spectroscopy. The results show that the quantity of MWCNTs in the debris is proportional to the concentration of MWCNTs in the composite, indicating that the exposure of the MWCNTs to environments by wear could be increased with their concentration in the composite.

Molybdenum Isotope Analysis of Standard Reference Materials (표준물질을 이용한 몰리브덴 동위원소 분석)

  • Jo, Yunsoo;Kil, Youngwoo;Ryu, Jongsik;Seol, Junghwan;Nguyen, The Cong;Jung, Woochul;Park, Sanghee
    • Economic and Environmental Geology
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    • v.49 no.2
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    • pp.89-95
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    • 2016
  • Mo isotope, one of highly redox-sensitive isotopes, has been shown to be useful tracers of geochemical processes. Many studies for Mo isotope have documented with the help of recently developed analysis tools, but it has not yet been documented in the Korea. In this study, we introduce two-stage column separation method of Mo using column tube (BioRad PolyPrep(R) column, 10 ml) and anion exchange resin (BioRad Resin AG(R) 1-X8, 200-400 mesh). Mo isotope ratios in the solid SRMs (BHVO-2, SDO-1, PACS-2) and liquid SRM (IAPSO) were measured on MC-ICP-MS (Multi-collector Inductively Coupled Plasma Mass Spectrometer) and then compared with reference Mo isotope ratios. Mo isotope ratios in our study overlap with reference Mo isotope ratios within analytical error.

MICROLEAKAGE IN RESIN COMPOSITE POLYMERIZED WITH VARIOUS LIGHT CURING UNITS (수종의 광중합기에 의한 복합레진 중합시 미세누출에 관한 연구)

  • Park, Sung-Jin;Kim, Dae-Eup;Lee, Kwang-Hee
    • Journal of the korean academy of Pediatric Dentistry
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    • v.32 no.4
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    • pp.604-610
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    • 2005
  • This study was to evaluate the effects of several light curing units on the microleakage of composite resin restorations in primary teeth. The types of curing units were traditional low intensity halogen light(Optilux 360), plasma arc light(Filpo) low heat plasma arc light(Aurys) and high intensity LED(Freelight 2). After preparing cavities on sound primary teeth, cavities were filled with composite resin(Z100) using the same resin bond agent(Scotchbond Multi-Purpose) and were cured with each curing light system. After storing each specimen in sterile water for 24 hours, thermal circulation was done 1,000 times followed by pigmentation using 2% methylene blue solution. Each specimen was sliced and the degree of pigmentation was graded. When microleakage is graded, the average of Aurys was 0.95 which was the lowest and Freelight 2(1.05), Filpo(1.25), Optilux 360(1.30) followed. But values were not shown statistically significant difference (P>0.05). The results suggest that the newly developed curing units which has advantage in children by decreasing discomfort and procedure time can increase the microleakage of the composite resin.

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Optimal Conditions for Pretreated Sample for Sr Isotope Analysis by MC-ICP-MS: A Comparison Between Eichrom (SR-R50-S)'s and Bio-Rad(AG®50W-X8)'s Resins (다검출기 유도결합 플라즈마 질량분석기에 의한 Sr 동위원소 분석을 위해 전처리된 시료의 최적 조건: Eichrom사 Sr 수지(SR-R50-S)와 Bio-Rad사 수지(AG®50W-X8) 비교)

  • Myoung Jung, Kim;Seung-Gu, Lee
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.4
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    • pp.507-520
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    • 2022
  • The Sr isotope ratio, which is used as basic data for rock formation time, crustal and mantle evolution studies, is determined by mass spectrometer such as thermal ionization mass spectrometry (TIMS) or multi-detector inductively coupled plasma mass spectrometry (MC-ICP-MS). In this technical report, we compared how incomplete chemical separation of elements affects the determination of Sr isotope ratios. For the experiment, commercial resin, NBS987(NIST SRM987) Sr isotope standard, and rock standard samples from the Geological Survey of Japan (GSJ) such as JG1a, JB3 and JA1 were used. As a result of the comparative experiment, it was clearly observed that the measured values of 87Sr/86Sr change when Rb remains due to incomplete separation of the NBS987 Sr isotope standard sample as well as the rock standard samples of GSJ. This indicates that complete separation is an important factor since the calculated value deviates from the true value even though correction for isotope interference by isobar is performed when measuring the isotope ratio with MC-ICP-MS. This also suggests that, when reporting the measurement result of Sr isotope ratio using MC-ICP-MS, the measurement strength of 85Rb should be reported together with the measurement strength of all isotopes of Sr so that isotope interference by isobar can be judged.

Study on Fiber Laser Annealing of p-a-Si:H Deposition Layer for the Fabrication of Interdigitated Back Contact Solar Cells (IBC형 태양전지 제작을 위한 p-a-Si:H 증착층의 파이버 레이저 가공에 관한 연구)

  • Kim, Sung-Chul;Lee, Young-Seok;Han, Kyu-Min;Moon, In-Yong;Kwon, Tae-Young;Kyung, Do-Hyun;Kim, Young-Kuk;Heo, Jong-Kyu;Yoon, Ki-Chan;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.430-430
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    • 2008
  • Using multi plasma enhanced chemical vapor deposition system (Multi-PECVD), p-a-Si:H deposition layer as a $p^+$ region which was annealed by laser (Q-switched fiber laser, $\lambda$ = 1064 nm) on an n-type single crystalline Si (100) plane circle wafer was prepared as new doping method for single crystalline interdigitated back contact (IBC) solar cells. As lots of earlier studies implemented, most cases dealt with the excimer (excited dimer) laserannealing or crystallization of boron with the ultraviolet wavelength range and $10^{-9}$ sec pulse duration. In this study, the Q-switched fiber laser which has higher power, longer wavelength of infrared range ($\lambda$ = 1064 nm) and longer pulse duration of $10^{-8}$ sec than excimer laser was introduced for uniformly deposited p-a-Si:H layer to be annealed and to make sheet resistance expectable as an important process for IBC solar cell $p^+$ layer on a polished n-type Si circle wafer. A $525{\mu}m$ thick n-type Si semiconductor circle wafer of (100) plane which was dipped in a buffered hydrofluoric acid solution for 30 seconds was mounted on the Multi-PECVD system for p-a-Si:H deposition layer with the ratio of $SiH_4:H_2:B_2H_6$ = 30:120:30, at $200^{\circ}C$, 50 W power, 0.2 Torr pressure for 20 minutes. 15 mm $\times$ 15 mm size laser cut samples were annealed by fiber laser with different sets of power levels and frequencies. By comparing the results of lifetime measurement and sheet resistance relation, the laser condition set of 50 mm/s of mark speed, 160 kHz of period, 21 % of power level with continuous wave mode of scanner lens showed the features of small difference of lifetime and lowering sheet resistance than before the fiber laser treatment with not much surface damages. Diode level device was made to confirm these experimental results by measuring C-V, I-V characteristics. Uniform and expectable boron doped layer can play an important role to predict the efficiency during the fabricating process of IBC solar cells.

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Preparation of Alkyl Acrylate and Functional Monomer Multi Core-Shell Composite Particles (알킬 아크릴레이트와 관능성 단량체계 다중 Core-Shell 복합입자의 제조)

  • Choi, Sung-Il;Cho, Dae-Hoon;Seul, Soo-Duk
    • Journal of Adhesion and Interface
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    • v.14 no.1
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    • pp.1-12
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    • 2013
  • Multi core-shell composite particles were prepared by the water-born emulsion polymerization of various core monomers such as methyl methacrylate (MMA), ethyl methacrylate (EMA) and shell monomers such as MMA, EMA, 2-hydroxyl ethyl methacrylate (2-HEMA), glycidyl methacrylate (GMA) and methacrylic acid (MAA) in the presence of different concentrations of sodium dodecyl benzene sulfonate (SDBS). The following conclusions are drawn from the conversion, particle size and distribution, average molecular weight, molecular structure, glass transition temperature with DSC, contact angle after plasma treatment, tensile strength and isothermal decomposition kinetics. In the case of the concentration of 0.02 wt% SDBS, the conversion of MMA core-(EMA/GMA) shell composite particles was excellent as 98.5%. In the case of the concentration of 0.03 wt% SDBS, the particle size of EMA core-(MMA/GMA) shell composite particles was high as $0.48{\mu}m$. We confirmed that 3 points of glass transition temperatures appear for multi core-shell composite particles compared to 1~2 points of glass transition temperatures appear for general copolymer particles. Overall, the adhesion strength of shell composite particles was in the order of EMA/MAA > EMA/2-HEMA > EMA/GMA.

Electrochemical Determination of Bisphenol A Concentrations using Nanocomposites Featuring Multi-walled Carbon Nanotube, Polyelectrolyte and Tyrosinase (다중벽 탄소 나노 튜브, 전도성고분자 및 티로시나아제 효소로 구성된 나노복합체를 이용한 비스페놀A 맞춤형의 전기화학적 검출법)

  • Ku, Nayeong;Byeon, Ayeong;Lee, Hye Jin
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.684-689
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    • 2021
  • In this paper, we develop a cost effective and disposable voltammetric sensing platform involving screen-printed carbon electrode (SPCE) modified with the nanocomposites composed of multi-walled carbon nanotubes, polyelectrolyte, and tyrosinase for bisphenol A. This is known as an endocrine disruptor which is also related to chronic diseases such as obesity, diabetes, cardiovascular and female reproductive diseases, precocious puberty, and infertility. A negatively charged oxidized multi-walled carbon nanotubes (MWCNTs) wrapped with a positively charged polyelectrolyte, e.g., polydiallyldimethylammonium, was first wrapped with a negatively charged tyrosinae layer via electrostatic interaction and assembled onto oxygen plasma treated SPCE. The nanocomposite modified SPCE was then immersed into different concentrations of bisphenol A for a given time where the tyrosinase reacted with OH group in the bisphenol A to produce the product, 4,4'-isopropylidenebis(1,2-benzoquinone). Cyclic and differential pulse voltammetries at the potential of -0.08 V vs. Ag/AgCl was employed and peak current changes responsible to the reduction of 4,4'-isopropylidenebis(1,2-benzoquinone) were measured which linearly increased with respect to the bisphenol A concentration. In addition, the SPCE based sensor showed excellent selectivity toward an interferent agent, bisphenol S, which has a very similar structure. Finally, the sensor was applied to the analysis of bisphenol A present in an environmental sample solution prepared in our laboratory.

Improving Hot Spot Problem in Layer of DL-LEACH

  • LEE, WooSuk;Jin, Seung Yeon;Jung, Kye-Dong;Lee, Jong-Yong
    • International Journal of Internet, Broadcasting and Communication
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    • v.9 no.2
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    • pp.64-69
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    • 2017
  • The abstract should summarize the contents of the paper and written below the author information. Use th In Wide-area Wireless Sensor Networks, network lifetime is short due to energy consumption due to transmission distance. To improve this, we divide the sensor field into layers and reduce transmission distance through multi-hop transmission. However, there is a problem in that the transmission rate drops because there is no Cluster Head in the layer, or the transmission distance increases due to the layer, and energy is wasted. There are DL-LEACH and EDL-LEACH as Protocols to improve this. DL-LEACH uses either single-hop transmission or multi-hop transmission depending on the situation. As a result, the transmission distance is optimized, thereby reducing energy consumption. In case of EDL-LEACH, it is proposed to improve the data rate in DL-LEACH. It is the same as DL-LEACH, but the Cluster Head is mandatory for all layers to improve the transmission rate. Although there is no Cluster Head for each layer, the transmission rate is improved, but the network life is shortened. In this paper, we try to improve the network lifetime while maintaining the EDL-LEACH transmission rate. The shortened network lifetime is due to Cluster Head overload near the base station. To improve this, the Cluster Head distribution method is improved and the network lifetime is improved.

Effects of Multi-extracts of Mori Folium and of Exercise on Serum Lipid Profiles and Tissue Differentiation in Streptozotocin-induced Diabetic Rats

  • Ko, Young-Cheol;Seok, Hye-Jin;Song, Kyung-Hee
    • Nutritional Sciences
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    • v.6 no.4
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    • pp.209-215
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    • 2003
  • This research was performed to investigate the effects of the supplementation of multi-extracts of mori folium (MF) and of exercise on blood lipid profiles and tissue differentiation in streptozotocin (STZ)-induced diabetic rats. The animal groups consisted of a normal-control group, a STZ-control group, three STZ-induced diabetic groups supplemented ad libitum with various amounts of MF extracts (MF-720, MF-360, and MF-180 groups), and a STZ-induced diabetic group supplemented with MF-360 combined with exercise; eight male Sprague-Dawley rats, 4 weeks old, were assigned to each experimental group and were raised in the laboratory for a 10 week experimental period. The MF supplementation group showed a significant reduction in levels of serum total cholesterol and triglyceride compared to the STZ-control group. HDL-cholesterol levels were significantly increased in the MF supplementation group compared to STZ-control group. The ratio of HDL-cholesterol to total cholesterol was significantly higher in MF supplementation group compared to the STZ-control group. The Atherogenic Index (AI) values in the MF supplementation groups were found to be significantly lower than in the STZ-control group. Serum AST and ALT levels were significantly reduced in the MF-supplementation groups compared to the STZ-control group. Total cholesterol level in the liver tissue was significantly decreased in the MF-360 group and in the MF-360 + exercise group compared to the STZ-control group. In immunohistochemical staining of the pancreatic islets of the MF-supplemented groups, a significantly higher number of insulin-immunoreactive cells were observed compared to the STZ-control group. In the MF supplementation groups, Bowman's capsules were clearly observed as hypertrophy of the glomeruli was not obvious. In the MF supplementation groups, a relative reduction in the hypertrophy of the basement membrane of the glomeruli and a significant reduction in the mesangium were observed compared to the STZ-control group. The results of this study suggest that supplementation of MF has beneficial effect in improving plasma lipid and tissue metabolism in streptozotocin-induced rats.

Investigation of Herb-Drug Interactions between Korean Red Ginseng Extract and five CYP Substrates by LC-MS/MS

  • Jo, Jung Jae;Lee, Sangkyu
    • Mass Spectrometry Letters
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    • v.8 no.4
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    • pp.98-104
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    • 2017
  • Ginseng (Panax ginseng Meyer) is a well-known health functional food used as a traditional herbal drug in Asian countries owing to its diverse pharmacological effects. Herb-drug interactions may cause unexpected side effects of co-administered drugs by the alteration of pharmacokinetics through effects on cytochrome P450 activity. In this study, we investigated the herb-drug interactions between Korean red ginseng extract (KRG) and five CYP-specific probes in mice. The pharmacokinetics of KRG extract induced-drug interactions were studied by cassette dosing of five CYP substrates for CYP1A, 2B, 2C, 2D, and 3A and the LC-MS/MS analysis of the blood concentration of metabolites of each of the five probes. The linearity, precision, and accuracy of the quantification method of the five metabolites were successfully confirmed. The plasma concentrations of five metabolites after co-administration of different doses of the KRG extract (0, 0.5, 1, and 2 g/kg) were quantified by LC-MS/MS and dose-dependent pharmacokinetic parameters were determined. The pharmacokinetic parameters of the five metabolites were not significantly altered by the dose of the KRG extract. In conclusion, the single co-administration of KRG extract up to 2 g/kg in vivo did not cause any significant herb-drug interactions linked to the modulation of CYP activity.