• Proceedings of the SAREK Conference
• /
• 2006.06a
• /
• pp.429-435
• /
• 2006

In this study multi-zone modeling program CONTAM 2.4 which is developed by NIST is used for modeling the air disinfection system which is consist of dilution, filtration, ultra violet germicidal irradiation (UVGI) for removing the indoor microorganism such as bacteria and fungus. Developed models those protect occupants against indoor microorganism generated in our daily life are enable to use for immune building simulation tool. Also, results indicate that those models are enable to compute the real situation that is almost impossible of carrying out experiment and identify the disinfection rate with highly reliance. Results also suggest that engineers will use these models as a design tool for the immune building system.

• Korean Journal of Materials Research
• /
• v.28 no.1
• /
• pp.68-74
• /
• 2018

Cobalt-incorporated zeolitic imidazolate framework ZIF-8 was synthesized by a simple one-pot synthesis method at room temperature. Powder X-ray diffraction patterns and energy dispersive X-ray spectrum confirmed the formation of the bimetallic Co/Zn-ZIF structure. UV-Vis diffuse reflectance spectra revealed that the bimetallic ZIF had a lower HOMO-LUMO gap compared with ZIF-8 due to the charge transfer process from organic ligands to cobalt centers. A hydrolytic stability test showed that Co/Zn-ZIF is very robust in aqueous solution - the most important criterion for any material to be applied in photodegradation. The photocatalytic efficiency of the synthesized samples was investigated over the Indigo Carmine (IC) dye degradation under solar simulated irradiation. Cobalt incorporated ZIF-8 exhibited high efficiency over a wide range of pH and initial concentration. The degradation followed through three distinct stages: a slow initial stage, followed by an accelerated stage and completed with a decelerated stage. Moreover, the photocatalytic performance of the synthesized samples was highly improved in alkaline environment rather than in acidic or neutral environments, which may have been because in high pH medium, the increased concentration of hydroxyl ion facilitated the formation of hydroxyl radicals, a reactive species responsible for the breaking of the Indigo Carmine structure. Thus, Co/Zn-ZIF is a promising and green material for solving the environmental pollution caused by textile industries.

• Journal of the Korean Solar Energy Society
• /
• v.27 no.2
• /
• pp.19-27
• /
• 2007

The previous study was conducted to develop an air source multi heat pump system that could be operated with the solar collector and air source heat exchangers as heat source of the system. There is a winter-sowing problems in air source multi heat pump system when the outdoor temperature goes down under freezing point. The winter-sowing problem was solved by adapting R-22 refrigerant as working fluid in the previous study. However, when the system operated at high temperature, another problems are come out such as overheating of the solar collector outlet which lead to the superheat of the compressor inlet of the heat pump system. The condition could deteriorates a compressor in some case. In this study, we installed the anti-superheating devices on the previously developed system. As results of system performance test, COP of the system with anti-superheating technique is 2.4. It is a little improved COP compare to previous study's 2.23. In the results of multi heat source heating system, during operating solar collector, COP is relatively high between $200\;W/m^2$ and $400\;W/m^2$ solar intensity. It is recommended to extend the study on performance optimization with balancing the solar collect and capacity of compressor at higher solar irradiation conditions.

• Radiation Oncology Journal
• /
• v.9 no.2
• /
• pp.343-350
• /
• 1991

The quasi-conformation therapy was performed to get a homogeneous dose distributions for irregeular shaped tumor lesion by using the arc moving beam and beam modifying filter which was made by cerrobend alloy($\rho$=9.4 g/cc) metal. In our dose calcuation programme, it was fundmentally based on Clarkson's method to calcuate the irregular multi-step block field in rotation therapy. In this study, the expected relative depth doses under multipartial attenuator agree well with measured data at same plane. The results of comparison the dose computation with that of TLD measurement are very closed within ${\pm}5\%$ uncertainties in the irradiation to phantom with quasi-comformation method. And it has shown that irregular typed multi-step filter can be applied to quasi-conformation therapy in high energy radiation plannings.

• Nuclear Engineering and Technology
• /
• v.51 no.5
• /
• pp.1406-1416
• /
• 2019

In this research, a multi-slit prompt-gamma camera was developed to locate the distal dose falloff of the proton beam spots in spot scanning proton therapy. To see the performance of the developed camera, therapeutic proton beams were delivered to a solid plate phantom and then the prompt gammas from the phantom were measured using the camera. Our results show that the camera locates the 90% distal dose falloff (= d90%), within about 2-3 mm of error for the spots which are composed $3.8{\times}10^8$ protons or more. The measured location of d90% is not very sensitive to the irradiation depth of the proton beam (i.e., the depth of proton beam from the phantom surface toward which the camera is located). Considering the number of protons per spot for the most distal spots in typical treatment cases (i.e., 2 Gy dose divided in 2 fields), the camera can locate d90% only for a fraction of the spots depending on the treatment cases. However, the information of those spots is still valuable in that, in the multi-slit prompt-gamma camera, the distal dose falloff of the spots is located solely based on prompt gamma measurement, i.e., not referring to Monte Carlo simulation.

• Journal of the Korean Ceramic Society
• /
• v.56 no.1
• /
• pp.98-103
• /
• 2019

Optical filters to control light wavelength of displays or cameras are fabricated by multi-layer stacking process of low and high index thin films. The process of multi-layer stacking of thin films has received much attention as an optimal process for effective manufacturing in the optical filter industry. However, multi-layer processing has disadvantages of complicated thin film process, and difficulty of precise control of film morphology and material selection, all of which are critical for transmittance and coloring effect on filters. In this study, the composite $TiO_2$, which can be used to control of UV absorption, coated on nano hollow silica sol, was synthesized as a coating material for optical filters. Furthermore, systematic analysis of the process parameters during the chemical reaction, and of the structural properties of the coating solutions was performed using SEM, TEM, XRD and photo spectrometry. From the structural analysis, we found that the 85 nm nano hollow silica with 2.5 nm $TiO_2$ shell formation was successfully synthesized at proper pH control and titanium butoxide content. Photo luminescence characteristics, excited by UV irradiation, show that stable absorption of 350 nm-light, correlated with a 3.54 eV band gap, existed for the $TiO_2$ shell-nano hollow silica reacted with 8.8 mole titanium butoxide solution. Transmittance observed on substrate of the $TiO_2$ shell-nano hollow silica showed effective absorption of 200-300 nm UV light without deterioration of visible light transparency.

• Korean Journal of Materials Research
• /
• v.20 no.7
• /
• pp.345-350
• /
• 2010

For the present paper, we prepared MgO/MWCNT/$TiO_2$ photocatalyst by using multi-walled carbon nanotubes (MWCNTs) pre-oxidized by m-chlorperbenzoic acid (MCPBA) with magnesium acetate tetrahydrate $(Mg(CH_2COO)_2\cdot4H_2O)$ and titanium n-butoxide $(Ti\{OC(CH_3)_3\}_4)$ as magnesium and titanium precursors. The prepared photocatalyst was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis. The decomposition of methylene blue (MB) solution was determined under irradiation of ultraviolet (UV) light. The XRD results show that the MgO/MWCNT/$TiO_2$ photocatalyst have cubic MgO structure and anatase $TiO_2$ structure. The porous structure and the $TiO_2$ agglomerate coated on the MgO/MWCNT composite can be observed in SEM images. The Mg, O, Ti and C elements can be also observed in MgO/MWCNT/$TiO_2$ photocatalyst from EDX results. The results of photodegradation of MB solution under UV light show that the concentration of MB solution decreased with an increase of UV irradiation time for all of the samples. Also, the MgO/MWCNT/$TiO_2$ photocatalyst has the best photocatalytic activity among these samples. It can be considered that the MgO/MWCNT/$TiO_2$ photocatalyst had a combined effect, the effect of MWCNT, which could absorb UV light to create photoinduced electrons $(e^-)$, and the electron trapping effect of MgO, which resulted in an increase of the photocatalytic activity of $TiO_2$.

• Journal of Powder Materials
• /
• v.23 no.6
• /
• pp.458-465
• /
• 2016

A $TiO_2$/CNT nanohybrid photocatalyst is synthesized via sol-gel route, with titanium (IV) isopropoxide and multi-walled carbon nanotubes (MWCNTs) as the starting materials. The microstructures and phase constitution of the nanohybrid $TiO_2$/CNT (0.005wt%) samples after calcination at $450^{\circ}C$, $550^{\circ}C$ and $650^{\circ}C$ in air are compared with those of pure $TiO_2$ using field-emission scanning electron microscopy and X-ray diffraction, respectively. In addition, the photocatalytic activity of the nanohybrid is compared with that of pure $TiO_2$ with regard to the degradation of methyl orange under visible light irradiation. The $TiO_2$/CNT composite exhibits a fast grain growth and phase transformation during calcination. The nanocomposite shows enhanced photocatalytic activity under visible light irradiation in comparison to pure $TiO_2$ owing to not only better adsorption capability of CNT but also effective electron transfer between $TiO_2$ and CNTs. However, the high calcination temperature of $650^{\circ}C$, regardless of addition of CNT, causes a decrease in photocatalytic activity because of grain growth and phase transformation to rutile. These results such as fast phase transformation to rutile and effective electron transfer are related to carbon doping into $TiO_2$.

• Elastomers and Composites
• /
• v.45 no.1
• /
• pp.25-31
• /
• 2010

We used activated carbon (AC), activated carbon fiber (ACF) and multi-walled carbon nanotube (MWCNT) as carbon sources and titanium n-butoxide as titanium source to prepare carbon-$TiO_2$ composites. For characterization their properties, scanning electron microscopy (SEM), transmission electron microscopy (TEM), BET surface area, X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDX) were used. And the photoactivity of the carbon-$TiO_2$ composites, under UV irradiation, was tested using the fixed concentration of methylene blue (MB, $C_{16}H_{18}N_3S{\cdot}Cl{\cdot}3H_2O$) in aqueous solution. After UV irradiation for a certain time, the concentration of MB solution was determined by UV-vis absorption spectroscopy.

• Nuclear Engineering and Technology
• /
• v.35 no.4
• /
• pp.356-368
• /
• 2003

Material properties such as coolant specific heat, film heat transfer coefficient, cladding thermal conductivity, surface diffusion coefficient of the multi-bubble are improved in MACSIS-Mod1. The axial power and flux profile module was also incorporated with irradiation history. The performance and feasibility of the updated driver fuel pin have been analyzed for nominal parameters based on the conceptual design for the KALIMER breakeven core by MACSIS-MOD1 code. The fuel slug centerline temperature takes the maximum at 700mm from the bottom of the slug in spite of the nearly symmetric axial power distribution. The cladding mid-wall and coolant temperatures take the maximum at the top of the pin. Temperature of the fuel slug surface over the entire irradiation life is much lower than the fuel-clad eutectic reaction temperature. The fission gas release of the driver fuel pin at the end of life is predicted to be $68.61\%$ and plenum pressure is too low to cause cladding yielding. The probability that the fuel pin would fail is estimated to be much less than that allowed in the design criteria. The maximum radial deformation of the fuel pin is $1.93\%$, satisfying the preliminary design criterion ($3\%$) for fuel pin deformation. Therefore the conceptual design parameters of the driver fuel pin for the KALIMER breakeven core are expected to satisfy the preliminary criteria on temperature, fluence limit, deformation limit etc.