• Title/Summary/Keyword: Monotonously increasing

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$NO_x$ Sensing Characteristic of $TiO_2$ Thin Film Deposited by R.F Magnetron Sputtering (R.F 마그네트론 스퍼트링으로 작성된 $TiO_2$박막의 $NO_x$ 감지 특성)

  • 고희석;박재윤;박상현
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.12
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    • pp.567-572
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    • 2002
  • In these days, diesel vehicle or power plant emits $NO_X\; and SO_2$ which cause air pollution like acid-rain, ozone layer destroy and optical smoke, therefore there are many kinds of methods considered for removing them such as SCR, catalyst, plasma process, and plasma-catalyst hybrid process. T$TiO_2$ is commonly used as catalyst to remove $NO_X$ gas because it have very excellent chemical characteristic as photo catalyst. In this paper, $NO_X$ sensing characteristic of $TiO_2$ thin film deposited by R.F Magnetron sputtering is investigated. A finger shaped electrode on $Al_2$O$_3$ substrate is designed and $TiO_2$ is deposited on the electrode by the magnetron sputtering deposition system. Chemical composition of the deposited $TiO_2$ thin film is $TiO_{1.9}$ by RBS analysis. When the UV is irradiated on it with flowing air, capacitance of $TiO_2$ thin film increases, however, when NO gas is put into the system with air, it immediately decreases because of photo chemical reaction. and it monotonously decreases with increasing NO concentration.

An experimental study on the dynamic behavior in an aero-valved pulsating combustor (공기밸브형 맥동연소기의 동적 특성에 관한 실험적 연구)

  • 임광열;최병륜;오상헌
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.5
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    • pp.846-855
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    • 1987
  • The experimental study was carried out to investigate the performance characteristics of the aero-valved pulsating combustor designed to increase the practical applications of the system. The geometric effect on the stable condition and the dynamic behavior of the system is identified. The equivalence ratio, the inflammability limit, the operating frequency, and thrust were also measured when the system oscillated stably. It is found that while the operating condition is sensitive to the diameter of the inlet pipe and the length of the tailpipe, the maximum value of the turn down ratio was obtained up to 3.2. The measured air flow rate shows that the equivalence ratio increases monotonously with the increasing fuel flow rate and decreasing air inlet diameter and tailpipe length. The measured operating frequency can be approximated by the simple linear equation and the discrepancy is within five percent. The system produced the maximum total thrust of 14N and the minimum specific fuel consumption of 0.155 Nm$^{3}$/h.N when the total thrust was 13N.

Viscosities of LaCl3-CsCl Binary Melts (LaCl3-CsCl 2성분계 용융염의 점도)

  • Kim, Kiho
    • Journal of the Korean institute of surface engineering
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    • v.46 no.2
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    • pp.87-92
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    • 2013
  • Viscosities of $LaCl_3$-CsCl binary melts were measured by the capillary method over the range of their liquidus temperatures to about 1200 K. The cell constant were determined by using pure water. The results obtained are summerized as follows: Viscosities of melted $LaCl_3$ were decreased with the content of CsCl for all over the composition range of binary melts. Composition versus viscosity relation for the binary melt showed a non-linear relationship from the additivity line and the deviations showed a maximum value at about 60 mol% CsCl. This suggest the existence of the complex ion of $LaCl_4{^-}$ in the melt. Activation energy for the viscous flow of the binary melts decreased monotonously with the increasing content of CsCl after a few increasement till 40 mol% CsCl. All of these results were the resemble with the viscosities of $LaCl_3$-NaCl binary melts.

Improvement of carrier transport in silicon MOSFETs by using h-BN decorated dielectric

  • Liu, Xiaochi;Hwang, Euyheon;Yoo, Won Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.97-97
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    • 2013
  • We present a comprehensive study on the integration of h-BN with silicon MOSFET. Temperature dependent mobility modeling is used to discern the effects of top-gate dielectric on carrier transport and identify limiting factors of the system. The result indicates that coulomb scattering and surface roughness scattering are the dominant scattering mechanisms for silicon MOSFETs at relatively low temperature. Interposing a layer of h-BN between $SiO_2$ and Si effectively weakens coulomb scattering by separating carriers in the silicon inversion layer from the charged centers as 2-dimensional h-BN is relatively inert and is expected to be free of dangling bonds or surface charge traps owing to the strong, in-plane, ionic bonding of the planar hexagonal lattice structure, thus leading to a significant improvement in mobility relative to undecorated system. Furthermore, the atomically planar surface of h-BN also suppresses surface roughness scattering in this Si MOSFET system, resulting in a monotonously increasing mobility curve along with gate voltage, which is different from the traditional one with a extremum in a certain voltage. Alternatively, high-k dielectrics can lead to enhanced transport properties through dielectric screening. Modeling indicates that we can achieve even higher mobility by using h-BN decorated $HfO_2$ as gate dielectric in silicon MOSFETs instead of h-BN decorated $SiO_2$.

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Effect of carbonization temperature on crystalline structure and properties of isotropic pitch-based carbon fiber

  • Kim, Jung Dam;Roh, Jae-Seung;Kim, Myung-Soo
    • Carbon letters
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    • v.21
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    • pp.51-60
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    • 2017
  • Isotropic pitch-based fibers produced from coal tar pitch with the melt-blowing method were carbonized at temperatures ranging from 800 to $1600^{\circ}C$ to investigate their crystalline structure and physical properties as a function of the carbonization temperature. The in-plane crystallite size ($L_a$) of the carbonized pitch fiber from X-ray diffraction increased monotonously by increasing the carbonization temperature resulting in a gradual increase in the electrical conductivity from 169 to 3800 S/cm. However, the variation in the $d_{002}$ spacing and stacking height of the crystallite ($L_c$) showed that the structural order perpendicular to the graphene planes got worse in carbonization temperatures from 800 to $1200^{\circ}C$ probably due to randomization through the process of gas evolution; however, structural ordering eventually occurred at around $1400^{\circ}C$. For the carbonized pitch powder without stabilization, structural ordering perpendicular to the graphene planes occurred at around $800-900^{\circ}C$ indicating that oxygen was inserted during the stabilization process. Additionally, the shear stress that occurred during the melt-blowing process might interfere with the crystallization of the CPF.

General picture of co-nonsolvency for linear and ring polymers

  • Park, Gyehyun;Lee, Eunsang;Jung, YounJoon
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.147-154
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    • 2016
  • Co-nonsolvency is a puzzling phenomenon that a polymer swells in a good solvent individually, but it collapses in a mixture of good solvents. This structural transition with changing solvent environment has been drawing attention due to practical application for stimuli-responsive polymer. The aim of this work is to describe the physical origin of the co-nonsolvency. In this work, we present Monte Carlo simulations for polymer solutions by using simple and general model. We simulate linear and ring polymers to compare their co-nonsolvency behaviors. Calculating Flory exponents and bridging fractions gives a good description for polymer structures. While the polymer structure shows non-monotonous behavior with increasing the cosolvent fraction, the chemical potential decreases monotonously. This indicates that coil-to-globule transition of polymers is purely controlled by free energy and can be regarded as a thermodynamics transition. We also present that ring polymers have higher looping probability than linear polymers, thus the bridging fraction remains higher at high cosolvent fraction. Our study provides a new perspective to understand polymer structure when the polymer "dissolves well" in any solvent.

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A Case Study on Evaluation of Educational Space in point of Universal Design - Focused on G Elementary School - (교육공간에 대한 유니버설 디자인 관점에서의 평가 사례연구(1) - G초등학교 사례를 중심으로 -)

  • Oh, Chan-Ohk;Park, Jin-Kyung
    • Korean Institute of Interior Design Journal
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    • v.21 no.5
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    • pp.12-22
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    • 2012
  • The demand on design for human diversity is increasing in the field of spatial design. This study evaluated the spatial environment of G elementary school in point of universal design. The study was carried out by the observing and measuring method and the survey method. It focused on 53 universal design related items which consisted of 5 principles; accessibility, supportiveness, adaptiveness, safety, and equality. The subjects for the survey were 170 students from first to sixth grade of G elementary school. Findings were as follows ; 1) The elementary school had many barriers for the wheelchair users to use. 2) The width of door and passage between desks, and the front and back space in classroom were not wide to pass through. Also, the students responded that the size of desk, chair, and individual locker was not enough. That is, Some items of accessibility and supportiveness were not met in classrooms. 3) Most items related to restroom were evaluated negatively by the students. 4) The dining tables were arranged monotonously in a rows. This emphasized the institutional mood. 5) Some evaluations to their school environment were significantly different by their gender and grade.

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Mechanical Properties of Polypropylene/Talc Composites Prepared via Solid-State Extrusion (고상 압출된 폴리프로필렌/탈크 복합재료의 기계적 물성)

  • Lee, Jaechoon;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.17 no.4
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    • pp.131-135
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    • 2016
  • We investigated the specific gravity and mechanical property changes of solid-state extruded polypropylene (PP)/talc composites before and after orientation. The specific gravity of the composites increases with increasing the filler contents. The specific gravity of the oriented specimen containing filler in PP matrix is found to be much smaller than that of pre-specimen due to the formation of more micro-voids. It was found that the tensile properties of the composites are increased up to the talc content of 10 wt%, but after the contents exceeding 10 wt%, the tensile properties are decreased. For oriented specimens, the tensile strength of the composites showed monotonously decrease with increasing talc contents. When the contents of talc is 10 wt%, the theoretical values according to Halpin-Tsai equation are close to the experimental values but over 20 wt% of talc contents, the deviation of the experimental values from the theoretical prediction becomes higher. The maximum flexural strength and modulus were observed for PP/talc composites when the talc contents was 10 wt% for both pre-specimen and oriented specimen.

Deformation Property of TiC-Mo Solid Solution Single Crystal at High Temperature by Compression Test (TiC-Mo 고용체 단결정의 고온 압축변형 특성)

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.24 no.11
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    • pp.625-631
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    • 2014
  • To investigate the deformation properties of TiC-(5-20) mol% Mo solid solution single crystals at high temperature by compression testing, single crystals of various compositions were grown by the radio frequency floating zone technique and were deformed by compression at temperature from 1250K to 2270K at strain rates from $5.1{\times}10^{-5}$ to $5.9{\times}10^{-3}/s$. The plastic flow property of solid solution single crystals was found to be clearly different among a three-temperature range (low, intermediate and high temperature ranges) whose boundaries were dependent on the strain rate. From the observed property, we conclude that the deformation in the low temperature range is controlled by the Peierls mechanism, in the intermediate temperature range by the dynamic strain aging and in the high temperature range by the solute atmosphere dragging mechanism. The work softening tends to become less evident with an increasing experimental temperature and with a decreasing strain rate. The temperature and strain rate dependence of the critical resolved shear stress is the strongest in the high temperature range. The curves are divided into three parts with different slopes by a transition temperature. The critical resolved shear stress (${\tau}_{0.2}$) at the high temperature range showed that Mo content dependence of ${\tau}_{0.2}$ with temperature and the dependence is very marked at lower temperature. In the higher temperature range, ${\tau}_{0.2}$ increases monotonously with an increasing Mo content.

Physical Properties of Fe Particles Fine-dispersed in AlN Thin Films (Fe 입자를 미세 분산 시킨 AlN 박막의 물리적 성질)

  • Han, Chang-Suk;Kim, Jang-Woo
    • Korean Journal of Materials Research
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    • v.21 no.1
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    • pp.28-33
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    • 2011
  • This paper describes the fabrication of AlN thin films containing iron and iron nitride particles, and the magnetic and electrical properties of such films. Fe-N-Al alloy films were deposited in Ar and $N_2$ mixtures at ambient temperature using Fe/Al composite targets in a two-facing-target DC sputtering system. X-ray diffraction results showed that the Fe-N-Al films were amorphous, and after annealing for 5 h both AlN and bcc-Fe/bct-$FeN_x$ phases appeared. Structure changes in the $FeN_x$ phases were explained in terms of occupied nitrogen atoms. Electron diffraction and transmission electron microscopy observations revealed that iron and iron nitride particles were randomly dispersed in annealed AlN films. The grain size of magnetic particles ranged from 5 to 20 nm in diameter depending on annealing conditions. The saturation magnetization as a function of the annealing time for the $Fe_{55}N_{20}Al_{25}$ films when annealed at 573, 773 and 873 K. At these temperatures, the amount of iron/iron nitride particles increased with increasing annealing time. An increase in the saturation magnetization is explained qualitatively in terms of the amount of such magnetic particles in the film. The resistivity increased monotonously with decreasing Fe content, being consistent with randomly dispersed iron/iron nitride particles in the AlN film. The coercive force was evaluated to be larger than $6.4{\times}10^3Am^{-1}$ (80 Oe). This large value is ascribed to a residual stress restrained in the ferromagnetic particles, which is considered to be related to the present preparation process.