• 한국재료학회지
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• 제20권3호
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• pp.167-173
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• 2010

In this study, we used activated carbon (AC) and titanium oxysulfate as a titanium precursor to prepare carbon/titania composites. We then mixed it with bentonite in different ratios to make a carbon/titania/bentonite monolith for use in architecture bricks by using Phenolic rosin (PR) as a bonding agent. The physicochemical properties of the prepared composites were analyzed by BET surface area, scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX), self-cleaning effect and bactericidal tests. The BET surface areas increased as the ratio of carbon/titania composites increased. The SEM microscopy showed that the $TiO_2$ and bentonite were coated on the surface of the AC. The XRD patterns showed a mixture structure of anatase and rutile of $TiO_2$ with a clear $SiO_2$ structure. The EDX spectra of the carbon/titania/bentonite monolith confirmed the presence of various elements, namely C, O, Ti and Si, as well as other, impure elements. Moreover, to determine the self-cleaning effect of the carbon/titania/bentonite monolith, we used methylene blue (MB, $C_{16}H_{18}N_3S{\cdot}Cl{\cdot}3H_2O$) in an aqueous solution under the irradiation of visible light. Accordingly, all of the samples had excellent degradation of the MB solution. Furthermore, it was observed that the composites with sunlight irradiation had a greater effect on E. coli than any other experimental conditions.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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• pp.181-186
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• 2004

Catalytic combustion is one of the suitable methods which is applicable to micro heat source due to high energy density and no flame quenching. And hydrogen can be oxidized at room temperature with platinum catalyst. So hydrogen-fueled micro catalytic combustor with platinum catalyst can be good and easy-handling heat source for another micro devices. In this work we focused on general catalytic combustion characteristics of hydrogen-air premixed gas in 10mm scale catalytic combustor for the further application to micro scale. Platinum was coated on dense ceramic monolith which can be installed in simple-structured catalytic combustor. We investigated the effect of flow rate, heat loss and platinum percentage in catalyst-coated monolith on catalytic combustion performance by temperature distribution in the combustor. By those results we confirmed catalytic reactivity and estimated reaction area. And we simulated micro scale catalytic reaction by sliced monolith. The results of this work will be important design factors for micro scale catalytic combustor.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2651-2656
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• 2012

Sulfonated cellulose tris(3,5-dimethylphenylcarbamate) (SCDMPC)-coated zirconia monolith (ZM) was used as the chiral stationary phase in capillary electrochromatography for separation of enantiomers of ten chiral compounds in acetonitrile (ACN)-phosphate buffer mixtures as the eluent. Influences of the ACN content, buffer concentration and pH on chiral separation have been investigated. Separation data on SCDMPC-ZM have been compared with those on CDMPC-ZM. Resolution factors were better on SCDMPC-ZM than CDMPC-ZM while retention factors were in general shorter on the former than the latter. Best chiral resolutions on SCDMPC-ZM were obtained with the eluent of 50% ACN containing 50 mM phosphate at pH around 4.

• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1809-1813
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• 2013

Sulfated ${\beta}$-cyclodextrin (SCD)-coated zirconia monolith was used as the chiral stationary phase in capillary electrochromatography for enantiomeric separation of basic chiral compounds. SCD adsorbed on the zirconia surface provided a stable chiral stationary phase in reversed-phase eluents. Retention, chiral selectivity and resolution of a set of six basic chiral compounds were measured in eluents of varying pH, composition of methanol and buffer. Optimum mobile phase condition for the separation of the compounds was found to be methanol content of 30%, buffer concentration of 30 mM and pH of 4.0.

• 한국자동차공학회논문집
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• 제11권5호
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• pp.77-82
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• 2003

A parametric study was conducted on pressure drop in a catalytic converter for automobile. In this work, we proposed a new pressure drop relation which contains the various parameters needed to calculate and got a few results. In a monolith of catalyst, the flow originally turbulent flow changes to laminar flow and thus the pressure drop through the monolith is linearly proportional to the velocity. The exhaust pressure is doubly affected by the increase of mean velocity and length when we decrease the diameter of monolith while the volume keeps constant. Theoretical parameters such as $\alpha$ and $\beta$ are suggested to use as a reference value when there is no a experimental data. Especially in the part load test, these values should be modified to consider the property change of exhaust gas.

• 한국자동차공학회논문집
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• 제3권6호
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• pp.41-54
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• 1995

A mathematical model for wall-flow monolith ceramic diesel particulate filter was developed in order to describe the processes which take place in the filter during regeneration. The major output of the model comprises ceramic wall temperature and regeneration time(soot reduction). Various numerical tests were performed to demonstrate how the gas oxygen concentration, flow rate and the initial particulate trap loading affect the regeneration time and peak trap temperature. The model is shown to b in reasonable agreement with the published experimental results. This model can be applied to predict the thermal shock failure due to high temperature during combustion regeneration process.

• 한국자동차공학회논문집
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• 제9권3호
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• pp.76-83
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• 2001

An experimental investigation has been performed on the steady flow in exhaust system. When individual flow coming from exhaust manifold entered UCC, the inlet conditions at entry to the diffuser in UCC were affected by the upstream pipe and manifold works. But those effects of the inlet condition on flow through monolith are negligible because the flows are concentrated on the center of monolith regardless of inlet flow distribution. To improve the flow distribution, we installed the cone type circular ring in diffuser of UCC. This led to increasement of flow uniformity, but there was minor increment of pressure drop.

• 청정기술
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• 제27권4호
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• pp.332-340
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• 2021

최근 사업장 질소산화물(NOx) 배출허용기준 강화(2019년 1월 적용)에 따라 다량 배출사업장에서 배출되는 질소산화물을 배출허용기준 이하로 만족하기 위한 노력이 필요하다. 대표적인 질소산화물 저감 방법으로 선택적 촉매 환원법(selective catalytic reduction, SCR)을 주로 사용하고 있으며, 일반적으로 세라믹 허니컴(ceramic honeycomb) 촉매를 사용하고 있다. 본 연구에서는 높은 열적 안정성과 기계적 강도를 가지는 금속지지체 탈질 코팅촉매를 적용하여 제철소에서 배출되는 질소산화물를 저감하기 위한 연구를 수행하였다. 금속지지체 코팅촉매는 최적화된 촉매슬러리(catalyst slurry) 코팅방법을 통해 제조하였고, 내마모 시험과 굽힙 시험을 통해 코팅된 촉매가 균일하고 강건하게 부착되어 있음을 확인하였다. 금속지지체가 가지는 우수한 열전도 특성으로 인해 저온영역(200 ~ 250 ℃)에서 세라믹 허니컴 촉매보다도 우수한 탈질효율을 보였다. 또한 경제적인 촉매 설계를 위해 금속지지체 표면 상에 코팅되는 촉매의 최적 코팅량을 확인하였다. 이러한 연구결과를 바탕으로 제철소 배기가스 모사환경에서 상용급 금속지지체 코팅촉매에 대한 준파일럿 탈질 성능평가를 수행하였고, 저온영역(220 ℃)에서도 배출허용기준치(60 ppm 이하)을 만족하는 우수한 성능을 나타내었다. 따라서 물리화학적 특성이 우수한 금속지지체 코팅촉매가 최소량의 촉매 사용으로도 우수한 탈질 성능을 나타내었으며, 넓은 비표면적을 가지는 고밀도 금속지지체 적용을 통해 배연 탈질 촉매 반응기의 콤팩트화 및 소형화가 가능하였다. 이러한 결과를 바탕으로, 본 연구에서 사용된 금속지지체 코팅촉매는 제철소뿐만 아니라 화력발전, 소각장, 선박, 건설기계 등 다양한 산업 분야에 적용할 수 있는 새로운 형태의 촉매가 될 것이다.

• Bulletin of the Korean Chemical Society
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• 제25권10호
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• pp.1589-1592
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• 2004

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2003년도 가을 학술논문집
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• pp.168-171
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• 2003

조사재시험시설(IMEF : Irradiated Materials Examination Facility)은 원자력연구소 부지 내에 위치하고 있는 핫셀 시험시설로써, 하나로 연구용 원자로 및 상용 원자력발전소에서 중성자에 조사한 사용후핵연료 및 구조재료 등의 조사특성에 대한 시험 및 평가를 수행하고 있다. 따라서 핫셀 내부에서 시험을 완료한 고준위 고체폐기물들은 시설의 고유기능을 지속적으로 수행하기 위해서 정기적으로 핫셀 외부로 반출 및 원자력연구소 부지내의 저장시설에 옮겨 처리해야 한다. 시설준공(1993년 말) 후 현재까지 고준위폐기시설인 모노리스(monolith)로 반출 및 처리한 물량은 50리터용 폐기물처리용 통(bin)으로 약 30개이며, 해마다 그 양이 늘어나고 있는 추세이다. 본 논문에서는 조사재시험시설의 핫셀에서 고준위폐기시설인 모노리스(monolith)까지의 일련의 반출 및 처리에 대한 절차 및 작업내용을 간략하게 기술하고자 한다.