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http://dx.doi.org/10.5012/bkcs.2012.33.8.2651

Chiral Separation on Sulfonated Cellulose Tris(3,5-dimethylphenylcarbamate)-coated Zirconia Monolith by Capillary Electrochromatography  

Lee, Jeong-Mi (Department of Chemistry, Yeungnam University)
Jang, Myung-Duk (Department of Gas Energy Engineering, Kundong University)
Park, Jung-Hag (Department of Chemistry, Yeungnam University)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.8, 2012 , pp. 2651-2656 More about this Journal
Abstract
Sulfonated cellulose tris(3,5-dimethylphenylcarbamate) (SCDMPC)-coated zirconia monolith (ZM) was used as the chiral stationary phase in capillary electrochromatography for separation of enantiomers of ten chiral compounds in acetonitrile (ACN)-phosphate buffer mixtures as the eluent. Influences of the ACN content, buffer concentration and pH on chiral separation have been investigated. Separation data on SCDMPC-ZM have been compared with those on CDMPC-ZM. Resolution factors were better on SCDMPC-ZM than CDMPC-ZM while retention factors were in general shorter on the former than the latter. Best chiral resolutions on SCDMPC-ZM were obtained with the eluent of 50% ACN containing 50 mM phosphate at pH around 4.
Keywords
Chiral separation; Zirconia monolith; Sulfonated cellulose 3,5-dimethylphenylcarbamate; Capillary electrochromatography;
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