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http://dx.doi.org/10.5012/bkcs.2013.34.6.1809

Chiral Separation of Basic Compounds on Sulfated β-Cyclodextrin-Coated Zirconia Monolith by Capillary Electrochromatography  

Hong, Jong-Seong (Department of Chemistry, Yeungnam University)
Park, Jung Hag (Department of Chemistry, Yeungnam University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.6, 2013 , pp. 1809-1813 More about this Journal
Abstract
Sulfated ${\beta}$-cyclodextrin (SCD)-coated zirconia monolith was used as the chiral stationary phase in capillary electrochromatography for enantiomeric separation of basic chiral compounds. SCD adsorbed on the zirconia surface provided a stable chiral stationary phase in reversed-phase eluents. Retention, chiral selectivity and resolution of a set of six basic chiral compounds were measured in eluents of varying pH, composition of methanol and buffer. Optimum mobile phase condition for the separation of the compounds was found to be methanol content of 30%, buffer concentration of 30 mM and pH of 4.0.
Keywords
Chiral separation; Capillary electrochromatography; Zirconia monolith; Sulfated ${\beta}$-cyclodextrin;
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