• 제목/요약/키워드: Mole Fraction

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Hexane Vapor Concentration Measurement of a Liquid Jet in Crossflow (수직분사제트에서의 헥산 증기농도측정)

  • Oh, Jeong-Seog;Lee, Won-Nam;Lee, Jong-Geun;Santavicca, Dominique A.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.05a
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    • pp.383-389
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    • 2010
  • The vapor concentration of hexane in a liquid spray jet in crossflow was qualitatively measured on the basis of the infrared (IR) extinction techniques. The objectives of the present study are to understand the whole evaporation process from droplet breakup to vapor and to confirm the usefulness of IR emission method in a lab-scale ramjet combustor. From the experimental results, we concluded that hexane vapor mole fraction increased with temperature rise and kept nearly constant during the variation of fuel to air momentum ratio.

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Alkali Volatilization in TV Screen Glass Melts

  • Kim, Ki-Dong;Hwang, Jong-Hee
    • The Korean Journal of Ceramics
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    • v.6 no.4
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    • pp.343-347
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    • 2000
  • The alkali volatilization of TV screen glass melts with various $K_2$O/R$_2$O mole fraction was investigated by dependence of weight loss on time. The melt conductivity was also determined to evaluate relative alkali diffusion in melts. Based on the results of time dependence and compositional dependence of volatilization combining the results of conductivity, the rate determining process of the volatilization was suggested. From the viewpoint of the production and the application of TV glass it was also discussed a correlation between the dependence of properties on $K_2$O/R$_2$O and the present commercial composition.

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An Analysis of the Phase Diagram fo the Crystal Growth of InGaAsP/GaAs in the Visible Region (가시광 InGaAsP/GaAs 결정성장을 위한 상평형도 해석)

  • Hong, Tchang-Hee;Cho, Ho-Sung;Oh, Jong-Hwan;Yea, Beyong-Deok;Hwang, Sang-Ku;Bea, Jung-Chul
    • Journal of the Korean Institute of Navigation
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    • v.15 no.3
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    • pp.99-106
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    • 1991
  • In order to grow InGaAsP epitaxial layer on GaAs by LPE, an accurate phase diagram for In-Ga-As-P quarternary compounds is required. But the short wavelength InGaAsP/GaAs phase diagram for full wavelength range was not yet reported. In this study, therefore, a theoretical calculation has been carried out by using thermodynamic's equation for InGaAsP/GaAs in order to get the relation between the mole fraction of the sloute and solid phase compounds. And the calculation being compared with the dta of Kawanishi et. al, the result has been shown that his phase diagram obtained by the calculation can apply to growing InGaAsP/GaAs by LPE.

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비정상 몰분율 효과에 대한 동역학적 격자기반 대정준 Monte Carlo 모의실험 연구

  • Yeo, Hye-Jin;Hwang, Hyeon-Seok
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.102-107
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    • 2016
  • 본 연구에서는 동역학적 격자기반 대정준 Monte Carlo (Kinetic Lattice Grand Canonical Monte Carlo, KLGCMC) 모의실험 방법을 이용하여 비정상 몰분율 효과 (Anomalous mole fraction effect)에 대해서 알아보고자 하였다. 이를 위해 양이온 선택성을 가진 이온채널 모델에서 $NH_4{^+}$$Rb^+$의 혼합물에 대하여 몰분율의 변화에 따른 이온전도도를 KLGCMC 모의실험을 이용하여 계산하고, 이를 평균장 이론인 Poisson-Nernst-Planck (PNP)의 결과와 비교해 봄으로써 비정상 몰분율 효과에 대하여 심도 있게 이해하고자 하였다. 본 연구 결과로부터 비정상 몰분율 효과는 이온채널의 이온 선택성에 의해서 발생함을 확인할 수 있었다. 즉, 두 종류 이상의 이온들이 채널 내부로 이동할 때, 이온채널의 이온 선택성에 의해서 각 이온들과 채널 간에 서로 상이한 상호작용을 하게 되고, 이로 인해서 이온 혼합물 조성의 변화, 즉 몰분율의 변화에 대해서 이온 전류가 선형적이 아닌 비선형적으로 변하게 됨을 알 수 있었다.

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Reduction of Lean VOC Emission by Reforming with a Rotating Arc Plasma and Combustion with a Turbulent Partially-Premixed Flame (난류 부분예혼합화염과 로테이팅 아크 플라즈마를 이용한 난연성 유증기의 연소처리)

  • Ahn, Taekook;Lee, Daehoon;Park, Sunho
    • Journal of the Korean Society of Combustion
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    • v.22 no.1
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    • pp.23-31
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    • 2017
  • Large-scale fuel tanks emit massive amount of hardly-combustible VOC mixtures which are light hydrocarbon species in dilution with nitrogen and carbon dioxide. We have developed a lab-scale burner to combust those VOC mixtures by use of a turbulent partially-premixed flame as a pilot flame. For a higher HC treatment ratio, the mixture gases were reformed by a rotating arc plasma device. The results showed that the nitrogen mole fraction and the injecting speed of the VOC mixture influence on the performance of the burner. It was also found that the size of the pilot flame and the power supplied to the plasma device determine the overall HC treatment ratio and the concentrations of CO and NOx in the exhaust gas.

A Study on Flame Structure of SNG Fuel Part I : Interaction between Flames Downstream (SNG 연료의 화염구조에 관한 연구 Part I : 화염후류간 상호작용)

  • Sim, Keunseon;Lee, Keeman
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.53-56
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    • 2015
  • A combined experimental and numerical study has been conducted to investigate the downstream interaction between simulated SNG-air premixed flames in fuel composition of 91% $CH_4$ + 6% $C_3H_8$ + 3% $H_2$. In this study, the effects of fuel molar concentration(lean-rich) and strain rate($a_g$) were major parameters. A main focus is to investigate flames behavior and chemical interaction at flames downstream. The numerical results were calculated by OPPDIF application. The reaction mechanism adopted was USC-II model including C3 reaction.

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Triplet Excitation Energy Transfer as a Function of Concentration in Glassy Methylbenzophenone

  • 한형순;이재광;남계준;최용국;국성근
    • Bulletin of the Korean Chemical Society
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    • v.19 no.9
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    • pp.923-926
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    • 1998
  • Spectral diffusion following direct triplet excitation from the ground state in glassy Methylbenzophenone as a function of transition energy has been studied. The concentrations of donor and acceptor have been determined for different transition energies. The geometrical distribution was determined by a computer simulation. The cluster size increases gradually with concentration and cluster percolation is observed at 0.31 mole fraction for a three dimensional system. The average distance between a donor and an acceptor also has been determined for different concentrations. The energy transfer efficiency changes abruptly at a critical concentration of 0.054, corresponding to a critical distance of 9.8 Å. The γvalue was evaluated to be 1.17.

Hexane Vapor Concentration Measurement of a Liquid Jet in Crossflow (수직분사제트에서의 헥산 증기농도측정)

  • Oh, Jeong-Seog;Lee, Won-Nam;Lee, Jong-Geun;Santavicca, Dominique A.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.4
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    • pp.25-31
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    • 2010
  • The vapor concentration of hexane in a liquid spray jet in crossflow was qualitatively measured on the basis of the infrared (IR) extinction techniques. The objectives of the present study are to understand the whole evaporation process from droplet breakup to vapor and to confirm the usefulness of IR emission method in a lab-scale ramjet combustor. From the experimental results, we concluded that hexane vapor mole fraction increased with temperature rise and kept nearly constant during the variation of fuel to air momentum ratio.

Electrostatic Adsorption of Uniformly Charged Electrolytes within Like-charged Electrodes

  • Jang, Seanea;Shin, Ghi Ryang;Kim, Soon-Chul
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1315-1323
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    • 2018
  • The classical-fluids density functional theory has been developed for studying the structural and the electrical properties of electrolyte solutions containing uniformly charged hard-spherical ions. The modified fundamental-measure theory has been used to evaluate the hard-sphere contribution. The mean-field approximation has been employed to calculate the cross correlation between the hard sphere contribution and the Coulomb interaction. The Poisson equation for ions carrying charges that are spatially separated has been solved. The present theory shows reasonably good agreement with the corresponding Monte Carlo simulation results. The calculated results show that the attraction between like-charged planar surfaces is the result of the intra-ionic correlation and depends strongly on the ion size, valence, mole fraction, and charge distribution of electrolytes.

3D Simulation on Polarization Effect in AlGaN/GaN HEMT (AlGaN/GaN HEMT의 분극 현상에 대한 3D 시뮬레이션)

  • Jung, Kang-Min;Kim, Jae-Moo;Kim, Hee-Dong;Kim, Dong-Ho;Kim, Tae-Geun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.10
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    • pp.23-28
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    • 2010
  • In this paper, we investigated the polarization effects on the electrical and structural characteristics of AlGaN/GaN HEMT. Both the Al mole-fraction and the barrier thickness of AlGaN, which determine the profiles of a two-dimensional electron gas, were simulated to obtain the optimum HEMT structure affecting the polarization effect. As a results, we found that the amount of bound sheet charges was increased by 16% and the maximum drain current density ($I_D$,max) was increased by more than 37%, while AI mole fractions are changed from 0.3 to 0.4. We also observed a 37% improvement in maximum drain current density ($I_D$,max) by increasing AIGaN layer thickness from 17 to 38 nm. However when AlGaN layer thickness reached the critical thickness, DC characteristics were dramatically lowered due to 'bulk' relaxation in AlGaN layer.