Browse > Article
http://dx.doi.org/10.3938/jkps.73.1315

Electrostatic Adsorption of Uniformly Charged Electrolytes within Like-charged Electrodes  

Jang, Seanea (Department of Physics, Andong National University)
Shin, Ghi Ryang (Department of Physics, Andong National University)
Kim, Soon-Chul (Department of Physics, Andong National University)
Publication Information
Journal of the Korean Physical Society / v.73, no.9, 2018 , pp. 1315-1323 More about this Journal
Abstract
The classical-fluids density functional theory has been developed for studying the structural and the electrical properties of electrolyte solutions containing uniformly charged hard-spherical ions. The modified fundamental-measure theory has been used to evaluate the hard-sphere contribution. The mean-field approximation has been employed to calculate the cross correlation between the hard sphere contribution and the Coulomb interaction. The Poisson equation for ions carrying charges that are spatially separated has been solved. The present theory shows reasonably good agreement with the corresponding Monte Carlo simulation results. The calculated results show that the attraction between like-charged planar surfaces is the result of the intra-ionic correlation and depends strongly on the ion size, valence, mole fraction, and charge distribution of electrolytes.
Keywords
Multivalent electrolytes; Density functional theory; Like-charged planar surfaces;
Citations & Related Records
연도 인용수 순위
  • Reference
1 L. Guldbrand, B. Jonsson, H.Wennerstrom and P. Linse, J. Chem. Phys. 80, 2221 (1984).   DOI
2 L. B. Bhuiyan, V. Vlachy and C. W. Outhwaite, Int. Rev. Phys. Chem. 21, 1 (2002).   DOI
3 S. May, A. Iglic, J. Rescic, S. Maset and K. Bohinc, J. Phys. Chem. B 112, 1685 (2008).   DOI
4 I. Szilagyi, A. Sadeghpour and M. Borkovec, Langmuir 28, 6211 (2012)   DOI
5 E. F. Marques, O. Regev, A. Khan, M. Miguel and B. Lindman, Macromolecules 32, 6626 (1999)   DOI
6 D. Frydel and Y. Levin, J. Chem. Phys. 138, 174901 (2013)   DOI
7 D. Frydel, J. Chem. Phys. 145, 184703 (2016).   DOI
8 K. Bohinc, G. V. Bossa, S. Gavryushov and S. May, J. Chem. Phys. 145, 234901 (2016).   DOI
9 S. Jang, G. R. Shin and S-C. Kim, J. Chem. Phys. 147, 036101 (2017).   DOI
10 K. Bohinc, J. Rescic and S. May, J. Mol. Liquids 228, 201 (2017).   DOI
11 D. Frydel and Y. Levin, J. Chem. Phys. 148, 024904 (2018).   DOI
12 R. Roth, R. Evans, A. Lang and G. J. Kahl, J. Phys.: Condens. Matter 14, 12063 (2002).   DOI
13 Y. Yu and J. Wu, J. Chem. Phys. 117, 10156 (2002)
14 E.Waisman and J. L. Lebowitz, J. Chem. Phys. 56, 3086 (1972)   DOI
15 L. Blum, Mol. Phys. 30, 1529 (1975)   DOI
16 K. Hiroike, Mol. Phys. 33, 1195 (1977).   DOI
17 D. Henderson, L. Blum and J. L. Lobowitz, J. Electroanal. Chem. 102, 315 (1979)   DOI
18 J. Stein, D. Shaliton and Y. Rosenfeld, Phys. Rev. A 37, 4854 (1988)   DOI
19 Y. Rosenfeld, Phys. Rev. A 35, 938 (1987)   DOI
20 A. R. Denton, Phys. Rev. E 67, 011804 (2003).   DOI
21 H. M. Manzanilla-Granados, F. Jimenez-Angeles and M. Lozada-Cassou, J. Phys. Chem. B 115, 12094 (2011)   DOI
22 J. Gonzalez-Calderon, M. Chavez-Paez, E. Gonzalez-Tovar and M. Lozada-Cassou, arXiv: 1712.00467v1 [cond-mat.soft] (2017).
23 K. Kiyohara, M. Yamagata and M. Ishikawa, J. Chem. Phys. 144, 134701 (2016),   DOI
24 S. Zhou, S. Lamperski and M. Sokoowska, J Stat. Mech.: Theory and experiment. 073207 (2017).
25 D. Gillespie, J. Phys. Chem. Letts. 2, 1178 (2011)   DOI
26 A. Sadeghpour, I. Szilagyi and M. Borkovec, Z. Phys. Chem. 226, 597 (2012).   DOI
27 D. Gottwald, C. N. Likos, G. Kahl and H. Lowen, Phys. Rev. Lett. 92, 068301 (2004).   DOI
28 Y. Yu and J. Wu, J. Chem. Phys. 118, 3835 (2003).   DOI
29 G. Rickayzen, Mol. Phys. 97, 721 (1999).   DOI
30 L. Blum and J. S. Hye, J. Phys. Chem. 81, 1311 (1977).   DOI
31 W. Olivares and D. A. McQuarrie, J. Phys. Chem. 84, 863 (1980)   DOI
32 Z. Tang, L. E. Scriven and H. T. Davis, J. Chem. Phys. 97, 9258 (1992).   DOI
33 J. Stein, D. Shalitin and Y. Rosenfeld, Phys. Rev. A 37, 4854 (1988).   DOI
34 A. R. Denton, Phys. Rev. E 67, 011804 (2003).   DOI
35 H. Manzanilla-Granados and M. Lozada-Cassou, J. Phys. Chem. B 117, 11812 (2013).   DOI
36 Z. Wang, Phys. Rev. E 93, 012605 (2016).   DOI
37 A. Schlaich, E. W. Knapp and R. R. Netz, Phys. Rev. Letts. 117, 048001 (2016).   DOI
38 F. Bordi, C. Cametti, S. Sennato and D. Viscomi, J. Chem. Phys. 126, 024902 (2007).   DOI