• Title/Summary/Keyword: MnO addition

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Characteristics of PAN-PZI Ceramics with $BaCO_3$Addition ($BaCO_3$ 첨가량에 따른 PAN-PZT계 세라믹스의 특성)

  • 박타리;이동균;최지원;김현재;윤석진;조봉희;고태국
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.981-984
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    • 2001
  • The piezoelectric properties of 0.05pb(A $l_{0.5}$N $b_{0.5}$) $O_3$-0.95Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_3$+0.7wt%N $b_2$ $O_{5}$ +0.5wt%Mn $O_2$ceramics with the additives of BaC $O_3$were investigated. For the additions of BaC $O_3$, the dielectric constant ($\varepsilon$$^{T}$ $_{33}$ ), the piezoelectric constant ( $d_{33}$ ), the electromechanical coupling factor ( $k_{p}$ ), and . the mechanical quality factor ( $Q_{m}$ ) were increased, but dielectric loss (tan$\delta$) was decreased. The highest piezoelectric properties and dielectric properties were observed at the sintered temperature of 120$0^{\circ}C$ and 0.4 wt% of BaC $O_3$, and the properties of $d_{33}$ , $k_{p}$ , and $Q_{m}$ were 339(x10$^{-12}$ C/N), 59% and 1754, respectively.vely.y.y.

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Effect of Potassium Permanganate on Corrosion Behavior of Magnesium Alloy Prepared by Micro-Arc Oxidation (마이크로 아크 산화처리된 마그네슘 합금의 부식특성에 미치는 과망간산칼륨의 영향)

  • Ko, Young Gun;Lee, Kang Min;Shin, Ki Ryong;Shin, Dong Hyuk
    • Korean Journal of Metals and Materials
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    • v.48 no.8
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    • pp.724-729
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    • 2010
  • The effect of potassium permanganate ($KMnO_4$) in an electrolyte on the corrosion performance of magnesium alloy coated by micro-arc oxidation (MAO) has been investigated in this study. For this purpose, MAO coating was carried out on the present sample under AC condition in an alkaline silicate electrolyte with and without $KMnO_4$. Irrespective of the addition of $KMnO_4$, it was found from structural observation that the ceramic coating layers consisted of inner and outer layers. In the sample processed in the electrolyte with $KMnO_4$, the outer layer became dense and even contained a number of $Mn_2O_3$ atoms, resulting in high corrosion resistance. Based on the results of a potentiodynamic polarization test, it was confirmed that the coating layer formed in the electrolyte with $KMnO_4$exhibited better corrosion resistance than that without $KMnO_4$. The high corrosion resistance of the MAO-treated magnesium alloy was explained in relation to the equivalent circuit model.

The Electrical Properties of High Voltage Mutilayer Chip Capacitor with X7R by addition of Er2O3 and Glass Frit (고압용 X7R 적층 칩 캐패시터의 Er2O3 및 유리프릿 첨가에 따른 전기적 특성)

  • Yoon, Jung-Rag;Kim, Min-Kee;Chung, Tae-Seog;Woo, Byoung-Chul;Lee, Seog-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.5
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    • pp.440-446
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    • 2008
  • To manufacture the MLCC with X7R for high voltage stability, $BaTiO_3-MgO-MnO_2-Y_2O_3$ with $(Ba_{0.4}Ca_{0.6})SiO_3$ glass frit was formulated. Based on this composition, the addition of $Er_2O_3$ showed that TCC(Temperature Coefficient Capacitance) at $85^{\circ}C$ was improved from 5 % to ${\sim}0\;%$, but the dielectric constant and IR (Insulation Resistance) were decreased. The glass frit improved the dielectric constant and IR, so the appropriate contents of $Er_2O_3$ and glass frit were 0.6 mol% and 1 wt%, respectively. It showed that the dielectric constant and RC constant were 2,550 and 2,000 (${\Omega}F$), respectively in the sintering condition at $1250^{\circ}C$ in PO2 $10^{-7}$ Mpa. The MLCC with $3.2{\times}1.6$ (mm) size and $1\;{\mu}F$ was also suited for X7R with the above composition.

Effects of Dietary Yellow Loess on Serum Constituents in Korean Rockfish, Sebastes schlegeli (황토 첨가 사료가 조피볼락의 혈청성분에 미치는 영향)

  • 강동수;조영철;최옥수;이영재;김해섭;배태진
    • Journal of Life Science
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    • v.10 no.3
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    • pp.286-291
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    • 2000
  • This study was performed to define the effects of various levels (0∼15%) of dietary yellow loess on serum constituents in Korean rockfish (Sebastes schlegeli). After seven weeks of feeding trial, hemoglobin, protein, albumin, triglyceride, cholesterol and bilirubin in serum were investigated. Chemical composition of yellow loess were composed of SiO2 49.80%, Al2O3 27.50%, FeO3 8.33%, CaO 0.09%, MgO 0.64%, K2O 1.62%, Na2O 0.12%, P2O5 0.20% and MnO 0.03%. Serum levels of total protein and albumin showed higher values the yellow loess addition groups than the control group, and the values of protein and albumin were increased with dietary yellow loess level. Serum levels of triglyceride and cholesterol in the groups fed yellow loess were lower than those in the group fed control diet. And these values decreased with dietary yellow loess level up 10%, then increased with 15% yellow loess diet. The values of bilirubin in serum significantly decreased with dietary yellow loess level up 10%, then increased with 15% yellow loess diet. Hemoglobin level from rockfish fed 7.5% and 10% yellow loess diet were significantly higher than those from fed the control diet.

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Petrology of the Cretaceous Volcanic Rocks in Eastern Part of the Kyeongsan Caldera (경산칼데라 동부지역에 분포하는 백악기 화산암류의 암석학적 특징)

  • Park Sung-Ok;Jang Yun-Deuk;Hwang Sang-Koo;Kim Jeong-Jin
    • The Journal of the Petrological Society of Korea
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    • v.15 no.2 s.44
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    • pp.90-105
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    • 2006
  • The Cretaceous volcanic rocks in the study area represented by andesitic rocks occupy eastern part of the Kyeongsan Caldera. The volcanic rocks comprise andesite I, andesitic tuff, andesite II, and andesitic tuff breccia in their stratigraphic succession, and andesitic porphyry. Andesite I is distinguished from andesite II in their color, texture, phenocryst mineralogy and petrochemisty. In outcrops, andesite I is compact and dark-green, and andesite II is brick red in color and porphyritic in texture. In their phenocryst mineralogy, andesite I contains olivine phenocryst in addition to plagioclase and pyroxene which occur in both of andesites. Compared to andesite II, andesite I is higher in $SiO_2$ and $K_2O$ contents and lower in CaO, MgO, MnO, $TiO_2,\;Fe_2O_3$, and $P_2O_5$. Major elements petrochemistry shows that magma series of the volcanic rocks spread widely from calc-alkaline to alkaline series. On the other hand, immobile trace elements petrochemistry shows that the magma series is calc-alkaline without exception, suggesting that the volcanics has experienced more or less alkali enrichment after their eruption. Trace element diagrams for discrimination of tectonic setting show that the volcanics of the study area might be originated from calc-alkaline continental volcanic arc.

Promoting Effect of Hydrogen Peroxide on 1-Methyl-4-phenylpyridinium-induced Mitochondrial Dysfunction and Cell Death in PC12 Cells

  • Lee, Dong-Hee;Lee, Chung-Soo
    • The Korean Journal of Physiology and Pharmacology
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    • v.10 no.1
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    • pp.51-58
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    • 2006
  • The promoting effect of hydrogen peroxide ($H_2O_2$) against the cytotoxicity of 1-methyl-4-phenylpyridinium ($MPP^+$) in differentiated PC12 cells was assessed by measuring the effect on the mitochondrial membrane permeability. Treatment of PC12 cells with $MPP^+$ resulted in the nuclear damage, decrease in the mitochondrial transmembrane potential, cytosolic accumulation of cytochrome c, activation of caspase-3, increase in the formation of reactive oxygen species (ROS) and depletion of GSH. Addition of $H_2O_2$ enhanced the $MPP^+-induced$ nuclear damage and cell death. Catalase, Carboxy-PTIO, Mn-TBAP, N-acetylcysteine, cyclosporin A and trifluoperazine inhibited the cytotoxic effect of $MPP^+$ in the presence of $H_2O_2$. Addition of $H_2O_2$ promoted the change in the mitochondrial membrane permeability, ROS formation and decrease in GSH contents due to $MPP^+$ in PC12 cells. The results show that the $H_2O_2$ treatment promotes the cytotoxicity of $MPP^+$ against PC12 cells. $H_2O_2$ may enhance the $MPP^+$-induced viability loss in PC12 cells by promoting the mitochondrial membrane permeability change, release of cytochrome c and subsequent activation of caspase-3, which is associated with the increased formation of ROS and depletion of GSH. The findings suggest that $H_2O_2$ as a promoting agent for the formation of mitochondrial permeability transition may enhance the neuronal cell injury caused by neurotoxins.

Effect of Milling Condition on Low-temperature Sinterability and Electrical Properties of BaTiO3 Ceramics (Milling 조건에 따른 BaTiO3의 저온 소결성 및 전기적 특성 변화)

  • Hong, Min-Hee;Sohn, Sung-Bum;Kim, Young-Tae;Hur, Kang-Heon
    • Journal of the Korean Ceramic Society
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    • v.46 no.2
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    • pp.200-210
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    • 2009
  • It is necessary to minimize the mismatch of sintering shrinkage between dielectric ceramic and Ni inner electrode layers for the purpose of developing the ultra high-capacity multi layered ceramic condenser(MLCC). Thus, low temperature sintering of dielectric $BaTiO_3$ ceramic should be precedently investigated. In this work, the influence of the milling condition on sintering behavior and electrical properties of $BaTiO_3$ ceramics was investigated in the $BaTiO_3$(BT)-Mg-Dy-Mn-Ba system with borosilicate glass as a sintering agent. As milling time increased, specific surface area(SSA) of the powder increased linearly, while both sinterability and dielectric property were found to be drastically decreased with an increasing SSA. It was also revealed that the sinterability of the excessively milled $BaTiO_3$ ceramics could be recovered by increasing Ba content, rather than increasing glass addition. These results suggest that the sintering behavior of $BaTiO_3$ ceramics under the high SSA was more strongly dependent on the transient liquid phase caused by Ba addition, than the liquid phase from additional glass.

Effect of Brown Algae (Undaria pinnatifida)-Noodle on Oxygen Radicals and Their Scavenger Enzymes in Liver of Sprague-Dawley Rats (미역 (Undaria pinnatifida) 국수의 투유가 랫트 간장중의 활성산소 및 제거효소에 미치는 영향)

  • CHOI Jin-Ho;KIM Dae-Ik;PARK Soo-Hyun;KIM Dong-Woo;BEAK Yeong-Ho;KIM Chang-Mok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.2
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    • pp.87-92
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    • 2000
  • This study was designed to investigate the effects og $10{\%},\;20{\%}\;and\;40{\%}$-addition of functional brown algae (FBA)-noodles on oxygen radicals and their scavenger enzymes in liver of Sprague-Dawley(SD) male rats. Hydroxyl radicals$({\cdot}OH)$ formations were significantly inhibited$(20{\~}35{\%}\;and\;12{\~}20{\%})$ in liver mitochondria and microsomes of rats administered $0{\%},\;20{\%}\;and\;40{\%}$ FBA-noodles compared with that of control group. Significant differences in $H_2O_2$ formations of liver microsome in these FBA-noodles fed groups could not be obtained, but superoxide-radical $(O_2^({\cdot}-))$ formations of liver cytosol resulted in a significant decrease about $10{\%}\;in\;20{\%}\;and\;40{\%}$ FBA-noodles compared with control group. Mn-SOD activities in liver mitochondria were significanlty increased $(10{\~}15{\%})$ in the groups fed $10{\%},\;20{\%}\;and\;40{\%}$ FBA-noodles, while a group administered $40{\%}$ FBA-noodle only resulted In a significant increases $(about 12{\%})$ in Mn-SOD activity of liver microsomes compared with control group. Cu, Zn-SOD activities in liver cytosol were significantly increased $(10{\~}20{\%})\;in\;10{\%},\;20{\%}\;and\;40{\%}$ FEA-noodles compared with control group. Administration of $10{\%},\;20{\%}\;and\;40{\%}$ FBA-noodles resulted in a marked increases$(20{\~}40{\%})$ in liver cytosolic glutathione peroxidase (GSHPx) compared with control group. Significant differences in lipid peroxide (LPO) levels of mitochondria and microsomes in $10{\%}$ FBA-noodle could not be obtained, while LPO levels of $20{\%} and 40{\%}$ FBA-noodles were significantly inhibited about $10{\%}$ in mitochondria and microsomes compared with control group. These results suggest that these FBA-noodles may play a desirable role in attenuating an oxygen radical formations and increasing a scavenger enzymes activity by some brown algae (Undaria pinnatifida) components.

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Piezoelectric Characteristics of Pb(Mnsub 1/3Nb 23)Osub 3-Pb(Zr, Ti)Osub 3 Ceramics with $CeO_2$ Impurity for the Piezoelectric Transformer (Cerium Oxide 첨가에 따른 압전트랜스포머용 $Pb(Mn_{1/3}Nb_{2/3})O_3-Pb(Zr,Ti)O_3$ 세라믹의 압전특성)

  • Ryu, Ju-Hyeon;Seo, Seong-Jae
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.9
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    • pp.611-615
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    • 1999
  • Piezoelectric properties of PMN-PZT ceramics with $CeO_2$ impurity were investigated. Mechanical quality factor, $Q_m$ of 1792, 1285 and the electromechanical coupling coefficient, $k_p$ of 0.52, 0.54 were obtained from the specimen with 0.25 and 0.5 mole % $CeO_2$ respectively. Curie temperature was decreased with the addition of $CeO_2$ while the electric coercive field was proportional to the amount of impurity. Based on the system ceramics with 0.5 mole % cerium oxide, a Rosen type piezoelectric transformer was fabricated and tested. Voltage step-up ratios of 230 and 13 were obtained from the transformer at no load and $100 k\Omega$ resistance, respectively. Experimental results showed a potential of the transformer for the practical use coupled with the expected strength increase by the grain size refinement.

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Studies for alternative material of media for Pleurotus eryngii (큰느타리버섯 배지재료의 다변화를 위한 연구)

  • Park, Jin-Young;Lee, Jae-Yun;Kim, Hyun-Tae;Kim, Sam-Soo;Kim, Sung-Yun;Kim, Mun-Ock;Lee, Jae-Dong
    • Journal of Mushroom
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    • v.4 no.3
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    • pp.88-100
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    • 2006
  • This study was performed to investigate the effective components of media of Pleurotus eryngii for bottle cultivation and several alternative material for reducing cost and smooth supply. The results show that Potato starch, Cocoa shell, Corn gluten feed, Soybean flour(solvent extracted), Cottonseed hull, Poultry manure can be replaced in Bean curd dregs of basal substrates. Especially addition of Soybean flour at 2~8% and Poulty manure at 2% in place of Bean curd dregs is effective for mycelial growth of P. eryngii, Also Pine sawdust appears that can be replaced by Softwood sawdust and addition of softwood sawdust at 25.2% is most effective. Addition of $CaCO_3$, at 2~3%, $K_2CO_3$, at 0.2%, $MgSO_4{\cdot}7H_2O$ in 0.1%, $MnSO_4{\cdot}5H_2O$ in 0.05% is effective for mycelial growth of P. eryngii, Activation materials used in this study have not enough benefit for mycelial growth in the financial aspect.

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