• Clean Technology
• /
• v.20 no.3
• /
• pp.218-225
• /
• 2014

Catalytic gasification of raw coals at mild condition is not realized yet mainly due to deactivation of catalysts via their irreversible interaction with mineral matters in coal. In this work, the gasification behavior of ash-free coal (AFC) was compared with that of the parent raw coal. In order to modify the gasification conditions, the raw coal gasified with fixed variables (water supply, space velocity, temperature, catalysts) in a fixed bed reactor. When catalysts are added by physical mixing method with coal, $K_2CO_3$ was the most effective additives for steam gasification of coal. However, the activity of ash-free coal (AFC) was much less reactive than raw coal due to high temperature extraction in a 1-methylnaphthalene under 30bar at $370^{\circ}C$ for 1 h, almost removed oxygen functional groups, and increased carbonization. The addition of $K_2CO_3$ in AFC achieved higher conversion rate at low temperature ($700^{\circ}C$). At that time, the molar ratio of gases ($H_2/CO$ and $CO_2/CO$) was increased because of water-gas shift reaction (WGSR) by addition of catalysts. This shows that catalytic steam gasification of AFCs is achievable for economic improvement of gasification process at mild temperature.

• Atmosphere
• /
• v.27 no.1
• /
• pp.41-54
• /
• 2017

Organic carbon (OC) and elemental carbon (EC) in $PM_{2.5}$ were measured using Sunset OC/EC Field Analyzer at Seoul Hwangsa Monitoring Center from March to April, 2016. The mean concentrations of OC and EC during the entire period were $4.4{\pm}2.0{\mu}gC\;m^{-3}$ and $1.4{\pm}0.6{\mu}gC\;m^{-3}$, respectively. OC/EC ratio was $3.4{\pm}1.0$. The average concentrations of $PM_{10}$ and $PM_{2.5}$ were $57.4{\pm}25.9$ and $39.7{\pm}19.8{\mu}g\;m^{-3}$, respectively, which were detected by an optical particle counter. The OC and EC peaks were observed in the morning, which were impacted by vehicle emission, however, their diurnal variations were not noticeable. This is determined to be contributed by the long-range transported OC or secondary formation via photochemical reaction by volatile organic compounds at afternoon. A conditional probability function (CPF) model was used to identify the local source of pollution. High concentrations of $PM_{10}$ and $PM_{2.5}$ were observed from the westerly wind, regardless of wind speed. When wind velocity was high, a mixing plume of dust and pollution during long-range transport from China in spring was observed. In contrast, pollution in low wind velocity was from local source, regardless of direction. To know the effect of long-range transport on pollution, a concentration weighted trajectory (CWT) model was analyzed based on a potential source contribution function (PSCF) model in which 75 percentiles high concentration was picked out for CWT analysis. $PM_{10}$, $PM_{2.5}$, OC, and EC were dominantly contributed from China in spring, and EC results were similar in both PSCF and CWT. In conclusion, Seoul air quality in spring was mainly affected by a mixture of local pollution and anthropogenic pollutants originated in China than the Asian dust.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.19 no.1
• /
• pp.100-108
• /
• 2015

The purpose of this study is to evaluate the effect of improvement on the impact resistance and strength properties of cement composites by surface modification of aramid fiber. For aramid fiber reinforced cement composites, therefore, dispersion capability and the bonding efficiency between the fibers and the cement composite material need to be improved. It is possible by modifying surface properties to hydrophobic, it is considered that oiling agent ratio of 1.2 % and improvement of performance is in need to be investigated. In this study, short aramid fibers were mixed by different fiber length and oiling agent ratio. And improvement of strength properties and impact resistance performance of hybrid cement composites were evaluated under the influence of steel fiber. As a result, strength properties of aramid fiber reinforced cement composites are different by mixing ratio of fiber, oiling agent ratio and length of fiber. In case of cement composites which have same volume fraction and fiber length, tensile strength and flexural strength were improved with increase of the emulsions throughput of the fiber surface. The results of evaluation on the static strength properties had effects on impact resistance performance by high-velocity impact. And it was observed that the scabbing of rear was suppressed with increase of the oiling agent ratio.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.32 no.1
• /
• pp.105-111
• /
• 1999

To investigate the relationships between ocean environmental characteristics and thechange of the catch, we analyzed various environmental factors such as mean temperature, salinity, current vectors, lunar day and wind vectors from 1995 to 1996 and the catch fluctuation of Hanlim set net from 1994 to 1996. The results are as follow ; 1) The proportion of fishes caught in Hanlim set net is highest for horse mackere1 ($69.2\%$) and is followed by common mackerel ($18.4\%$), hair tail ($5.6\%$), squid ($2.7\%$) and rabbit fish ($1.4\%$) in order. Two peaks in the monthly catch appeared in June and October in the operation period of May- December. 2) The flow direction was northward in flood time and southeastward in ebb time around the Hanlim set net. Thus, the vortical mixing of sea water was active and continued for more than 3 hours. In addition, mean daily temperature was low due to the presence of middle and bottom water in offshore. Increase in salinity or high salinity of sea water provides a favorable condition for catches of fishes. Catches in the first quarter and the last quarter of the moon were larger than that in full moon and the last of the month. In particular, when south or southeasterly wind velocity reaches about 3$\~$6.5 m/s, the possibility of catches increases.

• Journal of Korean Society of Environmental Engineers
• /
• v.33 no.5
• /
• pp.368-377
• /
• 2011

A package type of SCR (selective catalytic reduction) system that was proposed for removing the $NO_x$ found in flue gas from the small scale of air pollution sources was evaluated. The efficiency of the SCR system is determined by the proper utilization of catalytic media installed inside of the system, and the proper distribution of flow velocity and $NH_3$ concentration in the flue gas is a crucial factor for using the catalytic media. In this study, the distributions of $NH_3$ concentration were estimated under the various arrays and shapes of AIG at the given gas flow condition. The value of RMS (%) in $NH_3$ concentration is 95.3% at co-current flow (at $0^{\circ}$) injection but it is 90.1% at the condition of counter-current flow (at $120^{\circ}$) condition, which implies the counter-current injection is more favorable. By rearranging the $NH_3$ injection flow rates based on the distribution of velocity and $NH_3$ distribution in basic calculation, the value of RMS (%) in $NH_3$ concentration was reduced to 62.8%. The enhanced effect of $NH_3$ mixing by the combined effect of arrays and shapes are complied in the study.

• Korean Chemical Engineering Research
• /
• v.46 no.5
• /
• pp.922-930
• /
• 2008

The selective non-catalytic reduction(SNCR) performance is sensitive to the process parameters such as flow velocity, reaction temperature and mixing of reagent(ammonia or urea) with the flue gases. Therefore, the knowledge of the velocity field, temperature field and species concentration distribution is crucial for the design and operation of an effective SNCR injection system. In this work, a full-scale two-dimensional computational fluid dynamics(CFD)-based reacting model involving a droplet model is built and validated with the data obtained from a pilot-scale urea-based SNCR reactor installed with a 150 kW LPG burner. The kinetic mechanism with seven reactions for nitrogen oxides($NO_x$) reduction by urea-water solution is used to predict $NO_x$ reduction and ammonia slip. Using the turbulent reacting flow CFD model involving the discrete droplet phase, the CFD simulation results show maximum 20% difference from the experimental data for NO reduction. For $NH_3$ slip, the simulation results have a similar tendency with the experimental data with regard to the temperature and the normalized stoichiometric ratio(NSR).

• Korean Journal of Materials Research
• /
• v.3 no.2
• /
• pp.175-184
• /
• 1993

Abstract Co-and/or AI-added Nd-Fe-B-based magnetic alloys were fabricated by using vacuum induction melting frunace, and melt-spun ribbons were made of the magnetic alloys with single roll rapid quenching method. The variation of magnetic properties of the melt-spun ribbons as a function of Cuwheel velocity (Vs) were investigated. Bonded magnets were made of the optimally quenched ribbon fragments, and the magnetic properties of the melt-spun ribbons and the bonded magnets were studied, relating to the microstructure and crystalline structure. Cu-wheel surface velocity had a strong effect on the magnetic properties of the melt-spun ribbons, and the maximum properties were obtained around Vs =20m/sec. The optimally quenched ribbon had a cellura-type microstructure, in which fine N$d_2$F$e_14$B grains were surrounded by thin Nd-rich phase. In case of a 2.1at% AI-added melt-spun ribbon, the magnetic properties were as follows: iHc, Br, and (BH)max were 15.5KOe, 7.8KG and 8.5MGOe respectively. And resin bonded magnets were fabricated by mixing optimally quenched ribbon fragments with 2.5wt % polyamide resin, compacting and binding at room temperature. The iHc, Br and (BH)max of bonded magnet were lO.2KOe, 4.4KG and 3.3MGOe respectively. And hot-pressed magnets were made by pressing the overquenched ribbons at high temperature. The magnetic properties of hot-pressed magnets were better than those of bonded magnets, and when the holding time was 8 minutes, the iHc, Br, and (BH)max of the hot-pressed magnet were 1O.8KOe, 7.3KG and 8.0MGOe respectively. Domain structure was mainly maze pattern, which means that the easy magnetization axis could be aligned, and the domain width of the hot-pressed magnets was smaller than that of bonded magnets.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.17 no.1
• /
• pp.374-388
• /
• 2016

In Jeju-Do, there is the 1100 Road, 516 Road, and Bijarimro, which are typical mountain sight-seeing roads in Jeju. These roads are local roads that have been the location for many traffic accidents. This study focused on these roads, categorized the type of traffic accident and analyzed the accident characteristics. The major accident factors were analyzed through trip AHP analysis, Comparative analysis of the velocity distribution and the factors affecting traffic accidents were analyzed. Tourists took many trips on these roads. The mixing rate of the rental cars was 36.70%~71.60% in 1100 road and Bijarimro. Currently, these local roads are regulated by a speed limit of 60km/h. However, it might be necessary to reduce the speed limit to 40km/h considering the geometric line form of the road and the climate in these areas. The speed limit of more than 40km/h is found 87.0% on 516 Roads, 88.57% on 1100 roads, and 93.1% on Bjarimro, In these roads, the speed ratio is higher as described above. Therefore, these roads have been found to have a higher risk of traffic accidents by overspeeding driving. The overspeed driving ratio of these roads was 87.0%~93.1%, The overspeed driving enforcement method at one spot has only the effect of reducing the speed at that enforcement place; the effect cannot be expected for the other places or sections. It is necessary to introduce a section overspeed driving enforcement system utilizing the average velocity in these areas to prevent traffic accidents.

• Conservation Science in Museum
• /
• v.27
• /
• pp.103-124
• /
• 2022

This study examined the properties of the materials used in the three-story pagoda at Jangha-ri, Buyeo. It was performed in order to identify the objective condition of the pagoda and establish an appropriate plan for the conservation treatment of the pagoda. According to the study, the average total magnetic susceptibility was 3.71 (10^-3 SI unit), and at least four types of granite with different origins were likely used in the production of the pagoda. The ultrasonic velocity averaged 1,519m/s, and the coefficient of weathering showed an average of grade 4. The thermal gradient between the cement (restoration materials) and original materials was identified through thermal imaging. In some areas, the cement restoration materials required replacement with new stone materials with properties similar to those of the original stone materials. Taking into account these results, a map of weathering damage was prepared and appropriate conservation treatment plans were established based on the findings of previous studies. Since the pagoda had suffered severe biological damage and discoloration, surface contaminants were removed through wet cleaning with distilled water and a brush. The exfoliated areas were reinforced on the site by mixing epoxy resin with powdered stone with the same properties as the original stone materials of the pagoda.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.26 no.3
• /
• pp.242-253
• /
• 2020

This study examined the ef ects of freshwater discharge by artificial dikes from the Kanwol and Bunam lakes on the dynamics in the Chunsu Bay, Yellow Sea, Korea, during the summer season based on three-dimensional numerical modeling experiments. Model performances were evaluated in terms of skill scores for tidal elevation, velocity, temperature, and salinity and these scores mostly exceeded 90 %. The variability in residual currents before and after the freshwater discharge was examined. The large amount of lake water discharge through artificial dikes may result in a dramatically changed density field in the Chunsu Bay, leading to an estuarine circulation system. The density-driven current formed as a result of the freshwater inflow through the artificial dikes (Kanwol/Bunam) caused a partial change in the tidal circulation and a change in the scale and location of paired residual eddies. The stratification formed by strengthened static stability following the freshwater discharge led to a dramatic increase in the Richardson number and lasted for a few weeks. The strong stratification suppressed the vertical flux and inhibited surface aerated water mixing with bottom water. This phenomenon would have direct and indirect impacts on the marine environment such as hypoxia/anoxia formation at the bottom.