• Title/Summary/Keyword: Mixing region

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Effect of the imported bituminous coal and the domestic anthracite coal mixed with petroleum coke (석유코크스와 혼합된 국내무연탄과 수입유연탄 슬래그의 특성 규명)

  • Kim, Min-Kyung;Oh, Myong-Sook S.
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.230-233
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    • 2008
  • The vanadium rich ash of petroleum coke can give a slagging problem during because of the high melting point of $V_2O_3$. For continuous removal of the slag, petroleum coke is often mixed with coal, and the viscosity of the mixed slag is an important property, determining the gasification temperature. The viscosities of the mixed slag from various mixing ratios of petroleum coke and a bituminous coal were investigated. When mixed with a crystalline coal slag, $T_{cv}$ was increased at a higher the coke content in the mixed feed. When the $V_2O_3$ concentration was greater than 4.5%, it was difficult to get accurate measurements of $T_{cv}$. The SEM/EDX analyses of the cooled slag revealed that the major crystalline phase was anorthite, and $T_{cv}$ should be related to the formation temperature of anorthite. The SEM/EDX analyses also showed that, at low concentrations of vanadium, part vanadium formed a crystalline phase with Al-Si-Ca-Fe, and the rest remained in the glassy phase, suggesting that vanadium existed as a slag component at the low viscosity region. At a high concentration, vanadium forms a phase with Ca, and the Ca-V phase was separated from the slag phase, and formed a layer above the slag. FeO in petroleum coke also played an important role determining viscosity: at high temperatures, increased FeO lowered the viscosity, but as it formed a spinel phase, the depletion of FeO in the slag resulted in a higher viscosity.

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Morphology and Mechanical Properties of Waste PVC Blends (II)- The Relationship between Rheology and Morphology of Waste PVC/PE Blends (폐폴리(염화 비닐)계 고분자 블렌드의 구조 및 물성 연구(II)-폐폴리(염화 비닐)/폴리에틸렌 고분자 블렌드의 형태학 및 유변학적 거동)

  • 유영재;박재찬;원종찬;최길영;이재흥
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.460-467
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    • 2004
  • The polymer blends of waste poly(vinyl chloride) (RPVC) and waste polyethylene (RPE) were prepared by melt mixing. Their morphologies and rheological properties were investigated and torque changes were also measured. Comparing the torques calculated by the log additivity rule with measured torque changes, the polymer blends showed the large negative deviation behavior (NDB) due to their incompatibility. The shear viscosities of the blends decreased with increasing shear rates, showing shear thinning behavior. The shear viscosity of the blends with compatibilizer was larger than that of the blends without compatibilizer. SEM micrographs of the strands after measurement showed that the domain size of the blends was slightly enlarged with increasing the shear rate. Also, RPVC domain size was larger in the core-sections of the strands from capillary viscometer than in the surface region.

The Simulation about the Air Flow and Pressure Drop inside the Metal Foam (발포 금속 내 공기 유동 및 압력강하에 관한 시뮬레이션)

  • Kim, Pil-Hwan;Jin, Mei-Hua;Jang, Seok-Jun;Chung, Han-Shik;Jeong, Hyo-Min
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1053-1058
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    • 2008
  • Porous medium was considered in the present study for the heat transfer enhancement. This was attributed to its high surface area to volume ratio as well as intensive flow mixing by tortuous flow passages. But when the air or water flow through in the porous medium, it is occurred the pressure drop between inlet and outlet. So in the present study investigated simulation result about the pressure drop in the porous medium before apply to heat exchanger. In this simulation, the thickness of the solid inside the porous medium region was varied 0.2 mm to 0.4 mm. And then the simulation result were compared the pressure drop in the same unit cell ($0.5\;mm{\times}0.5\;mm{\times}0.5\;mm$). To make the analysis model, it was assumed the 14-sided tetrakaidecahedron cell which has long been considered the optimal packing cell first proposed by the Lord Kelvin in 1887. And then the simulation is carried out using by STAR-CCM+ which is commercial software. The simulation result can be showed quantified pressure drop by solid effect in the porous medium.

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Lead isotope ratios characteristics of Excavated bronzes from Korea peninsula (출토 지역과 시대에 따른 한국 청동기의 납동위원소비 분류 특성)

  • Kim, So-Jin;Han, Woo-Rim;Hwang, Jin-Ju;Jeong, Youn-Joong;Han, Min-su
    • 보존과학연구
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    • s.36
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    • pp.4-10
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    • 2015
  • This paper confirms characteristics of lead isotopes of bronze artifacts excavated from Korea peninsula using 673 data classified according to Age, type and region. Lead isotopes data in Early iron ages are distributed in the southern Korean peninsula, but data in Joseon ages are concentrated in zone 3. Also Bronze artifacts excavated from Seoul, Gyeonggi, Chungcheong, Jeolla and Gyeonsang are manufactured using raw materials of the entire Korea peninsula, but bronzes excavated from North Korea aren't produced using raw materials of Gyeonsang provinces. Lead isotopes data will be able to find moving routes of raw materials and to separate the period of mixing and recycling of lead.

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Variability of Water Quality and Limiting Factor for Primary Production in Semi-enclosed Masan Bay, South Sea of Korea (한국 남해 마산만에서 수질환경의 계절적 변동과 기초생산 제한인자)

  • Lim, Dhong-Il;Kim, Young-Ok;Kang, Mi-Ran;Jang, Pung-Kuk;Shin, Kyoung-Soon;Jang, Man
    • Ocean and Polar Research
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    • v.29 no.4
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    • pp.349-366
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    • 2007
  • Seasonal variations of various physicochemical components (temperature, salinity, pH, DO, COD, DOC, nutrients-silicate, DIN, DIP) and potential limiting factor for phytoplankton primary production were studied in the surface water of semi-enclosed Masan Bay. Seasonal variations of nutrient concentrations, with lower values in summer and winter, and higher in fall, are probably controlled by freshwater loadings to the bay, benthic flux and magnitude of occurrence of phytoplankton communities. Their spatial distributional patterns are primarily dependent on physical mixing process between freshwater and coastal seawater, which result in a decreasing spatial gradient from inner to outer part of the bay. In the fall season of strong wave action, the major part of nutrient inputs (silicate, ammonium, dissolved inorganic phosphorus) comes from regeneration (benthic flux) at sediment-water interface. During the summer period, high Si:DIN and Si:DIP and low DIN:DIP relative to Redfield ratios suggest a N- and secondarily P-deficiency. During other seasons, however, silicate is the potential limiting factor for primary production, although the Si-deficiency is less pronounced in the outer region of the bay. Indeed, phytoplankton communities in Masan Bay are largely affected by the seasonal variability of limiting nutrients. On the other hand, the severe depletion of DIN (relatively higher silicate level) during summer with high freshwater discharge probably can be explained by N-uptake of temporary nanoflagellate blooms, which responds rapidly to pulsed nutrient loading events. In Masan Bay, this rapid nutrient consumption is considerably important as it can modify the phytoplankton community structures.

Measurement of Atmospheric BTX in Seoul Using Differential Optical Absorption Spectroscopy (차등흡수 분광법을 이용한 서울 대기 중 BTX 측정)

  • Lee Chulkyu;Choi Yeo Jin;Lee Jeong Soon;Jung Jin Sang;Kim Young Joon;Kim Ki Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.1-14
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    • 2005
  • In this study, a Long Path Differential Optical Absorption Spectroscopy system (K-JIST LP-DOAS) has been used to simultaneously measure atmospheric monoaromatic hydrocarbons and other trace compounds. The validity of the K-JIST LP-DOAS for measuring atmospheric monoaromatic hydrocarbons was tested during a field campaign between 12 February and 14 March 2003 at an urban site in Seoul, Korea through inter-comparative measurements against a collocated on-line Gas Chromatography (GC) system. The concentrations of benzene, toluene, p-xylene, and m-xylene were measured with the K-JIST LP-DOAS system in the UV region (239~302 nm) over a 740 m beam path. For the other trace compounds, a longer spectral range (299~362 nm) was used. In order to remove the interference of atmospheric abundant species (such as oxygen, sulfur dioxide and ozone), two oxygen optical density spectra obtained at two pathlengths, 697 and 1133m, and reference spectra of sulfur dioxide and ozone were incorporated in the fitting procedure. The mean concentrations measured by our LP-DOAS during the measurement period were 0.77 ($\pm$0.38) ppbv for benzene, 3.68 ($\pm$1.90) ppbv for toluene, 0.41 ($\pm$0.19) ppbv for p-xylene, 0.54 ($\pm$0.24) ppbv for m-xylene. The concentration data of benzene, toluene, p-xylene and m-xylene obtained by our LP-DOAS were found to be in relatively good correlations with those of the online GC system. Pearson's coefficients in the observed concentrations between LP-DOAS and on-line GC were 0.84 for benzene, 0.83 for toluene and 0.65 for m,p-xylene. This study suggests that the LP-DOAS system can be used to provide reliable information on both the mixing ratios and temporal distribution characteristics of monoaromatic hydrocarbons in the urban air.

Six-Color Separation based on Limitation of Colorant Amount and Dot Visibility Ordering (잉크량 제한과 도트 가시성 순서에 기반한 6색 분리 방법)

  • Kim, Joong-Hyun;Son, Chang-Hwan;Jang, In-Su;Ha, Yeong-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.44 no.6
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    • pp.35-46
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    • 2007
  • This paper proposes a six-color separation method of reducing unnecessary usage of colorants based on the limitation of total colorant amount and dot visibility ordering. First, the CIELAB values of input RGB image are estimated through the color-mixing model and compared with pre-calculated CIELAB values corresponding to all combination of CMYKlclm colorants with a constraint of color difference, thereby selecting initial CMYKlclm candidates. Next, the limitation on total colorant amount Is imposed on initial CMYKlclm candidates to remove the excessive amounts of colorants, and then final CMYKlclm candidates are determined by minimizing the usage of light cyan and light magenta in the dark region based on the dot visibility ordering of C, M, Y, K, lc, and lm. Through the experiment, the proposed method is shown to reduce the excessive amount of colorants with preserving good image quality.

A Review on the Photochemical Oxidant Modeling as Applied to Air Quality Studies in Complex Terrain

  • Lee Hwa-Woon;Kim Yoo-Keun;Won Gyeong-Mee;Park Jong-Kil
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.1 no.1
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    • pp.19-33
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    • 1997
  • The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorological processes. In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification process through observation is emphasized.

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A study on Interpretating Japanese Menus (일식메뉴 해설에 관한 연구 I)

  • 송청락
    • Culinary science and hospitality research
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    • v.4
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    • pp.211-224
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    • 1998
  • This study is research about coinage and interpretation of Japanese Menus in luxury hotels in Seoul. Japanese Menus consist of three categories. These can be expressed A+B+C groupings. A represents Ingredients, C represents the cooking method, while B shows the name of a region(B1), the seasoning(B2), and a word that expresses the shape of the food(B3), etc. B can be flexible in meaning. However, the setting, A+B+C, is not always used strictly for these category meanings. Ingredients, A, is sometimes used independently(ex, ぃくとろろ), and at other times B1 + C, B2 + C or B3 + C are used. Sometimes A+C is used without B. The most general expression is Ingredients + the method for cooking(A+C Type). By knowing the menu description the food type and cooking method can be discovered. Most concrete method is Ingredients + procedure for seasoning + cooking method(A+B2+C Type) show how something is made and what kind of seasoning. This method is frequently used for roasted dishes with seasoning. Food which is expressed by A, Ingredients, does not require a complicated cooking process and is fixed by a conventional cooking process without any explanation ; delicacies(珍味), an hors d'oeuvres(前菜), sushi(Japanese vinegared rice delicacies) and sliced raw fish. There are two obstacles in interpreting Japanese Menus. First, we cannot look up the menu words easily in a dictionary because the mixing of Chinese Characters and the pronunciation of them differs from Korean chinese characters. Secondly, the names of Japanese food are inserted with a name of a place or another symbolic word, so they sometimes cannot be translated. We should offer various and accurate information for foreign customers because various Non-Japanese people use these restaurants frequently. This will enable them to enjoy themselves more comfortably. Therefore, you should decide the words carefully and provide an explanation about the complicated parts of the Menu when you work with Menu copywriter.

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Etch characteristics of TiN thin film adding $Cl_2$ in $BCl_3$/Ar Plasma ($BCl_3$/Ar 플라즈마에서 $Cl_2$ 첨가에 따른 TiN 박막의 식각 특성)

  • Um, Doo-Seung;Kang, Chan-Min;Yang, Xue;Kim, Dong-Pyo;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.168-168
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    • 2008
  • Dimension of a transistor has rapidly shrunk to increase the speed of device and to reduce the power consumption. However, it is accompanied with several problems like direct tunneling through the gate dioxide layer and low conductivity characteristic of poly-Si gate in nano-region. To cover these faults, study of new materials is urgently needed. Recently, high dielectric materials like $Al_2O_3$, $ZrO_2$, and $HfO_2$ are being studied for equivalent oxide thickness (EOT). However, poly-Si gate is not compatible with high-k materials for gate-insulator. Poly Si gate with high-k material has some problems such as gate depletion and dopant penetration problems. Therefore, new gate structure or materials that are compatible with high-k materials are also needed. TiN for metal/high-k gate stack is conductive enough to allow a good electrical connection and compatible with high-k materials. According to this trend, the study on dry etching of TiN for metal/high-k gate stack is needed. In this study, the investigations of the TiN etching characteristics were carried out using the inductively coupled $BCl_3$-based plasma system and adding $Cl_2$ gas. Dry etching of the TiN was studied by varying the etching parameters including $BCl_3$/Ar gas mixing ratio, RF power, DC-bias voltage to substrate, and $Cl_2$ gas addition. The plasmas were characterized by optical emission spectroscopy analysis. Scanning electron microscopy was used to investigate the etching profile.

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