• Journal of the Korean Crystal Growth and Crystal Technology
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• v.33 no.6
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• pp.226-233
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• 2023

In this study, the basic physical properties and microstructure of concrete interlocking blocks with amount of different CO₂ gas injection were analyzed according to determine the applicability of In-situ carbonation technology to construction secondary products. The amount of carbon dioxide gas injection was selected as 0, 0.1, 0.3, 0.5, 0.7 wt.% compared to cement amount. A lab-scale press equipment was designed to apply developed carbonation technology to real construction site. And mixer for stable CO₂ gas injection was designed. Using the designed devices, CO₂ gas injected samples were created and physical property of samples were performed. As a result of the physical property test, as the CO₂ injection amount increased to 0.3 %, it showed higher strength behavior compared to the original mix. And more than 0.5 % samples showed lower strength behavior than original sample, but they satisfied the standard of concrete interlocking block. This results were determined that CO₂ injection contributed to the creation of hydrates such as C-S-H. Therefore, the possibility of applying carbonation technology, which injects CO₂ during mixing, to various secondary construction products was confirmed.

• Journal of Wetlands Research
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• v.14 no.1
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• pp.75-87
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• 2012

Hyporheic zone is a region beneath and alongside a stream, river, or lake bed, where there is mixing of shallow groundwater and surfacewater. Hyporheic exchange controls a variety of physical, biogeochemical and thermal processes, and provides unique ecotones in a aquatic ecosystem. Field and experimental observations, and modeling studies indicate that hyporheic exchange is mainly in response to pressure gradients driven by the geomorphological features of stream beds. In the reach scale of a stream, pool-riffle structures dominate the exchange patterns. Flow over a pool-riffle sequence develops recirculation zones and stagnation points, and this flow structures make irregular pressure gradient which is driving force of the hyporheic exchange. In this study, 3 D hydro-dynamic model solves the Reynolds-averaged Navier-Stokes equations for the surface water and Darcy's Law and the continuity equation for ground water. The two sets of equations are coupled via the pressure distribution along the interface. Simulation results show that recirculation zones and stagnation points in the pool-riffle structures dominantly control the upwelling and downwelling patterns. With decrease of recirculation zones, length of donwelling zone formed in front of riffles is reduced and position of maximum downwelling point moves downward. The numerical simulation could successfully predict the behavior of hyporheic exchange and contribute the field study, river management and restoration.

• Applied Chemistry for Engineering
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• v.8 no.5
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• pp.763-770
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• 1997

The separation of benzene-cyclohexane mixture using (O/W)/O emulsion liquid membrane was studied. The operating parameters which can affect the selectivity, benzene yield, and emulsion size distribution were examined and determined by the batch type operation. The unsteady state and steady state extraction behavior in continuous pulse stirred reactor(CPSR) were verified. The optimum conditions for benzene selectivity and yield in batch operation were as follows; emulsion mixing intensity 4000 rpm, Tween 80 concentration 0.4%, volume ratio of membrane phase to internal phase 0.75, volume ratio of dispersed phase to continuous phase 0.5, and permeation time 10 minutes, As impeller speed increased and the microdrop holdup decreased, the Sauter mean diameter decreased. Turbulence damping parameter of modified Calabrease correlation considering microdrop holdup was 2.28. The optimum conditions of continuous operation were as follows; agitation speed 300 rpm, pulse frequence 2 times/sec, flow rate of continuous phase 30ml/min, and flow rate of emulsion phase 12.0ml/min.

• Applied Chemistry for Engineering
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• v.9 no.6
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• pp.901-906
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• 1998

Gas and liquid flow characteristics were investigated in an internal circulation airlift reactor using a single nozzle for a gas distributor. In three reactors with different diameters of the downcomer and heights of the riser, the gas holdup in the individual flow zone and the impulseresponse curve of tracer for an air-water system were measured for various gas velocities and reactor heights. Experimental results showed that the flow behavior of bubbles in the riser was the slug flow due to strong coalescences of bubbles and that the bubble flow pattern in the downcomer was the transition bubble flow for the smaller diameter of the downcomer, however, it was the homogeneous bubble flow for the larger one. And mean gas holdups in the individual flow zone and the reactor were greatly increased with decreasing the diameter of the downcomer for the equal ratio of height of the top section to that of the riser. Also, the mixing time was much effected by the height of the top section of reactor and for the equal ratio of height of top section to that of the riser, it was increased with increasing the diameter of the downcomer and the height of the riser. Flow characteristics of liquid were mainly varied with the bubble flow pattern in the downcomer and the size of the top section of reactor. And circulation velocities of liquid in the riser were increased with increasing gas velocities and the size of the top section of reactor, and for the equal ratio of height of top section to that of the riser, they were increased with increasing the diameter of the downcomer and the height of the riser.

• Journal of the Korean Electrochemical Society
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• v.4 no.4
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• pp.139-145
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• 2001

Various compositions of iron oxide based materials as a cathode of lithium secondary battery have been fabricated and tested with electrochemical method. A layered form of $LiFeO_2$ was synthesized by mixing and heating the initial materials of $FeCl_3\;6H_2O,\;LiOH$ and NaOH at low temperature. The effect of changing the precursors composition was investigated. As a result, when increasing the additive amount of NaOH, the capacity of the electrode is decreased but the performance and declining rate of capacity became smaller. $LiFeO_2$ synthesized with the weight ratio of $NaOH/FeCl_3/LiOH,\;2/1/7$ showed the largest capacity, but the discharging efficiency was sharply decreased after 30 cycles. Charge-discharge tests of lithium cells with $LiFeO_2$ cathode having the layer structure were performed. This cell showed the reversibility in the range of 1.5-4.5V of cell voltage. By using CPR method, chemical diffusion coefficients were measured in 1M $LiPF_6/EC/DEC$ solution. The value of chemical diffusion coefficient decreased with increasing the lithium content x, In 0.5$10^{-11}^cm^2/s$.

• Journal of the Korea Concrete Institute
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• v.14 no.5
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• pp.789-795
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• 2002

To evaluate the bind rate and behavior of two types chloride ion-one is the chloride ion added in mixture when un-washed sea sand is used as fine aggregate, one is the chloride ion admitted in the new version of concrete standard specification, pore solution extracted in cement paste were analyzed. The results are follow. 1 As passing the time, the chloride concentration in the pore solution decreases with the Increase in the chloride content absorbed by the hydrate products. As compared with chloride contents in mixing water, the bound ratio of chloride at 49 days is 64∼90％. 2. The bound ratio of chloride in cement paste considering evaporable water as pore solution is obtained. In case of Pl∼P3(added chloride content wt of cement 0.046∼0.16 ％), the bound ratio of chloride is 91.8∼93.5 ％. P4(added chloride wt of cement 0.3％) is 89.1％, but P5(added chloride wt of cement 0.617％) bound is only 77％. 3. The bound ratio of chloride to wt of cement is 0.015∼0.475％ with adding chloride. In case chloride added over 0.091 ％ wt of cement, the bound chloride content increases 1.7∼1.8 times in spite of added chloride increase twice. The bound ratio of chloride to wt of cement decreased with the increase in the chloride content. 4. The more increase added chloride content, the more increase the bound ration of chloride. But the absolute value of chloride content in pore solution increased.

• Journal of the Korean Geosynthetics Society
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• v.14 no.2
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• pp.95-103
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• 2015

In this study, the causes and countermeasures for the leakage of a sea dyke under construction are analyzed. In general, the seabed ground is clearly divided from the embankment but a lot of parts show abnormal zones with low resistivity from the results of electric resistivity survey. Hence the causes of the leakage are considered as following: three-dimensional shear strain behavior, irregular compulsory replacement of the soft seabed ground with low strength and quality deterioration of the waterproof sheets during the closing process. The improvement method is determined by considering the constructability in the seawater and its velocity condition, durability, economic feasibility, similar application cases and so on. Consequently, a combination of low slump mortar and slurry grouting and injection method is selected as an optimum combination. Mixing ratio and improvement pattern are determined after drilling investigation and pilot test. The improvement boundary is separated into general and intense leakage area. The construction is performed with each pattern and the improvement effects are confirmed. The confirmed effects with various tests after completion show tolerable ranges for all of the established standards. Finally, various issues such as prediction of length of the waterproof sheet, installation of it against seawater velocity, etc. should be considered when sea dykes are designed or executed around the western sea which has high tide difference.

• Journal of the Korean Chemical Society
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• v.42 no.1
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• pp.84-91
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• 1998

Random copolymers of N-isopropyl acrylamide (NIPAAm) and acrylic acid (AAc) which exhibit temperature- and pH-responsive behavior were synthesized by free-radical polymerization. The copolymers were characterized by means of FT-IR spectrometry and titration. The influence of polyelectrolyte on the lower critical solution temperature (LCST) of pH/temperature-sensitive polymers was investigated in the pH range of 2-12. The LCSTs of PNIPAAm/water in poly(NIPAAm-co-AAc) were determined by cloud-point measurements. A polyelectrolyte complex was prepared by mixing poly(NIPAAm-co-AAc) with poly(allylamine) (PAA) or poly(L-lysine) (PLL) solutions as anionic and cationic polyelectrolytes, respectively. Back titration was performed to determine the content of AAc and to study the effect of comonomer ionization on the LCST. The LCSTs of PNIPAAm/water in the copolymers were strongly affected by pH, presence of polyelectrolyte, AAc content, and charge density on the polymer. The polyelectrolyte complexes were formed at neutral condition. The influence of more hydrophobic PLL as polyelectrolyte on the cloud-point of PNIPAAm/water in the copolymer was stronger than that of poly(allylamine) (PAA).

• Polymer(Korea)
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• v.29 no.3
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• pp.282-287
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• 2005

A novel ice particle leaching method for fabrication of porous and biodegradable PLGA scaffold has been proposed for the application to tissue engineering. After uniform mixing of poly(L-lactide-co-glycolide) (PLGA) and bovine serum albumin-fluorescein isothiocyanate (FITC-BSA), the FITC-BSA loaded scaffold was fabricated by adding various ratio of ice particle. The release profiles of FITC-BSA were examined using pH 7.4 PBS for 28 days at $37^{circ}$. The release amount was determined by fluorescence intensity by using the fluorescence spectrophotometer and the morphological change of the scaffolds was observed by scanning electron microscope. The release initial burst of BSA containing scaffolds was lower than that of simple dipping scaffolds resulting in constant release aspect. Although the BSA concentration increased. the initial burst was not increased. As a result of this study, it can be suggested that ice particle leaching method for the tissue engineered scaffold miff be very useful and it is possible to impregnate with water soluble factors like cytokine. We suggest that ice particle leaching method may be useful to tissue engineered organ regeneration.

• Journal of Conservation Science
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• v.26 no.3
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• pp.229-245
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• 2010

The pupose of this study was to identify the material characteristics, firing environments and making techniques for the jar coffins from the Oryangdong kiln site and the Ungokdong tomb site in Naju. All jar coffins had very similar physical, mineralogical and geochemical characteristics, although it was excavated from the different sites. The wall thickness of the jar coffins was about 2.3 to 5.3 cm. Under the microscopy, the jar coffins include a large quantity of various quartz with some microcrystalline and showed partly orthoclase and biotite. It is presumed that the mineral sherds added to maintain the thick wall and to control the percentage of contraction during drying and firing of jar coffins and it has contained about 11.4 to 19.8 %. Firing temperature of the jar coffins is estimated as 1,000 to $1,150^{\circ}C$. Also, all jar coffins and soils show similar geochemical behavior of elements and clay-mineralization degree within the site. This indicates making that the soil is probable to be a raw material of the jar coffins. But it shows different characteristics in major elements of soils which is collected at the kiln floor and the trench region of the Oryangdong kiln site because of the lack of quartz and feldspar in the soils. Therefore, it can use of the jar coffins making clay, if it goes through a simple special process such as mixing temper.