• Title/Summary/Keyword: Mineral particle

Search Result 441, Processing Time 0.023 seconds

Differentiation of Sorptive Bindings of Some Radionuclides with Sequential Chemical Extractions in Sandstones (순차적화학추출법을 사용한 방사성핵종의 사암에 대한 수착유형 평가)

  • Park, Chung-Kyun;Hahn, Pil-Soo;Park, Hun-Hwee
    • Nuclear Engineering and Technology
    • /
    • v.26 no.4
    • /
    • pp.461-470
    • /
    • 1994
  • Sorption experiments of $^{60}$ Co, $^{85}$ Sr. and $^{137}$ Cs onto sandstone particles in a batch were carried out to investigate the migration mobility. Sorption kinetics and reversibility as well as sorption mechanisms were examined. Sorption reaction occurred mostly within 10 hours on the outer surface of the sandstone particle but diffusion into the inner surface of the mineral has still occurred after that time. In order to distinguish sorption types of radionuclides, a sequential chemical extraction was introduced. The sorbed radionuclides were then extracted by applying different solutions of synthetic groundwater, CaCl$_2$, KCl and KOX-HA Especially KCl is adopted to extract the ion-exchanged cesium. Sorption types considered are reversible sorption under groundwater condition, ion exchange, association with ferro-manganese oxides or oxyhydroxides, and irreversible fixation. Strontium sorbs onto the sandstone surface mainly by fast and reversible ion exchange reaction. However, cobalt and cesium do not sorb by simple process. The main sorptive binding of cobalt was the association with ferro-manganese oxides and the secondary one was irreversible fixation. Diffusion into the lattice of minerals controlled the sorption rate of cobalt The main sorptin type of cesium was irreversible fixation, while ion exchange reaction was the secondary importance. Hence the oreder of migration mobility for the three radionuclides was Sr$^{2+}$ > Co$^{2+}$ > Cs$^{+}$ in the sandstones.

  • PDF

Effect of extraction method on quality characteristics of the carrot juice (주스착즙 방식에 따른 당근 주스의 품질 특성 변화)

  • Park, Hye-Jung;Kim, Ji-Youn;Lee, Song Min;Kim, Hee Sook;Lee, Sang-Hyeon;Lee, Mun Hyon;Jang, Jeong Su
    • Korean Journal of Food Science and Technology
    • /
    • v.51 no.4
    • /
    • pp.369-378
    • /
    • 2019
  • This study aimed to compare the quality characteristics of carrot juice based on different extraction methods such as centrifugation, single gear, and twin gear methods. Juice quality was evaluated based on extraction yield, nutritional components, and cloud stability. Twin gear extraction resulted in the highest extraction yield, and the highest mineral content. In addtion, ${\beta}$-carotene level higher than the recommended daily intake was obtained only in the carrot juice prepared using twin gear extraction of 100 g carrots. The minimum particle size was observed in twin gear extraction, followed by single gear extraction and centrifugation method. Therefore, twin gear extraction was selected as the optimal method, and changes in the antioxidant and metabolic activity of carrot juice were investigated using this method. Consequently, the carrot juice showed a higher lipid peroxidation inhibition rate than ${\alpha}$-tocopherol (1 mg/mL), and angiotensin I-converting enzyme (ACE) inhibitory activity was increased upon digestion.

Development of Numerical Model for Simulating Remediation Efficiency Using Surfactant in a NAPL Contaminated Area (계면활성제에 의한 NAPL 오염의 정화효율 수치 모의를 위한 모델 개발)

  • Suk, Heejun;Son, Bongho;Park, Sungmin;Jeon, Byonghun
    • Clean Technology
    • /
    • v.25 no.3
    • /
    • pp.206-222
    • /
    • 2019
  • Recently, various multiphase flows have been developed, and among them some models have been commercialized. However, most of them have been developed based on a pressure-based approach; therefore, various numerical difficulties were involved inherently. Accordingly, in order to overcome these numerical difficulties, a multiphase flow model, MultiPhaSe flow (MPS), following a fractional-flow based approach was developed. In this study, by combining a contaminant transport module describing an enhanced dissolution effect of a surfactant with MPS, a MultiPhaSe flow and TranSport (MPSTS) model was developed. The developed model was verified using the analytical solution of Clement. The MPSTS model can simulate the process of surfactant enhanced aquifer remediation including interphase mass transfer and contaminant transport in multiphase flow by using the coupled particle tracking method and Lagrangian-Eulerian method. In this study, a surfactant was used in a non aqueous phase liquid (NAPL) contaminated area, and the effect of hydro-geological heterogeneity in the layered media on remediation efficiency was studied using the developed model. According to the numerical simulation, when hydraulic conductivity in a lower layer is 10 times, 20 times, and 50 times larger than that in an upper layer, the concentration of dissolved diesel in the lower layer is much higher than that in the upper layer because the surfactant moves faster along the lower layer owing to preferential flow; thus, the surfactant enhances dissolution of residual non aqueous phase liquid in the lower layer.

A study on the Red Painting of stone monuments (비석(碑石)에 칠해진 주사(朱砂)안료에 관한 연구)

  • Shin, Eun-Jung;Han, Min-Su;Kang, Dai-Il
    • Korean Journal of Heritage: History & Science
    • /
    • v.38
    • /
    • pp.359-385
    • /
    • 2005
  • Red ocher, red lead or cinnabar has been as red colorant for ages. Cinnabar of the red pigments has been highly regarded as a valuable ingredient because it represent a symbol of exorcising and a haute image. It was used as a pigment of painting and mural painting, bowl, clothes, rock writing, gravestone, etc. It is powder which dissolves in perilla oil or glue before using. Because it is high-priced, the use of cinnabar may be limited to the privileged class. Therefore, red ocher or red lead was used instead of cinnabar. "Gongsagyunmunrok" demonstrated that government official's gravestonea has been painted red by two colorants in the period of the Goryeo dynasty. However, cinnabar may be used to paint gravestones for the first time in the period of the Three States because it has been transmitted since the times. This study discuss the results obtained from an analysis of the pigments used on the red pigments of the Stone Monuments. The results can be briefly summarized as below; First, the microcrystalline structures seen on the surface section of analyzed pigments, samples of which were taken from various parts of red pigments show that different sizes and shapes of pigment particle. Second, a result of the analysis on the composition and structure of the pigments shows that the main components in their composition are : Red pigments - Red lead($Pb_3O_4$), Cinnabar(HgS) and Hematite($Fe_2O_3$) White pigments - Calcite($CaCO_3$) Especially, we knew that red Stone Monuments were found to be natural mineral pigments, which were used as a singular or a mixture.

Soil Properties of Granitic Weathered Soils in the Landslide-prone Areas in Seoul (서울지역 화강암 풍화토 토층지반의 토질특성)

  • Kim, Kyeong-Su
    • The Journal of Engineering Geology
    • /
    • v.29 no.1
    • /
    • pp.23-35
    • /
    • 2019
  • Landslides occur due to heavy rainfall in the summer season. Some of water may infiltrate into the ground; it causes a high saturation condition capable of causing a landslide. Soil properties are crucial in estimating slope stability and debris flow occurrence. The main study areas are Gwanaksan, Suraksan and Bukhansan (Mountain) in Seoul. A total of 44 soil samples were taken from the study area; and a series of geotechnical tests were performed. Physical and mechanical properties were obtained and compared based on region. As a result, among well-graded soils, they are classified as a clayey sand. Coarse-grained and fine-grained contents are approximately 95% and 5%, respectively, with very low amount of clay content. Density, liquid limit and dry unit weight are ranged in $2.62{\sim}2.67g/cm^3$, 27.93~38.15% and $1.092{\sim}1.814g/cm^3$. Cohesion and internal friction angle are 4 kPa and $35^{\circ}$ regardless of mountain area. Coefficient of permeability is varied between $3.07{\times}10^{-3}{\sim}4.61{\times}10^{-2}cm/sec$; it means that it results in great seepage. Permeability is inversely proportional to the uniformity coefficient and is proportional to the effective particle size. In the formal case, there was a difference by mountain area, while in the latter, the tendency was almost similar.

Analysis of electrical resistivity characteristics according to the mixing ratio of coarse fillings in artificial rock joint (인공 암반절리의 조립토 충진물 혼합비에 따른 전기비저항 특성 분석)

  • Haeju Do;Tae-Min Oh;Hangbok Lee
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.25 no.2
    • /
    • pp.141-155
    • /
    • 2023
  • Monitoring technology based on electrical resistivity is widely used for non-destructive data collection and health analysis of underground structures and tunnels. Vulnerable sections such as fault zone generates many problems during construction of the tunnel. These problems cause displacement and stress changes of the ground. Therefore, it is necessary to predict the state of the fault zone section to ensure the mechanical stability of the underground structure. Monitoring the size of joints and the porosity of the fillings is essential for rocks. Previous studies have not considered the variety of fillings in rock joints. In this study, electrical resistivity tests were conducted according to the particle mixing state of the sandy fillings. When the size of fillings is decreased at the constant porosity, the electrical resistivity tends to increase. The results of this study are expected to be useful as basic electrical resistivity data for predicting the ground conditions and evaluation of the ground behavior that is containing sandy fillings in the rock joint for tunnels.

Quality Enhancement of Recycled Concrete Aggregates for Backfill Materials by CO2 Carbonation: Development of a 5-kg-scale Prototype Reactor (이산화탄소의 탄산화 반응을 이용한 되메움재용 순환골재의 품질 개량: 5kg급 프로토타입 반응조 개발)

  • Kim, Jinwoo;Jeon, Min-Kyung;Kwon, Tae-Hyuk;Kim, Nam-Ryong
    • Journal of the Korean Geotechnical Society
    • /
    • v.40 no.1
    • /
    • pp.29-37
    • /
    • 2024
  • In this study, recycled concrete aggregates (RCA) were treated in a 5-kg-scale prototype reactor with carbon dioxide (CO2) to enhance their material quality and geotechnical performance. The aggregate crushing value (ACV) and California bearing ratio (CBR) were measured on untreated RCAs and CO2-treated RCAs. After CO2 treatment, the ACV decreased from 35.6% to 33.2%, and the CBR increased from 97.5% to 102.4%. The CO2 treatment caused a reduction of fine particle generation and an increase in bearing capacity through carbonation. When CO2 treatment was performed with mechanical agitation, which provided additional enhancement in mechanical quality, the ACV was reduced further to 30.3%, and the CBR increased to 137.7%. If upscaled effectively, the proposed CO2 treatment technique would be an effective method to reduce carbon emissions in construction industries.

Characteristic analysis of mortar using desulfurization gypsum and carbon dioxide conversion capture materials as a cement admixture (탈황석고와 탄산화물을 혼합재로 사용한 모르타르의 특성 분석)

  • Hye-Jin Yu;Sung-Kwan Seo;Yong-Sik Chu;Keum-Dan Park
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.34 no.3
    • /
    • pp.86-91
    • /
    • 2024
  • In this study, the characteristics of mortar using carbondioxide conversion capture materials (CCMs), fabricated by reacting CO2 with desulfurization gypsum (DG) by-produced from a oil refinery, as a cement mixture. Based on the chemical component and particle size analysis results, it estimated that desulfurized gypsum reacted with carbon dioxide to produce carbonate crystals such as CaCO3. Using CCMs as a cement mixture, physical property and durability analysis were conducted by measuring such as workability, compressive strength, compressive strength ratio after freezing-thawing and accelerated carbonation depth. The experimental results showed that as the content of the admixture increased, workability and compressive strength characteristics decreased. Compressive strength after freezing-thawing and accelerated carbonation depth also showed similar characteristics to the physical property measurement results. In addition, compared to desulfurized gypsum, using CCMs showed better physical properties and durability. This was assumed to be due to differences in the crystal phases of the mixed materials such as free-CaO and CaCO3.

Development of Korean Lunar Highland Soil Simulant (KIGAM-L1) (한국형 달 고원 모사토(KIGAM-L1) 개발)

  • Tae-Yun Kang;Eojin Kim;Kyeong Ja Kim
    • Journal of Space Technology and Applications
    • /
    • v.4 no.2
    • /
    • pp.121-136
    • /
    • 2024
  • Korea Pathfinder Lunar Orbiter (KPLO), launched in August 2022, is successfully carrying out its mission. Korea's lunar lander and rover programs are expected to proceed in the future. To successfully carry out the mission after the lunar lander has landed on the surface, the performance of the equipment to be mounted should be checked in a laboratory environment similar to the Moon. Scientists and engineers of several countries, including the United States and China, use lunar soil simulant which is developed to resemble lunar soil for simulating the surface of the lunar landing site. Several lunar probe landing sites are being discussed in Korea, and lunar soil simulants such as Korea Hanyang Lunar Simulant-1 (KOHLS-1), Korea Aerospace University Mechanical Lunar Simulants (KAUMLS), and Korea Lunar Simulant-1 (KLS-1), which are similar to the characteristics of lunar mare soil, have been developed. However, those simulants are not useful if the landing site is chosen as a highland area. In this study, we introduce the process of developing KIGAM-L1, a lunar highland soil simulant similar to the chemical composition of the Apollo 16 lunar soil sample and the particle size distribution of lunar soil sample 60500-1, in case the lunar lander lands at highland area.

Precise Diagnosis and Conservation Treatment of the Twin-lion Stone Lantern from the Godalsa Temple Site, Yeoju (여주 고달사지 쌍사자 석등의 정밀진단 및 보존처리)

  • National Museum of Korea Conservation Science Division;Damwon Cultural Heritage Inc.;Man Gyeong Corp.
    • Conservation Science in Museum
    • /
    • v.31
    • /
    • pp.71-103
    • /
    • 2024
  • The National Museum of Korea Conservation science division conducted a precise diagnosis and a non-destructive investigation to comprehensively assess the overall damage of the Twin-lion stone lantern from the Godalsa Temple site, Yeoju to be placed on display in the museum's outdoor stone garden, then reviewed the relevant conservation and management plan and applied conservation treatment to the artifact. The museum carried out the treatment in the following order: precise diagnosis; dismantling of the previously-restored part of the roof stone; reinforcement and restoration of the roof structure with new stone; restoration of the previously-restored part of the lantern's support stone (jungseok); surface texture treatment to the restored area; cleaning (basic, laser); and color matching. The previously-restored part of the roof stone was removed and restored with new stone material, based on the results of a safety diagnosis regarding the separation at the said part. Granite from the Sangju area was selected as the material for the restoration in consideration of the results of mineral analysis as well as the surface color and particle size. The new stone was divided into three pieces based on the descending edges of the octagonal roof structure and joined together using epoxy resin. The structure was further strengthened by inserting titanium rods. It is expected that the status diagnosis and conservation treatment of the twin-lion stone lantern from the Godalsa Temple site in Yeoju will be used as a reference for the future conservation and management of outdoor displays of stone cultural heritage.