• Rapid Communication in Photoscience
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• v.3 no.4
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• pp.64-66
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• 2014

Synthesis of a deuterium-labeled derivative of nitrospirobenzopyran (NSP), one of representative photochromic compounds, has been described. Four deuteriums were successfully introduced on 1-methyl and ${\alpha}$-methyne relative to spiro-carbon in the title compound with more than 95atom%D purity. Main photodegraded products of NSP were two oxindoles in acetonitrile, and additional products were formed in poly(isobutyl-methacrylate) films possibly due to restricted molecular motion in polymer matrix. Quantitative HPLC analysis revealed that partial introduction of deuterium to NSP brought a noticeable isotope effect, recognizable enhancement in photo-resistivity of NSP, i.e.,8.3% in solutions and 29% in polymeric films.

• Proceedings of the IEEK Conference
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• 2006.06a
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• pp.981-982
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• 2006

In this study, the synthesis and semiconducting properties of cation and defect-doped KTaO3 film is reported. KTaO3is an important material for optoelectronic and tunable microwave applications. It is an incipient ferroelectric with a cubic structure that becomes ferroelectric when doped with Nb. the films were grown on (001) MgO single crystal substrates using pulsed-laser deposition. Semiconducting behavior is achieved by inducing oxygen vacancies in the KTaO3 lattice via growth in a hydrogen atmosphere. The resistivity of semiconducting KTaO3:Ca films was as low as 10cm, and n-type semiconducting behavior was indicated. Hall mobility and carrier concentration were 0.27 cm2/Vs and 3.21018cm-3.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.26 no.12
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• pp.1031-1043
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• 2015

This paper describes the pattern synthesis method of two kinds of conformal array antenna using the Enhanced Adaptive Genetic Algorithm (EAGA). One is the $1{\times}16$ conformal array antenna on a curved cylindrical metallic surface with quadratic function, and the other is the 18-element conformal arrary antenna on a metallic surface obtained by the rotation of a quadratic function curve around the axis. The active element pattern is utilized in the pattern synthesis. Especially for the case of the rotated-type conformal array antenna the transformed active element pattern obtained from the Euler's angle rotation of the active element pattern of the planar concentric array is utilized, which reduces the synthesis time a lot. To verify the validity of the proposed synthesis method the MATLAB results are compared with the MWS results. Furthermore, for the case of $1{\times}16$ conformal array antenna the measured results are compared with the MATLAB synthesized results.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.46 no.11
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• pp.50-55
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• 2009

In this paper, a distributed amplifier is designed using distributed network synthesis that provides the optimum absorption capability of a capacitance. Transfer functions of filters, which consist of the amplifier, are synthesized by a low-pass Chebyshev approximation. Capacitances that a filter network can absorb are calculated as a function of its minimum insertion loss(MIL) and ripple. Active devices in a distributed amplifier are modeled as equivalent circuits by using their S-parameters, and their equivalent capacitances are absorbed into filter structures by properly adjusting the MIL and ripple of a transfer function. As an application example, a distributed amplifier with the gain of about 12.5dB is designed that operates over the frequency range between 0.1 and 7.5GHz. Experimental results prove that distributed network synthesis, which considers capacitance absorption capability, is useful to the design of distributed amplifiers.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2835-2840
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• 2010

A series of $MoO_3/CeO_2-ZrO_2$ catalysts with different Mo content (8 - 20 wt %) were prepared by simple co-precipitation followed by impregnation method and were characterized by X-ray diffraction (XRD), infrared spectroscopy (IR), scanning electron microscopy (SEM), energy dispersive spectroscopic (EDS) techniques. The prepared materials were tested for catalytic activity by the synthesis of benzimidazole derivatives using condensation of aromatic aldehydes and o-phenylenediamine by conventional and microwave method. Obtained results reveal that the catalytic activity increases with increase in Mo wt % loading. The best catalytic activity was obtained with 20 wt % $MoO_3/CeO_2-ZrO_2$. The particle size or crystallite size was estimated using Debye-Scherrer equation. After completion of reaction, the catalyst can be recovered efficiently and reused with consistent activity.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.17 no.10 s.113
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• pp.929-934
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• 2006

In the paper, we suggest a simpler synthesis technique for capacitively-coupled match circuit(CCMC) which have a function of DC block and impedance matching simultaneously, and introduce a stability margin analysis technique for designing microwave amplifier under conditionally stable state. Stability margin analysis is used to determine optimum match point that ensure maximum gain under the given stability margin. It can reduce time consuming work for selecting match points in the conditionally stable state. Also, suggested miniaturization scheme of matching network is distinguished from previous work with respect to reducing deterministic parameters for CCMC synthesis. To verify utility of suggested method, 24 GHz gain block is fabricated under conditionally stable state using an internal thin-film fabrication process, Measured results show a stable gain of 10 dB and flatness of 1 dB, which is well coincident with simulated one.

• The Korean Journal of Pesticide Science
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• v.11 no.1
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• pp.1-7
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• 2007

We have developed an efficient synthesis of 2(5H)-furanones using the microwave-promoted Suzuki-Miyaura coupling reaction and evaluated their fungicidal activities against six fungal pathogens in vivo. In addition, 2-cyclopentenones or 2-cyclohexenones possessing one or two additional methylene groups instead of the oxygen in the 2(5H)-furanone skeleton were also prepared by using the similar method. As the results of in vivo fungicidal screening against 6 plant diseases, a few derivatives displayed specific fungicidal activities against rice blast and tomato late blast. Further studies toward the optimization of the chemical structures are necessary for the development of novel fungicides with high potency.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.199-199
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• 2011

The addition of a carbanion to ${\yen}{\acute{a}}{\yen}{\hat{a}}$-unsaturated carbonyl compounds is of importance in the C-C bond formation reactions for modern pharmaceuticals and organic synthesis. Recently, heterogeneous asymmetric catalysis became more attractive area of research because of the easy recovery and separation of the catalyst from the reaction system. Most of synthetic methods for heterogeneous catalysts were grafting or immobilization of homogeneous catalyst onto the solid supports. Trans-1,2-Diaminocyclohexane(DACH) and L-proline ligands have been enormously used as chiral ligands in several catalytic transformation under homogenous conditions. Our group prepared l-proline functionalized mesoporous silica was synthesized under acidic condition using a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer template (EO20PO70EO20, Pluronic P-123, BASF). Furthermore, we successfully directly synthesized trans-1,2 diaminocyclohexane functionalized mesoporous silica by using microwave method. The direct functionalization of chiral ligand into the framework of mesoporous materials is expected to be useful for the heterogeneous asymmetric catalysis. So, we adopt the direct synthesis of chiral ligand functionalized mesoporous silica by using thermal and microwave irradiation. Then, chiral ligand functionalized mesoporous silicas were applied to enantioselective asymmetric catalytic reactions.

• Journal of the Korean Chemical Society
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• v.51 no.6
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• pp.506-512
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• 2007

Various long chain aliphatic acid hydrazides react with aromatic and heterocyclic aldehydes in alcoholic medium in refluxing conditions to give corresponding 2-hydroxy benzylidene and 1H-indol-3-ylmethylene hydrazides, a newer class of mosquito para-pheromones. We describe here synthesis of various novel long chain aliphatic acid (2- hydroxy benzylidene and 1H-indol-3-ylmethylene) hydrazides by conventional as well as microwave irradiation techniques. The structures of these compounds have been confirmed by spectroscopic techniques (FTIR, NMR & MS). Some of the interesting features of the electron impact mass spectral fragmentation pattern of these compounds have also been discussed.

• Journal of the Korean Chemical Society
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• v.55 no.6
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• pp.1007-1011
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• 2011

Dioctyl succinates and succinic anhydride were synthesized from succinic acid in the presence of a cation exchange resin, Amberlite IR-120. The synthesis of dioctyl succinate from succinic acid and octanol was perfomed in 18 h reflux condition with Amberlite IR-120 and the isolated yield of product was over 90%. For the synthesis of succinic anhydride, succinic acid was refluxed in isopropenyl acetate for 18 h with Amberlite IR-120 as a catalyst. The long reaction time was significantly reduced to less than 10 min under microwave irradiation. The catalyst was reusable at least 4 times with keeping product yield of higher than 80%.