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http://dx.doi.org/10.5012/jkcs.2011.55.6.1007

Chemical Transformation of Succinic Acid by Using Amberlite IR-120 and the Reusability of Catalyst  

Lee, Byong-Wook (Department of Chemistry, Chungnam National University)
Kim, Hwang-Min (Department of Chemistry, Chungnam National University)
Kim, Young-Wun (Chemical Biotechnology Research Center for Green Chemistry Catalyst, Korea Research Institute of Chemical Technology)
Kim, Yeong-Joon (Department of Chemistry, Chungnam National University)
Publication Information
Journal of the Korean Chemical Society / v.55, no.6, 2011 , pp. 1007-1011 More about this Journal
Abstract
Dioctyl succinates and succinic anhydride were synthesized from succinic acid in the presence of a cation exchange resin, Amberlite IR-120. The synthesis of dioctyl succinate from succinic acid and octanol was perfomed in 18 h reflux condition with Amberlite IR-120 and the isolated yield of product was over 90%. For the synthesis of succinic anhydride, succinic acid was refluxed in isopropenyl acetate for 18 h with Amberlite IR-120 as a catalyst. The long reaction time was significantly reduced to less than 10 min under microwave irradiation. The catalyst was reusable at least 4 times with keeping product yield of higher than 80%.
Keywords
Microwave irradiation; Succinic anhydride; Esterification; Reuseability; Cation exchange resin;
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