• Bulletin of the Korean Chemical Society
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• v.35 no.10
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• pp.2917-2921
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• 2014

Cerium-activated yttrium aluminate ($Y_3Al_5O_{12}:Ce^{3+}$) exhibiting a garnet structure has been widely utilized in the production of light emitting diodes (LEDs) as a yellow emitting phosphor. The commercialized yttrium aluminum garnet (YAG) phosphor is typically synthesized by a solid-state reaction, which produces irregular shape particles with a size of several tens of micrometers by using the top-down method. To control the shape and size of particles, which had been the primary disadvantage of top-down synthetic methods, we synthesized YAG:Ce nanoparticles with a diameter of 500 nm using a coprecipitation method under the atmospheric pressure without the use of template or special equipment. The precursor particles were formed by refluxing an aqueous solution of the nitrate salts of Y, Al, and Ce, urea, and polyvinylpyrrolidone (55 K) at $100^{\circ}C$ for 12 h. YAG:Ce nanoparticles were formed by the calcination of precursor particles at $1100^{\circ}C$ for 10 h under atmospheric conditions. The phase identification, microstructure, and photoluminescent properties of the products were evaluated by X-ray powder diffraction, scanning electron microscopy, absorption spectrum and photoluminescence analyses.

• Proceedings of the KWS Conference
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• 2005.06a
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• pp.276-278
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• 2005

Bridge constructed recently is preferred to have a long span and a simple structure detail considering not only functions as bridge but scenic beauty, maintenance, construction term and life cycle cost, etc. Therefore, it demands a high quality steel like a thick plate steel and a high performance steel. A TMCP steel produced by theme-mechanical control process is now spotlighted due to the weldability for less carbon equivalent. It improved at strength and toughness in microstructure. Resently the SM570-TMC steel, a high strength TMCP steel whose tensile strength is 600MPa, is developed and applied to steel structures. But, for the application of this steel to steel structures, it is necessary to elucidate not only the material characteristics but also the mechanical characteristic of welded joint. In this paper, we investigated the characteristics of residual stresses generated by welding of SM570-TMC steels through an experimental study

• Journal of Welding and Joining
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• v.32 no.1
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• pp.53-60
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• 2014

The automatic arc welding is generally accepted as the preferred joining technique and commonly chosen for assembly of large metal structures such as in areas of automotive, aircraft and shipbuilding due to its joint strength, reliability, and low cost compared to other joint processes. Recently, several mathematical models have been developed and studied for control and monitoring welding quality, productivity, microstructure and weld properties in arc welding processes. This study indicates the prediction of process parameters for the expected welding quality with accordance to the adaptive GTA welding process. Furthermore, the mathematical models is also develop to aid the selection of an optimal welding process as the generation of process controls to predict the bead geometry as a function output parameters in the GTA welding process. The developed models through this study showed comparatively excellent predicted results, and will extend to other welding processes to integrate an optimized system for the robotic welding process.

• Journal of the Korean Graphic Arts Communication Society
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• v.23 no.2
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• pp.117-128
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• 2005

Printing inks are basically dispersions of solid pigment particles in a vehicle. Pigment flocculation and/or colloidal aggregates created by thixotrope additives form a three- dimensional network in the inks. This structure complicates the flow behaviour of inks. However, if the internal structure is formed under control, the printing process will benefit from it because the ink must satify rheological requirements over a very wide range of shear conditions. The presence of internal structure results in the following prominent non-Newtonian rheological properties: viscoelasticity, yield stress, shear thinning and thixotropy. If the components of printing inks were changed, the rheological characteristics such as viscosity, yield stress, viscoelasticity and tack value were considerably varied. Thus, in this paper, the effects of changing the content of rosin modified phenolic resin on rheological properties of the vehicle will be studied. For that, the rheological properties were found by flow, yield stress, creep and oscillation measurements using Bohlin C-VOR Rotational Rheometer. And Emulsion rheology and its microstructure will be investigated.

• Journal of Powder Materials
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• v.18 no.5
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• pp.443-448
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• 2011

The HDDR(hydrogenation-disproportionation-desorption-recombination) process can be used as an effective way of converting no coercivity Nd-Fe-B material, with a coarse $Nd_2Fe_{14}B$ grain structure to a highly coercive one with a fine grain. Careful control of the HDDR process can lead to an anisotropic $Nd_2Fe_{14}B$ without any post aligning process. In this study, the effect of hydrogen gas input at various temperature in range of $200{\sim}500^{\circ}C$ of hydrogenation stage (named Modified-solid HDDR, MS-HDDR) on the magnetic properties has been investigated. The powder from the modified-solid HDDR process exhibits Br of 11.7 kG and iHc of 10.7 kOe, which are superior to those of the powder prepared using the normal HDDR process.

• Journal of the Korea Concrete Institute
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• v.17 no.6 s.90
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• pp.1053-1064
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• 2005

The mechanical damage of concrete is normally attributed to the formation of microcracks and their propagation and coalescence into macroscopic cracks. This physical degradation is caused from progressive and hierarchical damage of the microstructure due to debonding and slip along bimaterial interfaces at the mesoscale. Their growth and coalescence leads to initiation of hairline discrete cracks at the mesoscale. Eventually, single or multiple major discrete cracks develop at the macroscale. In this paper, from this conceptual model of mechanical damage in concrete, the computational efforts were made in order to characterize physical cracks and how to quantify the damage of concrete materials within the laws of thermodynamics with the aid of interface element in traditional finite element methodology. One dimensional effective traction/jump constitutive interface law is introduced in order to accommodate the normal opening and tangential slips on the interfaces between different materials(adhesion) or similar materials(cohesion) in two and three dimensional problems. Mode I failure and mixed mode failure of various geometries and boundary conditions are discussed in the sense of crack propagation and their spent of fracture energy under monotonic displacement control.

• Journal of the Korean Ceramic Society
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• v.36 no.4
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• pp.432-443
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• 1999

The self-toughened Si3N4 ceramics where needle-like coarse ${\beta}$-Si3N4 grains were dispersed within fine-grain-ed matrix were prepared via hot-prssing at 1730$^{\circ}C$ for 2 h using 5 vol% ${\beta}$-Si3N4 whiskers as a seed. In this study the microstructures and mechanical properties of self-toughened Si3N4 ceramics were investigated. The flexural strength of self-toughened Si3N4 ceramics was increased from 600-800 MPa of the Si3N4 monolith to 830-1025 MPa. The KIC was also increased from 4.0-5.0MPa$.$m1/2 of the Si3N4 monolith to 5.8-6.5MPa$.$m1/2$.$The needle-like coarse Si3N4 grains in self-toughened ceramics were considered to induce various toughening mechanisms including the crack deflection pull-out and bridging and to contribute to KIC improvement. In ad-dition to toughening mechanisms the KIC improvement was considered to be partially indebted also to the orien-tation of large ${\beta}$-Si3N4 grains and to the promoting effect of ${\beta}$-Si3N4 whiskers on the ${\alpha}$ to ${\beta}$ transtion.

• Journal of the Korean Ceramic Society
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• v.36 no.5
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• pp.471-477
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• 1999

Fe and Fe-Mo binder were used to produce TiB2 based cermet by a pressureless sintering. The densification behaviour of TiB2-Fe-Mo cermet during liquid-phase sintering in argon was studied in relation to binder phase charactertics. The effects of Mo addition and sintering condition on the sintering behaviour and mechanical properties were also investigated. TiB2-based cermets with Fe-Mo binder composition showed a better sinterability than the cermets with only Fe binder. In TiB2-Fe-Mo cermet higher densities in the wide temperature range were obtained and also fully densified sintered cermet were obtained at 1873K The enhancement in the densification phenomenon of TiB2-Fe-Mo system can be explained by improved liquid phase wettability associated with the roles of Mo components as solute atoms. When Fe-Mo binders were used cermets with a finer grain size and enhanced mechanical properties wereproduced and new phases such as Fe2B and Mo2FeB2 were observed in the sintered cermet. The highest bending strength was obtained from the 20vol% Fe-Mo cermet and these hardness-fracture toughness combination in the wide binder compositions is better than that of TiB2-Fe cermet. In order to improve mechanical properties microstructure control with high purity powders is desirable because high purity powders prevent the formation of Fe2B and Mo2FeB2 phase which comsume the ductile binder phase.

• Journal of the Korean Ceramic Society
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• v.50 no.6
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• pp.446-450
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• 2013

TRISO coated particles with a ZrC barrier layer were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for a use in a very high temperature gas-cooled reactor (VHTR). The ZrC layer was deposited by the reaction between $ZrCl_4$ and $CH_4$ gases at $1500^{\circ}C$ in an $Ar+H_2$ mixture gas. The amount of free carbon codeposited with in ZrC was changed by controlling the dilution gas ratio. Near-stoichiometric ZrC phase was also deposited when an impeller was employed to a $ZrCl_4$ vaporizer which effectively inhibited the agglomeration of $ZrCl_4$ powders during the deposition process. A near-stoichiometric ZrC coating layer had smooth surface while ZrC containing the free carbon had rough surface with tumulose structure. Surface roughness of ZrC increased further as the amount of free carbon increased.

• Progress in Superconductivity and Cryogenics
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• v.21 no.4
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• pp.19-23
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• 2019

A large grain YBCO bulk superconductor is fabricated by the top-seeded melt growth (TSMG) method. In the TSMG process, the seed crystal is placed on the top surface of a partially melted compact and therefore the seed crystal is frequently tilted during the melt process due to intrinsic unstable nature of Y211 particle +liquid phase mixture. In this work, we report the successful growth of single-domain YBCO bulk superconductors by a bottom-seeded melt growth (BSMG) method. Investigations on the trapped magnetic field and the microstructures of the synthesized specimens show that a bottom-seeded melt growth method has hardly affected on the crystal growth behavior, the microstructure development and the magnetic properties of the large grain YBCO bulk superconductors. The bottom-seeded melt growth method is clearly beneficial for the stable control of seed orientation through the melt process for the fabrication of a large grain YBCO bulk superconductor.