• Journal of Electrochemical Science and Technology
• /
• 제11권4호
• /
• pp.330-335
• /
• 2020

Silicon surface nanostructures, which can be easily prepared by electrochemical etching, have attracted considerable attention because of its useful physical properties that facilitate application in diverse fields. In this work, electrochemical and electrochemical-scanning tunneling microscopic (EC-STM) techniques were employed to study the evolution of surface morphology during the electrochemical etching of Si(111)-H in a fluoride solution. The results exhibited that silicon oxide of the Si(111) surface was entirely stripped and then the surface became hydrogen terminated, atomically flat, and anisotropic in the fluoride solution during chemical etching. At the potential more negative than the flat band one, the surface had a tendency to be eroded very slowly, whereas the steps of the terrace were not only etched quickly but the triangular pits also deepened on anodic potentials. These results provided information on the conditions required for the preparation of porous nanostructures on the Si(111) surface, which may be applicable for sensor (or device) preparation (Nanotechnology and Functional Materials for Engineers, Elsevier 2017, pp. 67-91).

• Current Applied Physics
• /
• 제18권11호
• /
• pp.1388-1392
• /
• 2018

Metal thin films are used widely to solve the vibration problem. However, damping mechanism is still not clear, which limits the further improvement of the damping properties for film and the development of multi-functional damping coating. In this paper, Damping microscopic mechanism of porous metal films was investigated at both macroscopically and microscopically mixed levels. Molecular dynamics simulation method was used to model and simulate the loading-unloading numerical experiment on the micro-pore and vacancy model to get the stress-strain curve and the microstructure diagram of different defects. And damping factor was calculated by the stress-strain curve. The results show that dislocations and new vacancies appear in the micro-pores when metal film is stretched. The energetic consumption from the motion of dislocation is the main reason for the damping properties of materials. Micro-mechanism of damping properties is discussed with the results of in-situ experiment.

• 대한설비공학회:학술대회논문집
• /
• 대한설비공학회 2009년도 하계학술발표대회 논문집
• /
• pp.1159-1165
• /
• 2009

In the present study, the flow and heat transfer characteristics of a large plate heat exchanger are investigated numerically. The flow passages are very complicated due to the grooved corrugation patterns of the plate surface so that the detailed mesh and the large amount of the computation time have to be required in the numerical simulation for the conjugate heat transfer analysis. In order to accomplish the efficient and fast analysis of the heat transfer characteristics in the plate heat exchanger, a semimicroscopic method using the porous media model has been investigated numerically. The results showed that the characteristics of the heat transfer and pressure drop, which are respectively presented with Colburn j-factor and Fanning f-factor, are in a good agreement between the detailed mesh and the porous media model. The results of the present study could be applicable to the numerical analysis of entire flow passages in the large plate heat exchanger using porous media treatment.

• Archives of Pharmacal Research
• /
• 제26권1호
• /
• pp.76-82
• /
• 2003

Drug releasing porous poly($\varepsilon$-caprolactone) (PCL)-chitosan matrices were fabricated for bone regenerative therapy. Porous matrices made of biodegradable polymers have been playing a crucial role as bone substitutes and as tissue-engineered scaffolds in bone regenerative therapy. The matrices provided mechanical support for the developing tissue and enhanced tissue formation by releasing active agent in controlled manner. Chitosan was employed to enhance hydrophilicity and biocompatibility of the PCL matrices. PDGF-BB was incorporated into PCL-chitosan matrices to induce enhanced bone regeneration efficacy. PCL-chitosan matrices retained a porous structure with a 100-200 $\mu$m pore diameter that was suitable for cellular migration and osteoid ingrowth. $NaHCO_3$ as a porogen was incorporated 5% ratio to polymer weight to form highly porous scaffolds. PDGF-BB was released from PCL-chitosan matrices maintaining therapeutic concentration for 4 week. High osteoblasts attachment level and proliferation was observed from PCL-chitosan matrices. Scanning electron microscopic examination indicated that cultured osteoblasts showed round form and spread pseudopods after 1 day and showed broad cytoplasmic extension after 14 days. PCL-chitosan matrices promoted bone regeneration and PDGF-BB loaded matrices obtained enhanced bone formation in rat calvarial defect. These results suggested that the PDGF-BB releasing PCL-chitosan porous matrices may be potentially used as tissue engineering scaffolds or bone substitutes with high bone regenerative efficacy.

• Carbon letters
• /
• 제24권
• /
• pp.73-81
• /
• 2017

Interconnected meso/microporous activated carbons were prepared from pumpkin seeds using a simple chemical activation method. The porous carbon materials were prepared at different temperatures (PS-600, PS-700, PS-800, and PS-900) and demonstrated huge surface areas ($645-2029m^2g^{-1}$) with excellent pore volumes ($0.27-1.30cm^3g^{-1}$). The well-condensed graphitic structure of the prepared activated carbon materials was confirmed by Raman and X-ray diffraction analyses. The presence of heteroatoms (O and N) in the carbon materials was confirmed by X-ray photoemission spectroscopy. High resolution transmission electron microscopic images and selected area diffraction patters further revealed the porous structure and amorphous nature of the prepared electrode materials. The resultant porous carbons (PS-600, PS-700, PS-800, and PS-900) were utilized as electrode material for supercapacitors. To our delight, the PS-900 demonstrated a maximum specific capacitance (Cs) of $303F\;g^{-1}$ in 1.0 M $H_2SO_4 $ at a scan rate of 5 mV. The electrochemical impedance spectra confirmed the poor electrical resistance of the electrode materials. Moreover, the stability of the PS-900 was found to be excellent (no significant change in the Cs even after 6000 cycles).

• 한국재료학회지
• /
• 제21권1호
• /
• pp.21-27
• /
• 2011

A nano-porous structure of tin oxide was prepared using an anodic oxidation process and the sample's electrochemical properties were evaluated for application as an anode in a rechargeable lithium battery. Microscopic images of the as-anodized sample indicated that it has a nano-porous structure with an average pore size of several tens of nanometers and a pore wall size of about 10 nanometers; the structural/compositional analyses proved that it is amorphous stannous oxide (SnO). The powder form of the as-anodized specimen was satisfactorily lithiated and delithiated as the anode in a lithium battery. Furthermore, it showed high initial reversible capacity and superior rate performance when compared to previous fabrication attempts. Its excellent electrode performance is probably due to the effective alleviation of strain arising from a cycling-induced large volume change and the short diffusion length of lithium through the nano-structured sample. To further enhance the rate performance, the attempt was made to create porous tin oxide film on copper substrate by anodizing the electrodeposited tin. Nevertheless, the full anodization of tin film on a copper substrate led to the mechanical disintegration of the anodic tin oxide, due most likely to the vigorous gas evolution and the surface oxidation of copper substrate. The adhesion of anodic tin oxide to the substrate, together with the initial reversibility and cycling stability, needs to be further improved for its application to high-power electrode materials in lithium batteries.

• Maxillofacial Plastic and Reconstructive Surgery
• /
• 제11권1호
• /
• pp.101-116
• /
• 1989

Proplast and Porous Polyethylene which have porous structures as low-modulus polymers have been recently used in maxillofacial plastic and reconstructive surgery. The purpose of this study was to compare the response of adajacent tissue, new bone formation and stability after augmentation by differen methods of subperiosteal graft using proplast and purous polythylene in rabbit mandible. The augmentation procedure was carried out by dividing into two groups, A and B. A group consisted of subperiosteal graft on the cortex, and the other B group was made up only graft following artificial decortication in the mandibular body of rabbit. The experimental animals were sacrificed on the 1st, 2nd, 4th and 8th week after grafting for macroscopic and light microscopic examination. The samples extracted at the 6th postgrafting week were also used for biometric testing and scanning electron microscopic examination. The results obtained from this study were as follows : 1. Macroscopically, infection of graft site, deformation and migration of graft material were not observed in all experimental groups. 2. B group showed more rapid and increased bone formation and the greater stability than A group, and tissue response was similar to each other. 3. In the tissue response, macrophages and cellular infiltrations were observed in Proplast group, but few in PHDPE group. 4. In bone formation of A group, Proplast group showed no bone formation until the 8th week, but PHDPE group showed small quantity of osteoid tissue from the 2nd week and appositional bone growth with new bone formation at the 8th week. 5. In bone formation of B group, both Proplast and PHDPE group showed bone formation, but PHDPE group showed more rapid and larger bone formation. 6. In pattern of bone formation, Proplast group mainly showed appositional bone growth pattern connected with graft site. On the other hand, PHDPE group showed mixed pattern of new bone formation in the pore connective tissue with appositional bone growth from graff site. 7. The maximum mean values of shear stress were serially $111.3gf/mm^{2}$ in PHDPE of B group, $84.8gf/mm^{2}$ in PHDPE of A group, $32.9gf/mm^{2}$ in Proplast B group, and $15.7gf/mm^{2}$ in Proplast of A group. From above results, It was suggested that the capacity of bone formation and stability between bone and graft material were dependent on the pore size and structure of graft material itself, the state of graft site and tissue response.

• 유기물자원화
• /
• 제16권1호
• /
• pp.46-52
• /
• 2008

자연계로 유출된 유류 및 유기용매 등 비수용성액체는 토양공극사이에 존재하며 서서히 용해되면서 지속적인 수질오염원으로 작용한다. 본 연구는 유리로 제작된 다공성매체 실험장치를 이용하여 토양 공극사이에 위치한 비수용성액체의 용해현상을 시각화하였고, 이미지 분석기술을 이용하여 용해속도를 정량화하였다. 다공성매체 공극사이 TCE는 물의 유량을 빠르게 할수록 용해속도가 증가하는 것으로 나타났다. 이는 TCE로 오염된 지역의 강우량이 많거나, 지하수 유속이 빠른 지역일 경우 토양내 TCE 제거는 용이하게 일어날 수 있지만, 용해된 TCE의 지하수 유입으로 증가한다는 점을 시사한다. 다공성매체 공극사이 TCE의 현미경 이미지 관측결과, 물의 유량이 빠른 경우 역시 TCE blob 수가 급격히 감소함을 확인하였다. 물의 흐름이 용이한 우선흐름경로에 존재하고 있는 TCE는 물과의 용이한 접촉으로 용해가 빠르게 진행되었다. 반면 정체구역에 존재하는 TCE의 용해속도는 매우 느리게 나타났다. 현장 토양에서도 동일한 현상이 일어날 것이므로 지하수 조사결과 TCE의 검출이 계속된다면, 토양 공극사이에 여전히 TCE가 존재하고 있음을 암시하므로 이에 대한 대책이 강구되어야 한다.

• 한국전산유체공학회:학술대회논문집
• /
• 한국전산유체공학회 2004년도 춘계 학술대회논문집
• /
• pp.183-189
• /
• 2004

The flow and the heat transfer about the cross-flow fin-tube heat exchanger in an out-door unit of a heat pump system has been numerically Investigated. Using the general purpose analysis code, FLUENT, the Navier-Stokes equations and the energy equation are solved for the three dimensional computation domain that encompasses multiple rows of the fin-tube. The temperature on the fin and tube surface is assumed constant but compensated later through the fin efficiency when predicting the heat-transfer rate. The contact resistance is also taken into consideration. The flow and temperature fields for a wide range of inlet velocity and fin-tube arrangements are examined and the results are presented in the paper. The details of the flow are very well captured and the heat transfer rate for a range of inlet velocity is in excellent agreement with the measured data. The flow solution provides the effective permeability and the inertial resistance factor of the heat exchanger if the exchanger were to be approximated by the porous medium. This information is essential in carrying out the global flow field calculation which, in turn, provides the inlet velocity lot the microscopic temperature-field calculation of the heat exchanger unit.

• Journal of Periodontal and Implant Science
• /
• 제24권1호
• /
• pp.185-195
• /
• 1994

This study was conducted to evaluate the healing potential of hydroxyapatite and demineralized freeze dried bone in 5 dogs. Chronic periodontitis was induced by ligating elastic wire randomized as follows. The group in which only flap operation was performed was used as control. The group in which flap operation using nonresorbable nonporous hydroxyapatite (Orthomatrix)was performed was used as experimental I. The group which flap operation using resorbable porous hydroxyapatite (Biocoral) was performed as experimental II. The group in which flap operation using demineralized freeze-dried bone was performed was used as experimental III. Thereafter dogs serially sacrificed at the 1,2,4 and 8 weeks and the specimens were prepared, and stained with Hematoxilin-Eosin stain for the light microscopic evaluation. The results of the this study were as follows : 1. Control group : progressive inflammatory cell infiltration till 4 weeks and epithelial undergrowth. 2. Group I. : epithelial undergrowth and new bone formed with fibrous margin around HA granule. 3. Group II. : no epithelial undergrowth and direct bone formation at the porous granule 4. Group III. : could not see epithelial undergrowth but obviously new cementum formation.