• Title/Summary/Keyword: Mg-doped

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Analysis on Bowing and Formation of Al Doped P+ Layer by Changes of Thickness of N-type Wafer and Amount of Al Paste (N타입 결정질 실리콘 웨이퍼 두께 및 알루미늄 페이스트 도포량 변화에 따른 Bowing 및 Al doped p+ layer 형성 분석)

  • Park, Tae Jun;Byun, Jong Min;Kim, Young Do
    • Korean Journal of Materials Research
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    • v.25 no.1
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    • pp.16-20
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    • 2015
  • In this study, in order to improve the efficiency of n-type monocrystalline solar cells with an Alu-cell structure, we investigate the effect of the amount of Al paste in thin n-type monocrystalline wafers with thicknesses of $120{\mu}m$, $130{\mu}m$, $140{\mu}m$. Formation of the Al doped $p^+$ layer and wafer bowing occurred from the formation process of the Al back electrode was analyzed. Changing the amount of Al paste increased the thickness of the Al doped $p^+$ layer, and sheet resistivity decreased; however, wafer bowing increased due to the thermal expansion coefficient between the Al paste and the c-Si wafer. With the application of $5.34mg/cm^2$ of Al paste, wafer bowing in a thickness of $140{\mu}m$ reached a maximum of 2.9 mm and wafer bowing in a thickness of $120{\mu}m$ reached a maximum of 4 mm. The study's results suggest that when considering uniformity and thickness of an Al doped $p^+$ layer, sheet resistivity, and wafer bowing, the appropriate amount of Al paste for formation of the Al back electrode is $4.72mg/cm^2$ in a wafer with a thickness of $120{\mu}m$.

The Phase Transition and Thermochromic Characteristics of W/Mg-codoped Monoclinic VO2 Nanoparticle and Its Composite Film

  • Park, Heesun;Kim, Jongmin;Jung, Young Hee;Kim, Yeong Il
    • Journal of the Korean Chemical Society
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    • v.61 no.2
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    • pp.57-64
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    • 2017
  • Monoclinic $VO_2(M)$ nanoparticles codoped with 1.5 at. % W and 2.9 at. % Mg were synthesized by the hydrothermal treatment and post-thermal transformation method of $V_2O_5-H_2C_2O_4-H_2O$ with $Na_2WO_4$ and $Mg(NO_3)_2$. The composite thin film of the W/Mg-codoped $VO_2(M)$ with a commercial acrylic block copolymer was also prepared on PET substrate by wet-coating method. The reversible phase transition characteristics of the codoped $VO_2(M)$ nanoparticles and the composite film were investigated from DSC, resistivity and Vis-NIR transmittance measurements compared with the undoped and Wdoped $VO_2(M)$ samples. Mg-codoping into W-doped $VO_2(M)$ nanoparticles synergistically enhanced the transition characteristics by increasing the sharpness of transition while the transition temperature ($T_c$) lowered by W-doping was maintained. The codoped composite film showed the prominently enhanced NIR switching efficiency compared to only W-doped $VO_2(M)$ film with a lowered $T_c$.

Electrical Conductivity of YO$_{1.5}$-TaO$_{2.5}$-MgO Based Fluorite Phase (YO$_{1.5}$-TaO$_{2.5}$-MgO 계 Fluorite 상의 전기전도도)

  • Choi, Soon-Mok;Kim, Shin;Lee, Hong-Lim
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.521-527
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    • 1998
  • Electrical conductivity of fluorite structure phases in the {{{{ {Y }_{0.8 } }}{{{{ { Ta}_{ 0.2} {O }_{1.7 }-MgO }} system has been studied. Electrical conductivity of 8mol% MgO doped {{{{ {Y }_{0.8 } }} {{{{ {Ta }_{0.2 } {O }_{1.7 } }} fluorite phase was lower than that of the undoped {{{{ {Y }_{0.8 } }}{{{{ {Ta }_{0.2 } {O }_{1.7 } }} When {{{{ { P}_{H2O } }} was increased electrical conductivity of {{{{ {Y }_{0.8 } }}{{{{ {Ta }_{0.2 } {O }_{1.7 } }} increased linealy with {{{{ { P}`_{H2O } ^{ {1 } over {2 } } }} The {{{{ {Y }_{0.8 } }}{{{{ {Ta }_{0.2 } {O }_{1.7 } }} fluorite phase exhibited higher electrical conductivity in wet atmosphere than in dry atmosphere. The identical trend was observed from the 8mol% MgO doped {{{{ {Y }_{0.8 } }}{{{{ {Ta }_{0.2 } {O }_{1.7 } }} fluorite phase.

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Improvement of Thermoelectric Properties in Te-Doped Zintl Phase Magnesium-Antimonide

  • Rahman, Md. Mahmudur;Ur, Soon-Chul
    • Korean Journal of Materials Research
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    • v.31 no.8
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    • pp.445-449
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    • 2021
  • Zintl compound Mg3Sb2 is a promising candidate for efficient thermoelectric material due to its small band gap energy and characteristic electron-crystal phonon-glass behavior. Furthermore, this compound enables fine tuning of carrier concentration via chemical doping for optimizing thermoelectric performance. In this study, nominal compositions of Mg3.8Sb2-xTex (0 ≤ x ≤ 0.03) are synthesized through controlled melting and subsequent vacuum hot pressing method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) are carried out to investigate phase development and surface morphology during the process. It should be noted that 16 at. % of excessive Mg must be added to the system to compensate for the loss of Mg during melting process. Herein, thermoelectric properties such as Seebeck coefficient, electrical conductivity, and thermal conductivity are evaluated from low to high temperature regimes. The results show that Te substitution at Sb sites effectively tunes the majority carriers from holes to electrons, resulting in a transition from p to n-type. At 873 K, a peak ZT value of 0.27 is found for the specimen Mg3.8Sb1.99Te0.01, indicating an improved ZT value over the intrinsic value.

Effects of $PbTiO_3$ Addition on Dielectric Properties and Extent of PbO Loss in Nd-Doped $Pb(Mg^{1/3}Nb^{2/3})O_3$ System ($Nd^{3+}$로 치환된 $Pb(Mg^{1/3}Nb^{2/3})O_3$$PbTiO_3$ 첨가에 따른 유전특성과 PbO 휘발)

  • 김성열;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.671-677
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    • 1993
  • Effects of PbTiO3 addition on dielectric properties and extent of PbO loss in Nd-doped Pb(Mg1/3Nb2/3)O3 system were investigated. As the proportion of dopping increased, the phase transition temperature shifted to low region, and the dielectric constant at room temperature decreased rapidly. But as the proportion of PbTiO3 increased, the phase transition temperature shifted to high retion, and the dielectric constant at room temperature increased. The substitution of Nd3+ for Pb2+ decreased the amount of PbO evaporation, therefore the sample sintered well in case of only 1 mole% adding excess PbO.

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Nozzles from Alumina Ceramics with Submicron Structure Fabricated by Radial Pulsed Compaction

  • Kaygorodov, Anton;Rhee, Chang;Kim, Whung-Whoe;Ivanov, Viktor;Paranin, Sergey;Spirin, Alexey;Khrustov, Vladimir
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.368-369
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    • 2006
  • By means of magnetic pulsed compaction and sintering of weakly aggregated alumina based nanopowders the jet forming nozzle samples for the hydroabrasive cutting were fabricated. The ceramics was obtained from pure alumina, as well as from alumina, doped by $TiO_2$, MgO and AlMg. It was shown that the samples sintered from AlMg doped $Al_2O_3$ powder have the best mechanical properties and structural characteristics: relative density ${\sim}0.97$, channel microhardness. - 18-20 GPa, channel surface roughness ${\sim}0.7\;{\mu}m$, average crystallite size ${\sim}1\;{\mu}m$.

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Preparation of $SnO_2$ Semiconducting Gas Sensor by Wet Process (습식방법에 의한 $SnO_2$ 반도체 가스센사 제조)

  • 전병식;김홍대;최병현;최성근
    • Journal of the Korean Ceramic Society
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    • v.23 no.3
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    • pp.53-61
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    • 1986
  • A gas sensor which has been made by wet process had fabricated by coating each of the mixture on alumina tube and firing at 85$0^{\circ}C$ for 3hrs. A gas concentration such $H_2$, CO, $C_3H_8$, $C_2H_2$ and $CH_4$ vs its detection voltage characteristics has been in-vestigated on $SnO_2-In_2O_3-MgO$ system doped with PdO, $La_2O_3$, $ThO_2$, NiO and $Nb_2O_5$ The optimum sensitivity composition for various gases were 90w/o $SnO_2$-9w/o $In_2O_3$-1w/o MgO for $H_2$, $C_2H_2$ CO and $C_3H_8$ and 95w/o $SnO_2$-4w/o $In_2O_3$-1w/o MgO for $CH_4$. The sample which has been made by wet process than dry process had predominated sensitivity for each gases and particle size of the sample coprecipitated with PH=9 was 0.1${\mu}{\textrm}{m}$ The $SnO_2$-In2_O_3-MgO$ system doped with 2w/o $Nb_2O_5$ and NiO was the most sensitive for $H_2$ and $C_2H_2$ gas. In $SnO_2$-In2_O_3-MgO$ system doped with $ThO_2$ the sensitivity of $H_2$ gas was decreased but CO gas was in-creased when dopant con was increased.

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Synthesis and Characterization of V2O - Doped Karrooite Brown Pigments (V2O5가 고용된 Karrooite계의 Brown색 안료합성과 특성)

  • Kim, Gum-Sun;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.303-306
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    • 2011
  • [ $V_2O_5$ ]doped Karrooite pigments were synthesized by the solid state method to get stabilized brown pigment in oxidation and reduction atmosphere. Optimum substitution condition and limited dopant with $V_2O_5$ for Karrooite pigment was investigated. With calcination at $1250^{\circ}C{\sim}1400^{\circ}C$, compositions were designed varying $V_2O_5$ molar ratio by increasing 0.02mole to the formula $Mg_1-xTi_2-xM_{2x}O_5$(x = 0.01~0.09 mole). Synthesized pigments were analyzed by XRD, Raman spectroscopy and UV-vis. When $V_2O_5$ was doped from 0.01 to 0.05 mole, single phase of Karrooite was observed at temperature $1300^{\circ}C$ and soaking time 4h by Raman spectroscopy. However, it was found that excess $VO_2$ peak appeared with 0.07 and 0.09 mole of $V_2O_5$ doped to $MgTi_2O_5$. This result indicated that the maximum limit of solid solution is 0.05 mole $V_2O_5$. Karrooite pigments were applied as a ceramic pigment to achieve brown colors in lime magnesia glaze and lime barium graze at both of oxidation and reduction atmosphere. CIE color coordinates are $L^*$ = 40.34, $a^*$ = 9.94, $b^*$ = 21.40 in lime magnesia glaze.