• Title/Summary/Keyword: Metallic Contaminant

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Development of Contaminant Detection System using HTS SQUIDs

  • Ohtani, T.;Tanaka, S.;Narita, Y.;Ariyoshi, S.;Suzuki, S.
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.4
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    • pp.38-42
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    • 2015
  • In terms of food safety,mixture of contaminants in food is a serious problem for not only consumers but also manufacturers. In general, the target size of the metallic contaminant to be removed is 0.5 mm. However, it is a difficult task for manufacturers to achieve this target, because of lower system sensitivity. Therefore, we developed a food contaminant detection system based on high-Tc RF superconducting quantum interference devices (SQUIDs), which are highly sensitive magnetic sensors. This study aims to improve the signal to noise ratio (SNR) of the system and detect a 0.5 mm diameter steel ball. Using a real time digital signal processing technique along with analog band-pass filters, we improved the SNR of the system. Owing to the improved SNR, a steel ball with a diameter as small as 0.3 mm, with stand-off distance of 117 mm was successfully detected. These results suggest that the proposed system is a promising candidate for the detection of metallic contaminants in food products.

High-$T_c$ SQUID Application for Roll to Roll Metallic Contaminant Detector

  • Tanaka, S.;Kitamura, Y.;Uchida, Y.;Hatsukade, Y.;Ohtani, T.;Suzuki, S.
    • Progress in Superconductivity
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    • v.14 no.2
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    • pp.82-86
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    • 2012
  • A sensitive eight-channel high-Tc Superconducting Interference Device (SQUID) detection system for magnetic contaminant in a lithium ion battery anode was developed. Finding ultra-small metallic foreign matter is an important issue for a manufacturer because metallic contaminants carry the risk of an internal short. When contamination occurs, the manufacturer of the product suffers a great loss from recalling the tainted product. Metallic particles with outer dimensions smaller than 100 microns cannot be detected using a conventional X-ray imaging system. Therefore, a highly sensitive detection system for small foreign matter is required. We have already developed a detection system based on a single-channel SQUID gradiometer and horizontal magnetization. For practical use, the detection width of the system should be increased to at least 65 mm by employing multiple sensors. In this paper, we present an 8-ch high-Tc SQUID roll-to-roll system for inspecting a lithium-ion battery anode with a width of 65 mm. A special microscopic type of a cryostat was developed upon which eight SQUID gradiometers were mounted. As a result, small iron particles of 35 microns on a real lithium-ion battery anode with a width of 70 mm were successfully detected. This system is practical for the detection of contaminants in a lithium ion battery anode sheet.

Influence of Metallic Contamination on Photovoltaic Characteristics of n-type Silicon Solar-cells (중금속 오염이 n형 실리콘 태양전지의 전기적 특성에 미치는 영향에 대한 연구)

  • Kim, Il-Hwan;Park, Jun-Seong;Park, Jea-Gun
    • Current Photovoltaic Research
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    • v.6 no.1
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    • pp.17-20
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    • 2018
  • The dependency of the photovoltaic performance of p-/n-type silicon solar-cells on the metallic contaminant type (Fe, Cu, and Ni) and concentration was investigated. The minority-carrier recombination lifetime was degraded with increasing metallic contaminant concentration, however, the degradation sensitivity of recombination lifetime was lower at n-type than p-type silicon wafer, which means n-type silicon wafer have an immunity to the effect of metallic contamination. This is because heavy metal ions with positive charge have a much larger capture cross section of electron than hole, so that reaction with electrons occurs much more easily. The power conversion efficiency of n-type solar-cells was degraded by 9.73% when metallic impurities were introduced in the silicon bulk, which is lower degradation compared to p-type solar-cells (15.61% of efficiency degradation). Therefore, n-type silicon solar-cells have a potential to achieve high efficiency of the solar-cell in the future with a merit of immunity against metal contamination.

The Characteristic of breakdown Particle Contaminated Model GIS with Epoxy Coated Electrodes (모의 GIS 내부에 파티클 유입시 코팅전극의 절연파괴 특성)

  • Koo, K.S.;Lee, D.Z.;Kwak, H.R.;Kim, Y.C.;Park, J.S.;Park, H.Y.
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1887-1889
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    • 2002
  • One of the most frequent sources of the accident is metal contaminant in GIS. This paper deals with the characteristics of breakdown voltage of metallic particles using electrodes of various epoxy coating thickness. As experimental results, breakdown voltage of the thickly coated electrode is higher than that of thinly coated electrode. It is considered that resistance of the epoxy coating impedes the development of pre-discharges in the gas.

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Recovery of manganese compounds from electric arc furnace dust by Aluminothermy Process (테르밋 반응을 이용한 페로망간 전기로 분진의 재활용에 관한 연구)

  • Ha, Tae-Young;Jo, Young-Min;Park, Young-Koo;Kim, Youn-Che
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.23-30
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    • 2015
  • The properties of dust collected from electric arc furnace of ferro manganese production units was investigated, and also the metallic manganese was recovered from the dust by aluminothermy process. The ferromanganese dust collected from electric arc furnace contained about 15% of manganese oxide ($Mn_3O_4$) and 9% of carbon as the contaminant, and have a 5um of 50% median diameter and irregular particle shape. The carbon contaminant in the dust could be reduced until about 0.1~0.5% level by roasting in the air at a temperature of 600~900C for 60minutes. The recovery of manganese could not be carried out using only ferromanganese dust from electric arc furnace by aluminothermy process, but the ferromanganese which contained manganese of about 92% and iron of about 5% could be obtained from the mixture of ferromanganese dusts from electric arc furnace and converter. The best mixing condition of dust fixed at electric arc furnace dust / converter dust ratio of 1:9 and 2:8, and the mixing rato of 3:7 or more could not separated the metal and slag from the reactant after aluminothermy reaction.

The Effect on the Microroughness of Si Substrate by Metallic Impurity Ca (금속 불순물 Ca이 Si 기판의 표면 미세 거칠기에 미치는 영향)

  • Choe, Hyeong-Seok;Jeon, Hyeong-Tak
    • Korean Journal of Materials Research
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    • v.9 no.5
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    • pp.491-495
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    • 1999
  • In this study, we focus on Ca contaminant which affects on the roughness Si substrate after thermal process. The initial Si substrates were contaminated intentionally by using a standard Ca solution. The contamination levels of Ca impurity were measured by TXRF and the chemical composition of that was analyzed by AES. Then we gre the thermal oxide to investigate the effect of Ca contaminants. The microroughness of the Si surface, the thermal oxide surface, and the surface after removing the thermal oxide were measured to examine the electrical characteristics. The initial substrates that were contaminated with the standard solution of Ca exhibited the contamination levels of 10\ulcorner~10\ulcorneratoms/$\textrm{cm}^2$ which was measured by TXRF. The Ca contaminants were detected by AES and exhibited the peaks of Ca, SI, C and O.After intentional contamination, the surface microroughness of this initial substrate was increased from $1.5\AA$ to 4$\AA$ as contamination levels became higher. The microroughness of the thermal oxide surfaces of both contaminated and bare Si substrates exhibits similar values. But the microroughness of the contaminated$ Si/SiO_2$ interface was increased as contamination increased. The thermal oxide of contaminated substrate exhibited the small minority carrier diffusion length, low breakdown voltage, and slightly high leakage current.

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Non-Destructive Scientific Analysis of the Gold Fabric Excavated of Cheongsong Shim's Grave (청송심씨 묘에서 출토된 금직물의 비파괴 과학적 분석)

  • Lee, Hwang-Jo;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.38 no.3
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    • pp.243-253
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    • 2022
  • Using non-destructive analytical methods, we identified the material characteristics of two gold fabric artifacts excavated from the Cheongsong Sim clan (Bugeum Wonsam, Jikgeum Chima), including the artifact condition, fiber type, surface contamination, and metallic threads. We found that the artifacts were buried and had turned brown; thus, we were unable to determine their original color. The fiber type was determined to be silk from cocoons, based on scanning electron microscopy, Fourier transform infrared (FT-IR) analyses of Amide I, II, III, and IV peaks, and color reactions Further, the FT-IR and X-ray fluorescence (XRF) analyses identified the white and black stains as natural resin hydrolyzed substances, such as lipids and proteins, that occurred as microbial decomposition due to body decay. Finally, the XRF analyses identified the thin gold layer of the metallic yarn as gold (Au). According to the FT-IR data and the color reaction to the metallic yarn medium, the adhesive component of the medium was a product of-Amides I, II, III, and 3000 cm-1 within Amides A and B (an animal type), respectively. Thus, the medium was identified as Hanji (Korean paper), which is made from domestically produced Broussonetia kazinoki fibers.

A Study on Plasma Etching Reaction of Cobalt for Metallic Surface Decontamination (금속 표면 제염을 위한 코발트의 플라즈마 식각 반응 연구)

  • Jeon, Sang-Hwan;Kim, Yong-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.1
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    • pp.17-23
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    • 2008
  • In this study, plasma processing of metal surface is experimentally investigated to enhance the surface decontamination efficiency and to find out the reaction mechanism. Cobalt, the major contaminant in the nuclear facilities, and three fluorine-containing gases, $CF_4/O_2$, $SF_6/O_2$, and $NF_3$ are chosen for the investigation. Thin metallic disk specimens are prepared and their surface etching reactions with the three plasma gases are examined. Results show that the maximum etching rate of $17.2\;{\mu}m/min.$ is obtained with NF3 gas at $420^{\circ}C$, while with $CF_4/O_2$, $SF_6/O_2$ gas plasmas those of $2.56\;{\mu}m/min.$ and $1.14\;{\mu}m/min.$ are obtained, respectively. Along with etching experiments, constituent elements of the reaction products are identified to be cobalt, oxygen, and fluorine by AES (Auger Electron Spectroscopy) analysis. It turns out that the oxygen atoms are physically adsorbed ones to the surface from the ambient not participation ones during the analysis after reaction, which supports that the surface reaction of cobalt is mainly to be a fluorination reaction.

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A Study on the contamination measurement of spacecraft components under High Vacuum Environment (고진공하에서의 위성체 부품의 오염측정에 관한 연구)

  • 이상훈;서희준;문귀원;최석원
    • Journal of the Korean Vacuum Society
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    • v.11 no.2
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    • pp.87-96
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    • 2002
  • Outgassing from such sources as paints, coatings, adhesives and other non-metallic surfaces can contaminate satellites, especially second surface mirror and optical lens, it cause satellite to fail in own missions. The vacuum bake-out test using high temperature(more than $85 ^{\circ}C$)and high vacuum(less than $5.0{\times}1-^{-3}$ Pa) certify that the components of satellite work properly and can survive and operate in space environment like high vacuum. In the bake-out chamber installed at SITC of KARI, Rotary vacuum pump and Booster pump produce low vacuum of 5.0 Pa, and then two cryopumps produce high vacuum of below $5.0{\times}10^{-3}$ Pa. Also 48 ceramic heaters were provided to simulate high temperature. During the vacuum bake-out test, we detected contaminants using RGA(Residual Gas Analyzer) and measure the outgassing rate of the contaminant using the TQCM(Thermoelectric Quartz Crystal Microbalance). Also, IR/UV Spectrometer and witness plate be used to certify that the components were suitable for the spacecraft. This paper includes the preparation and procedures of the bake-out test for SAR(Solar Array Regulator) and MLI(Multi Layer Insulator), which were the components of the spacecraft. Especially, we discussed the methods and results of the contamination measurement. In the bake-out for SAR, the contamination was measured continuously although it was on the decrease from TQCM results. And RCA established that it is a highly polymerized compound. In the MLI bake-out using RGA and witness plate, we didn't detect any contamination materials.