• 제목/요약/키워드: Metal core

검색결과 623건 처리시간 0.027초

The Role of the Surface Oxide Layer on Ru Nanoparticles in Catalytic Activity of CO Oxidation

  • Kim, Sun-Mi;Qadir, Kamran;Jin, Sook-Young;Jung, Kyeong-Min;Reddy, A. Satyanarayana;Joo, Sang-Hoon;Park, Jeong-Young
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.304-304
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    • 2010
  • The study on the catalytic oxidation of carbon monoxide (CO) to carbon dioxide ($CO_2$) using the noble metals has long been the interest subject and the recent progress in nanoscience provides the opportunity to develop new model systems of catalysts in this field. Of the noble metal catalysts, we selected ruthenium (Ru) as metal catalyst due to its unusual catalytic behavior. The size of colloid Ru NPs was controlled by the concentration of Ru precursor and the final reduction temperatures. For catalytic activity of CO oxidation, it was found that the trend is dependent on the size of Ru NPs. In order to explain this trend, the surface oxide layer surrounding the metal core has been suggested as the catalytically active species through several studies. In this poster, we show the influence of surface oxide on Ru NPs on the catalytic activity of CO oxidation using chemical treatments including oxidation, reduction and UV-Ozone surface treatment. The changes occurring to UV-Ozone surface treatment will be characterized with XPS and SEM. The catalytic activity before and after the chemical modification were measured. We discuss the trend of catalytic activity in light of the formation of core-shell type oxide on nanoparticles surfaces.

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전기 도금된 CoFeNi계 박막의 결정크기와 방향성이 자기특성에 미치는 영향 (The Effect of Magnetic Property According to Size and Orientation of Crystal for Electroplated Co-Fe-Ni Alloys)

  • 정원용;김현경;박창빈
    • 한국자기학회지
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    • 제16권5호
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    • pp.249-254
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    • 2006
  • CoFeNi 합금은 HDD, MEMS 분야에서 head core 재료로 쓰이는 permalloy(FeNi)합금보다 뛰어난 우수한 자기적 특성을 가진 재료로써 최근 많이 연구되어지고 있다. 전기도금된 CoFeNi합금 박막의 열처리에 따른 미세구조 변화와 결정학적 특성이 자기특성에 미치는 영향을 조사하였다. 삼원계 합금을 열처리하면 전기도금 시 결정의 크기와 결정구조의 변화가 자기특성에 영향을 미친다. 이를 조사하여 열처리를 통하여 얻어지는 CoFeNi계 박막의 자기 특성을 향상시키고자 하였고, $300{\sim}400^{\circ}C$까지 열처리를 함으로써 보자력을 최소화하고 포화자화 값을 증가시켰다. 포화자화 값의 증가는 bcc상의 생성으로 야기되는 것으로 판단된다.

A Preliminary Design Concept of the HYPER System

  • Park, Won S.;Tae Y. Song;Lee, Byoung O.;Park, Chang K.
    • Nuclear Engineering and Technology
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    • 제34권1호
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    • pp.42-59
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    • 2002
  • In order to transmute long-lived radioactive nuclides such as transuranics(TRU), Tc-99, and I- l29 in LWR spent fuel, a preliminary conceptual design study has been performed for the accelerator driven subcritical reactor system, called HYPER(Hybrid Power Extraction Reactor) The core has a hybrid neutron energy spectrum: fast and thermal neutrons for the transmutation of TRU and fission products, respectively. TRU is loaded into the HYPER core as a TRU-Zr metal form because a metal type fuel has very good compatibility with the pyre- chemical process which retains the self-protection of transuranics at all times. On the other hand, Tc-99 and I-129 are loaded as pure technetium metal and sodium iodide, respectively. Pb-Bi is chosen as a primary coolant because Pb-Bi can be a good spallation target and produce a very hard neutron energy spectrum. As a result, the HYPER system does not have any independent spallation target system. 9Cr-2WVTa is used as a window material because an advanced ferritic/martensitic steel is known to have a good performance under a highly corrosive and radiation environment. The support ratios of the HYPER system are about 4∼5 for TRU, Tc-99, and I-129. Therefore, a radiologically clean nuclear power, i.e. zero net production of TRU, Tc-99 and I-129 can be achieved by combining 4 ∼5 LWRs with one HYPER system. In addition, the HYPER system, having good proliferation resistance and high nuclear waste transmutation capability, is believed to provide a breakthrough to the spent fuel problems the nuclear industry is faced with.

Free vibration of various types of FGP sandwich plates with variation in porosity distribution

  • Aicha Kablia;Rabia Benferhat;Tahar Hassaine Daouadji;Rabahi Abderezak
    • Structural Engineering and Mechanics
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    • 제85권1호
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    • pp.1-14
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    • 2023
  • The use of functionally graded materials in applications involving severe thermal gradients is quickly gaining acceptance in the composite mechanics community, the aerospace and aircraft industry. In the present study, a refined sandwich plate model is applied to study the free vibration analysis of porous functionally graded material (FGM) sandwich plates with various distribution rate of porosity. Two types of common FG sandwich plates are considered. The first sandwich plate is composed of two FG material (FGM) face sheets and a homogeneous ceramic or metal core. The second one consists of two homogeneous fully metal and ceramic face sheets at the top and bottom, respectively, and a FGM core. The displacement field of the present theory is chosen based on nonlinear variations in the in-plane displacements through the thickness of the sandwich plate. The number of unknowns and equations of motion of the present theory is reduced and hence makes them simple to use. In the analysis, the equation of motion for simply supported sandwich plates is obtained using Hamilton's principle. In order to present the effect of the variation of the porosity distribution on the dynamic behavior of the FGM sandwich plates, new mixtures are proposed which take into account different rate of porosity distribution between the ceramic and the metal. The present method is applicable to study the dynamic behavior of FGM plates and sandwich plates. The frequencies of two kinds of FGM sandwich structures are analyzed and discussed. Several numerical results have been compared with the ones available in the literature.

MAD/MAM을 이용한 치과용 지르코니아 코어의 변연 적합도 (Marginal fidelity of zirconia core using MAD/MAM system)

  • 강동림;심준성;문홍석;이근우
    • 대한치과보철학회지
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    • 제48권1호
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    • pp.1-7
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    • 2010
  • 연구 목적: 본 연구에서는MAD/MAM 시스템으로 제작된 지르코니아 코어를 통상적인 방법으로 제작된 금속-도재관 코어와 CAD/CAM 시스템으로 제작된 코어와의 변연부 적합도를 비교 분석해 보고자 한다. 연구 재료 및 방법: 레진치를 전부 도재관 제작을 위한 형태로 삭제하고, 이를 복제하여 석고 모형을 제작하였다. 석고 모형에 대해 금속-도재관, CAD/CAM ($Cercon^{(R)}$), 3종의 MAD/MAM 시스템 ($Ceramill^{(R)}$, $Rainbow^{(TM)}$, $Zirkonzhan^{(R)}$)으로 각각 10개의 코어를 제작하였다. 제작된 코어를 다이에 합착하여 광학 현미경 상에서 50배율로 변연 간격을 관찰, 계측하였다. 측정된 결과는 one-way ANOVA test로 분석하고, Tukey's HSD test로 사후검정 하였다. 결과: 각 시스템에서 변연 간격의 평균과 표준 편차는 금속-도재관 코어 $51.97{\pm}23.38{\mu}m$, $Cercon^{(R)}$ $62.16{\pm}25.88{\mu}m$, $Ceramill^{(R)}$ $67.64{\pm}40.38{\mu}m$, $Rainbow^{TM}$ $125.07{\pm}42.19{\mu}m$, $Zirkonzhan^{(R)}$ $105.02{\pm}44.61{\mu}m$로 측정되었다. 결론: 금속-도재관 코어나 CAD/CAM에 비해 MAD/MAM 방식으로 제작된 코어의 변연 간격이 큰 것으로 나타났다 (P < .05). MAD/MAM 시스템 내에서도 $Ceramill^{(R)}$, $Zirkonzhan^{(R)}$, $Rainbow^{TM}$ 순으로 변연 간격이 작은 것으로 측정되었으며, 이중 $Ceramill^{(R)}$은 CAD/CAM 시스템인 $Cercon^{(R)}$과 변연 간격에 유의차가 없었다.

금속 유지장치의 오염이 레진 접착 결합력에 미치는 영향 (The effect of contamination of the etched matal retainer on resin bonding strength)

  • 박하옥;방몽숙
    • 구강회복응용과학지
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    • 제18권3호
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    • pp.217-224
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    • 2002
  • The purpose of this study was to evaluate the influence of saliva contamination on the resin bonding of the etched metal retainers. The test samples were made of Verabond, and divided into 3 groups. Retainers in group1 had normally etched metal surfaces. Retainers in group2 had normally etched metal surfaces which were saliva-contaminated for 30 seconds and cleaned with streaming, luke-warm for 1 minute and dried thoroughly. Retainers in group3 had normally etched metal surfaces which were saliva- contaminated for 30 seconds and dried thoroughly without water-cleansing. Each 3 group specimen was watched on SEM. A resin core, 5mm in diameter and 6mm in length, was made of Panavia using Teflon mold on the each specimen. These 3 groups were tested to evaluate shear bond strength, using universal testing machine. The results were as follows : 1. The shear bond strength showed no significant difference between group1 and group2. 2. The shear bond strength showed significant difference between group1 and group3. 3. The shear bond strength significant difference between group2 and group3. 4. Scanning electron microscope photographs of group1 and group2 showed no signs of contamination but of group3 showed somewhat contaminated.

Decoupled Plasma Nitridation에 의한 Flicker 노이즈 개선에 관한 연구 (A study on Flicker Noise Improvement by Decoupled Plasma Nitridation)

  • 문성열;강성준;정양희
    • 한국전자통신학회논문지
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    • 제9권7호
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    • pp.747-752
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    • 2014
  • 본 논문은 $0.13{\mu}m$ 기술의 디자인을 10% 축소하는데 기존의 로직 디바이스만의 축소와는 달리 로직뿐 아니라 입, 출력 회로의 축소에 관한 것이다. 게이트 산화막(1.2V)을 decoupled plasma nitridation(DPN) oxide로 변경함으로써 flicker 노이즈를 축소 전 공정에 비해 1/3-1/5배 감소됨을 확인하였다. 또한, 축소에 의한 피할 수 없는 문제는 일반적인 metal insulator metal(MIM)의 캐패시터 문제이다. 이를 해결하기 위하여 20% 높은 MIM 캐패시터($1.2fF/{\mu}m^2$)를 개선하고 그 특성을 평가하였다.

초음속 코히어런트 제트에 관한 기초적 연구 (A Fundamental Study of the Supersonic Coherent Jet)

  • 정미선;조위분;김희동
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.2139-2144
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    • 2003
  • In steel-making processes of iron and steel industry, the purity and quality of steel can be dependent on the amount of CO contained in the molten metal. Recently, the supersonic oxygen jet is being applied to the molten metal in the electric furnace and thus reduces the CO amount through the chemical reactions between the oxygen jet and molten metal, leading to a better quality of steel. In this application, the supersonic oxygen jet is limited in the distance over which the supersonic velocity is maintained. In order to get longer supersonic jet propagation into the molten metal, a supersonic coherent jet is suggested as one of the alternatives which are applicable to the electric furnace system. It has a flame around the conventional supersonic jet and thus the entrainment effect of the surrounding gas into the supersonic jet is reduced, leading to a longer propagation of the supersonic jet. The objective of the present study is to investigate the supersonic coherent jet flow. A computational study is carried out to solve the compressible, axisymmetric Navier-Stokes equations. The computational results of the supersonic coherent jet are compared with the conventional supersonic jet.

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자수기용 로터리 훅 개발을 위한 금속분말 사출성형해석 (Metal Injection Molding Analysis for Developing Embroidering Machine Rotary Hooks)

  • 김상윤;박보규;정재옥;조규상;정일섭
    • 한국기계가공학회지
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    • 제17권4호
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    • pp.160-168
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    • 2018
  • Among the components of rotary hooks, a core component of an embroidery sewing system, a study was conducted to apply metal injection molding to the manufacture of a hook body and a housing that was very difficult to mechanical working. The correlation of feedstock, a mixture of binder and SCM 415 metal powder, and properties of the pressure-volume-temperature interrelationship, viscosity, specific heat, and thermal conductivity were measured. Injection molds for the hook body and the housing were developed through injection molding analysis using these properties and conducted injection tests. Optimal injection gate position and number, injection pressure, and injection time were obtained through a comparison of analysis results with the experiment results.

ESTABLISHMENT OF A NEURAL NETWORK MODEL FOR DETECTING A PARTIAL FLOW BLOCKAGE IN AN ASSEMBLY OF A LIQUID METAL REACTOR

  • Seong, Seung-Hwan;Jeong, Hae-Yong;Hur, Seop;Kim, Seong-O
    • Nuclear Engineering and Technology
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    • 제39권1호
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    • pp.43-50
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    • 2007
  • A partial flow blockage in an assembly of a liquid metal reactor could result in a cooling deficiency of the core. To develop a partial blockage detection system, we have studied the changes of the temperature fluctuation characteristics in the upper plenum according to changes of the t10w blockage conditions in an assembly. We analyzed the temperature fluctuation in the upper plenum with the Large Eddy Simulation (LES) turbulence model in the CFX code and evaluated its statistical parameters. Based on the results of the statistical analyses, we developed a neural network model for detecting a partial flow blockage in an assembly. The neural network model can retrieve the size and the location of a flow blockage in an assembly from a change of the root mean square, the standard deviation, and the skewness in the temperature fluctuation data. The neural network model was found to be a possible alternative by which to identify a flow blockage in an assembly of a liquid metal reactor through learning and validating various flow blockage conditions.