• Title/Summary/Keyword: Metal Nanomaterial

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One-dimensional Nanomaterials for Field Effect Transistor (FET) Type Biosensor Applications

  • Lee, Min-Gun;Lucero, Antonio;Kim, Ji-Young
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.4
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    • pp.165-170
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    • 2012
  • One-dimensional, nanomaterial field effect transistors (FET) are promising sensors for bio-molecule detection applications. In this paper, we review fabrication and characteristics of 1-D nanomaterial FET type biosensors. Materials such as single wall carbon nanotubes, Si nanowires, metal oxide nanowires and nanotubes, and conducting polymer nanowires have been widely investigated for biosensors, because of their high sensitivity to bio-substances, with some capable of detecting a single biomolecule. In particular, we focus on three important aspects of biosensors: alignment of nanomaterials for biosensors, surface modification of the nanostructures, and electrical detection mechanism of the 1-D nanomaterial sensors.

Research Status on Flexible Electronics Fabrication by Metal Nano-particle Printing Processes (금속 나노입자 프린팅 공정을 이용한 유연전기소자 연구 현황)

  • Ko, Seung Hwan
    • Particle and aerosol research
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    • v.6 no.3
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    • pp.131-138
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    • 2010
  • Flexible electronics are the electronics on flexible substrates such as a plastic, fabric or paper, so that they can be folded or attached on any curved surfaces. They are currently recognized as one of the most innovating future technologies especially in the area of portable electronics. The conventional vacuum deposition and photolithographic patterning methods are well developed for inorganic microelectronics. However, flexible polymer substrates are generally chemically incompatible with resists, etchants and developers and high temperature processes used in conventional integrated circuit processing. Additionally, conventional processes are time consuming, very expensive and not environmentally friendly. Therefore, there are strong needs for new materials and a novel processing scheme to realize flexible electronics. This paper introduces current research trends for flexible electronics based on (a) nanoparticles, and (b) novel processing schemes: nanomaterial based direct patterning methods to remove any conventional vacuum deposition and photolithography processes. Among the several unique nanomaterial characteristics, dramatic melting temperature depression (Tm, 3nm particle~$150^{\circ}C$) and strong light absorption can be exploited to reduce the processing temperature and to enhance the resolution. This opens a possibility of developing a cost effective, low temperature, high resolution and environmentally friendly approach in the high performance flexible electronics fabrication area.

A Study on Rinsing Effects of Sn Sensitization and Pd Activation Processes for Uniform Electroless Plating (무전해 도금에서 Sn 민감화와 Pd 활성화 공정의 세척 효과에 대한 연구)

  • Seong-Jae, Jeong;Mi-Se, Chang;Jae-Won, Jeong;Sang-Sun, Yang;Young-Tae, Kwon
    • Journal of Powder Materials
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    • v.29 no.6
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    • pp.511-516
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    • 2022
  • Electroless plating is widely utilized in engineering for the metallization of insulator substrates, including polymers, glass, and ceramics, without the need for the application of external potential. Homogeneous nucleation of metals requires the presence of Sn-Pd catalysts, which significantly reduce the activation energy of deposition. Therefore, rinsing conducted during Sn sensitization and Pd activation is a key variable for the formation of a uniform seed layer without the lack or excess of catalysts. Herein, we report the optimized rinsing process for the functionalization of Sn-Pd catalysts, which enables the uniform FeCo metallization of the glass fibers. Rinsing enables good deposition of the FeCo alloy because of the removal of excess catalysts from the glass fiber. Concurrently, excessive rinsing results in a complete removal of the Sn-Pd nucleus. Collectively, the comprehensive study of the proposed nanomaterial preparation and surface science show that the metallization of insulators is a promising technology for electronics, solar cells, catalysts, and mechanical parts.

Preservation Conditions of Aqueous Samples Containing silver Nanomaterials (은나노물질을 포함한 수질시료의 보관조건)

  • Kang, Mun Hee;Park, Sol;Lee, Sang-Woo;Kim, Hyun-A;Lee, Byung-Tae;Eom, Ig-Chun;Kim, Soon-Oh
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.4
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    • pp.218-227
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    • 2015
  • A prerequisite for precise quantification of nanomaterials contained in environmental samples is to prepare suitable preservation conditions of samples. This study was initiated to suggest preservation conditions of aqueous samples for analyses of metal nanomaterials. Variation in the size of silver nanomaterial (cit-AgNP) was observed according to change in various conditions, such as pH, electrolyte concentration, temperature, nanomaterial concentration, and time. Aggregation of AgNP was characterized for each environmental condition, and finally proper preservation conditions of samples were proposed based on experimental results on AgNP aggregation. In addition, the preservation period of sample was computed by the doublet time of AgNP. The results indicate that the aggregation rate of cit-AgNP was close to 0 at the conditions of pH of ${\geq}7$, electrolyte ($Ca(NO_3)_2$) concentration of ${\leq}3mM$, temperature of $4^{\circ}C$, and cit-AgNP concentration of ${\leq}2mg/L$. Furthermore, the experimental results on doublet time of cit-AgNP suggest that maximum preservation period was evaluated to be 15.79~17.53 days when the concentration of 100 nm cit-AgNP is assumed to be $1{\mu}g/L$ which is considered as an environmentally-relevant concentration of engineered nanomaterials. Our results suggest that samples should be preserved at $4^{\circ}C$ and analyzed within 2 weeks.

Assembly of Biomimetic Peptoid Polymers

  • Nam, Gi-Tae
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.10.2-10.2
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    • 2011
  • The design and synthesis of protein-like polymers is a fundamental challenge in materials science. A biomimetic approach is to explore the impact of monomer sequence on non-natural polymer structure and function. We present the aqueous self-assembly of two peptoid polymers into extremely thin two-dimensional (2D) crystalline sheets directed by periodic amphiphilicity, electrostatic recognition and aromatic interactions. Peptoids are sequence-specific, oligo-N-substituted glycine polymers designed to mimic the structure and functionality of proteins. Mixing a 1:1 ratio of two oppositely charged peptoid 36 mers of a specific sequence in aqueous solution results in the formation of giant, free-floating sheets with only 2.7 nm thickness. Direct visualization of aligned individual peptoid chains in the sheet structure was achieved using aberration-corrected transmission electron microscopy. Specific binding of a protein to ligand-functionalized sheets was also demonstrated. The synthetic flexibility and biocompatibility of peptoids provide a flexible and robust platform for integrating functionality into defined 2D nanostructures. In the later part of my talk, we describe the use of metal ions to construct two-dimensional hybrid films that have the ability to self-heal. Incubation of biomimetic peptoid polymers with specific divalent metal ions results in the spontaneous formation of uniform multilayers at the air-water interface. We anticipate that ease of synthesis and transfer of these two-dimensional materials may have many potential applications in catalysis, gas storage and sensing, optics, nanomaterial synthesis, and environmentally responsive scaffolds.

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Research Trends of Two-Dimensional Nanomaterial-Based Tactile Sensors (이차원 나노 소재 기반 촉각 센서 기술 동향)

  • Min, B.K.;Kim, S.J.;Yi, Y.;Choi, C.G.
    • Electronics and Telecommunications Trends
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    • v.33 no.1
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    • pp.123-130
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    • 2018
  • Tactile sensors, which are commonly referred to as pressure and strain sensors, have been extensively investigated to meet the demands for attachable and wearable electronics for monitoring the health status or activity of human users. For this purpose, the introduction of two-dimensional (2D) materials such as graphene and transition metal dichalcogenides (TMDs) with high mechanical strength at the atomic scale is very suitable for tactile sensors applicable for use in human-friendly devices. In this paper, we examine a descriptive summary of a tactile sensor and review state-of- the-art research trends of 2D material-based tactile sensors in terms of the material and architecture. Finally, we propose a roadmap for future studies into advanced tactile sensors based on our ongoing research.

Study on synthesis of carbon nanomaterials by hydrogen mixing in counterflow methane diffusion flames (메탄 대향류 확산화염내 수소를 첨가한 탄소나노물질 합성에 관한 연구)

  • Shin, Woo-Jung;Choi, Jung-Sik;Yoon, Seok-Hun;Lee, Hyun-Sik;Choi, Jae-Hyuk
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2011.10a
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    • pp.88-89
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    • 2011
  • The study on synthesis of carbon nanomaterials by H2 mixing in counterflow methane diffusion flames has been experimentally conducted. We have also investigated on effect of catalyst and temperature in flame. The counterflow flame was formed by many kind of gas (fuel side using $CH_4-H_2-N_2$ and oxidizer side $N_2-O_2$) and nitrogen shields discharge on each other side to cut off oxidizer of the atmosphere. Ferrocene was used as a metal catalyst for CNTs synthesis. substrate was used to deposit carbon nanomaterials and these were analyzed by FE-SEM. We could find that carbon nanotubes and many kind of carbon nano materials were formed in Cu wire substrate, through this experiment.

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Fabrication and Characterization of Ag Nanoparticle Dispersed Polymer Nanofiber and Ag Nanofiber Using Electrospinning Method (전기방사법을 이용한 Ag 나노입자 분산 고분자 나노파이버와 Ag 나노파이버 제조 및 특성 평가)

  • Kim, Hee-Taik;Hwang, Chi-Yong;Song, Han-Bok;Lee, Kun-Jae;Joo, Yeon-Jun;Hong, Seong-Jei;Kang, Nam-Kee;Park, Seong-Dae;Kim, Ki-Do;Cho, Yong-Ho
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.114-118
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    • 2008
  • Functional nanomaterial is expected to have improved capacities on various fields. Especially, metal nanoparticles dispersed in polymer matrix and metal nanofiber, one of the functional nanomaterials, are able to achieve improvement of property in the electric and other related fields. In this study, the fabrication of metal (Ag) nanoparticle dispersed nanofibers were attempted. The Ag nanoparticle dispersed polymer nanofiber and Ag nanofiber were fabricated by electrospinning method using electric force. First, PVP/$AgNO_3$ nanofibers were synthesized by electrospinning in $18{\sim}22kV$ voltage with the starting materials (Ag-nitrate) added polymer (PVP; poly (vinylpyrrolidone)). Then Ag nanoparticle dispersed polymer nanofibers were fabricated to reduce hydrogen reduction at $150^{\circ}C$ for 3hr. And Ag nanofibers were synthesized by the decomposited of PVP at $300{\sim}500^{\circ}C$ for 3hr. The nanofibers were analyzed by XRD, TGA, FE-SEM and TEM. The experimental results showed that the Ag nanofibers could be applied in many fields as an advanced material.

Fabrication of Gold Nanostructures Using Electrochemical Deposition Integrated with Solution Process (용액 공정을 접목한 전기화학 증착 기법을 활용한 금 나노 구조체 제작)

  • Jihee Kim;Donghyeon Kim;Mijeong Kang
    • Journal of the Korean Electrochemical Society
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    • v.27 no.3
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    • pp.81-87
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    • 2024
  • Nanomaterial electrodes are used to improve the analytical performances of electrochemical measurements in biological and chemical field. Frequently used methods for fabricating metal nanostructures are solution processing and electrodeposition. In the solution process, it is possible to control the characteristics (e.g., direction) of metal growth by using capping agents, thereby fabricating nanoparticles of specific structures. In the electrodeposition, the electrode surface and the deposited metal atoms are in direct contact. Each process has its own limitation as well, and many studies are conducted to overcome such limitation. In this paper, we report an integration of the two fabrication methods and the characteristics, such as structural and electrochemical properties, of the fabricated electrodes. Lastly, we discuss the possibility of using the fabricated nanostructured electrode as a sensor.

A review: methane capture by nanoporous carbon materials for automobiles

  • Choi, Pil-Seon;Jeong, Ji-Moon;Choi, Yong-Ki;Kim, Myung-Seok;Shin, Gi-Joo;Park, Soo-Jin
    • Carbon letters
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    • v.17 no.1
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    • pp.18-28
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    • 2016
  • Global warming is considered one of the great challenges of the twenty-first century. In order to reduce the ever-increasing amount of methane (CH4) released into the atmosphere, and thus its impact on global climate change, CH4 storage technologies are attracting significant research interest. CH4 storage processes are attracting technological interest, and methane is being applied as an alternative fuel for vehicles. CH4 storage involves many technologies, among which, adsorption processes such as processes using porous adsorbents are regarded as an important green and economic technology. It is very important to develop highly efficient adsorbents to realize techno-economic systems for CH4 adsorption and storage. In this review, we summarize the nanomaterials being used for CH4 adsorption, which are divided into non-carbonaceous (e.g., zeolites, metal-organic frameworks, and porous polymers) and carbonaceous materials (e.g., activated carbons, ordered porous carbons, and activated carbon fibers), with a focus on recent research.