• Title/Summary/Keyword: Metal

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Effects of Similar Metal Weld on Residual Stress in Dissimilar Metal Weld According to Safe End Length (동종금속용접이 이종금속용접부 잔류응력에 미치는 영향 평가 시 안전단 길이에 따른 효과)

  • Song, Tae-Kwang;Chun, Yun-Bae;Oh, Chang-Young;Bae, Hong-Yeol;Kim, Yun-Jae;Lee, Sang-Hoon;Lee, Kyoung-Soo;Park, Chi-Yong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.7
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    • pp.664-672
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    • 2009
  • Nozzle in nuclear power plant is connected to pipe using safe end. Dissimilar metal weld between nozzle and safe end is followed by similar metal weld between safe end and pipe. And thus residual stress in dissimilar metal weld can be affected by similar metal weld. Similar metal weld impose bending stress on dissimilar metal weld, which is according to the length of safe end. In this study, simple nozzle model which covers various radius to thickness ratios was proposed to quantify residual stress in dissimilar metal weld based on finite element analyses. As a result, short length of safe end was proved to be more effective to mitigate residual stress in dissimilar metal weld and critical effective length of safe end is provided according to the radius to thickness ratio.

Study on the Electrical Conductivity in Polysiloxane/Metal Composite Containing Metal Oxide (금속산화물을 포함한 변성폴리실록산/금속 복합체의 전기 전도성 연구)

  • Im, Hyungu;Kim, Jooheon
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.307-312
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    • 2009
  • The block-co-polymer type thermosetting polysiloxane coordinated with metal oxide was synthesized to investigate the effect of metal oxide on the dispersity of metal powder in the polysiloxane/metal composite material. The metal powder in the polysiloxane/metal composite materials is better dispersed with metal oxide complex polysiloxane than the case without metal oxide. To understand the effect of quantities of metal oxide on the polysiloxane chain, the various polysiloxanes with different ratios of block unit were synthesized. Electrical conductivity was interpreted by percolation threshold theory to understand the dispersity of dense composite. The behavior of conductivity was in good agreement with theoretical value. The critical value was decreased as the quantities of metal oxide are increased. As a result, as the metal oxide increased on the polymer chain, the dispersity of metal filler was increased.

Base Metal's Price Hike and Chinese Economic Growth (Base Metal 가격상승과 중국의 경제성장)

  • Lee, Hyun-Bock
    • Economic and Environmental Geology
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    • v.43 no.5
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    • pp.523-528
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    • 2010
  • With the financial crisis from USA had negative impacts on the real economy, base metals price on LME was downward in 4 quarter of 2008. Following the deepest global downturn in recent history, economic growth solidified and broadened to advanced countries and simultaneously the price of base metal on LME showed a rising curve over 2009. There are three factors supported an upward tendency of base metal's price. The First factor is the US economy recovery, the second factor is the weak dollar, the third factor is the chinese base metal demand. Among the factors, the last one is a major factor. Therefore, this study analyze the factor of the movement of price of base metal with linear regression analysis. The result of analysis show that the chinese GDP growth has effect on the recent upward base metal price. Despite the result, the upward movement is difficult to be sustained without the full recovery of advanced economies.

Biochemical and Biodiversity Insights into Heavy Metal Ion-Responsive Transcription Regulators for Synthetic Biological Heavy Metal Sensors

  • Jung, Jaejoon;Lee, Sang Jun
    • Journal of Microbiology and Biotechnology
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    • v.29 no.10
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    • pp.1522-1542
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    • 2019
  • To adapt to environmental changes and to maintain cellular homeostasis, microorganisms adjust the intracellular concentrations of biochemical compounds, including metal ions; these are essential for the catalytic function of many enzymes in cells, but excessive amounts of essential metals and heavy metals cause cellular damage. Metal-responsive transcriptional regulators play pivotal roles in metal uptake, pumping out, sequestration, and oxidation or reduction to a less toxic status via regulating the expression of the detoxification-related genes. The sensory and regulatory functions of the metalloregulators have made them as attractive biological parts for synthetic biology, and the exceptional sensitivity and selectivity of metalloregulators toward metal ions have been used in heavy metal biosensors to cope with prevalent heavy metal contamination. Due to their importance, substantial efforts have been made to characterize heavy metal-responsive transcriptional regulators and to develop heavy metal-sensing biosensors. In this review, we summarize the biochemical data for the two major metalloregulator families, SmtB/ArsR and MerR, to describe their metal-binding sites, specific chelating chemistry, and conformational changes. Based on our understanding of the regulatory mechanisms, previously developed metal biosensors are examined to point out their limitations, such as high background noise and a lack of well-characterized biological parts. We discuss several strategies to improve the functionality of the metal biosensors, such as reducing the background noise and amplifying the output signal. From the perspective of making heavy metal biosensors, we suggest that the characterization of novel metalloregulators and the fabrication of exquisitely designed genetic circuits will be required.

Metal Transfer Characteristics of Aluminium under Pulsed Current Metal Inert Gas Welding (알루미늄의 펄스 전류 미그 용접)

  • 최재호;최병도;김용석
    • Journal of Welding and Joining
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    • v.20 no.5
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    • pp.127-133
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    • 2002
  • In this study, metal transfer characteristics in pulsed current metal inert gas (MIG) welding of aluminum was investigated. Based on the metal transfer characteristics from direct current electrode negative MIG welding, the one drop per one pulse(ODOP) condition was predicted and compared with experimental data. The results indicated that experimental pulse range for the ODOP condition is wider than that predicted from the DCEP MIG welding data. In addition, more stable metal trnasfer behavior was obtained at the higher end of the ODOP condition.

Microbial Metal Transformations

  • Gadd, Geoffrey M.
    • Journal of Microbiology
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    • v.39 no.2
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    • pp.83-88
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    • 2001
  • There is considerable interest in how microbiological processes can affect the behaviour of metal contaminants in natural and engineered environments and their potential for bioremediation. The extent to which microorganisms can affect metal contaminants is dependent on the identity and chemical form of the metal and the physical and chemical nature of the contaminated site or substance. In general terms, microbial processes which solubilize metals increase their bioavailability and potential toxicity, whereas those that immobilize them reduce bioavailability. The balance between mobilization and immobilization varies depending on the metal, the organisms, their environment and physico-chemical conditions.

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Noble metal catalysts for water gas shift reaction and their effectiveness factor (귀금속 계열 촉매의 수성가스전환반응특성과 유효인자)

  • Lim, Sung-Kwang;Bae, Joong-Myeon;Kim, Ki-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.514-517
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    • 2008
  • Water gas shift(WGS) is an important step in fuel process for fuel cells, and improperness of commercial WGS catalysts for use in fuel cell systems has prompted numerous researches on noble metal catalysts. A selected noble metal catalyst for water gas shift reaction(WGS) was prepared with various metal loadings. The prepared catalysts were tested under two feeding conditions. At moderate residence time, carbon monoxide conversion was much higher on the noble metal catalysts as compared to commercial high-temperature shift catalyst. Effects of metal loading were examined by activity tests at short residence time. Higher metal loading effected higher reaction rate. The kinetic data was fitted to simple reaction equations and effectiveness factor was estimated. The results suggest the necessity of a structural design for the highly active noble metal catalysts.

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A study on the development of Ti-Cu-Ni-Si insert metal for Ti alloys (Ti합금 접합용 Ti-Cu-Ni-Si계 삽입금속의 개발에 관한 연구)

  • 김경미;우인수;강정윤;이상래
    • Journal of Welding and Joining
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    • v.14 no.1
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    • pp.47-56
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    • 1996
  • The purpose of this study is to develope an insert metal which can be brazed at lower temperature than the conventionally used insert metal and provide higher strength joint than base metal. In the review of binary phase diagram concerning Ti, Cu and Ni resulted in the discovery of Si having eutectic composition with them. The microstructure and the distribution of elements in reaction zone between CP Ti and insert metal were investigated by Optical Microscopy, SEM/EDX, EPMA, X-RAY. The newly developed insert metal is Ti-15wt%Cu-18wt%Ni-2wt%Si, which can yield the lower brazing temperature(1183K) compared with the conventional Ti-Cu-Ni system insert metal. The joints with this insert metal had tensile strength of 385MPa in the bonding temperature range of 1183K to 1243K.

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A study of minimizing heavy metal content in metal complex dye development (중금속 최소화를 위한 메탈 함유 염료 개발에 관한 연구)

  • Kim, So-Jin;Park, Young-Hwan;Lee, Hea-Jung;Lim, Jae-Ho;Ryu, Tae-Soo
    • Journal of Fashion Business
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    • v.13 no.5
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    • pp.55-65
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    • 2009
  • Metal complex dyes are usually used to dye amide fiber such as wool, silk and nylon to achieve high concentrated color and excellent color fastness. However, metal complex dyes that contain various heavy metal components cause not only serious environmental problem but also human health. In this study the ordinary 1:2 metal acid dyes and the modified 1:2 metal dyes, which are environmental friendly, are compared and analyzed in existing dyes investigated the trends in the evaluation system of their harmfulness, containing heavy metals and examined exhaustion rates and dyeing characteristics.

Decreased Effectiveness on Cytotoxicity of Metal-Metal and Metal-Chelator Combinations (중금속 상호간의 작용 및 착화제에 의한 세포독성의 억제효과)

  • Kim, Jai-Min
    • Journal of Korean Ophthalmic Optics Society
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    • v.1 no.1
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    • pp.115-118
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    • 1996
  • The study on the cytotoxicities of heavy metals, metal-metal and metal-chelator combinations was carried out to evaluate the cytotoxic effect of those on mouse L929 fibroblasts. The colorimetric assays (NR and MTT) were conveniently carried out in 96-well microtiter plates. The rank order was Cd > Zn Ni > Cr(III) for the heavy metals tested. Examination of the effect of metal-metal interaction on cytotoxicity showed a moderate reduction of cadmium toxicity by zinc. The colorimetric assays were also effectively used to investigate the effect of the chelators, ethylenediamine tetra acetic acid (EDTA) and chitosan. Reduction of heavy metal toxixity by chelator was efficient.

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