• Title/Summary/Keyword: Melt processing

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Crystallization Behavior of Ti-(50-x)Ni-xCu(at%) (x = 20-30) Alloy Ribbons

  • Kim, Min-Su;Jeon, Young-Min;Im, Yeon-Min;Lee, Yong-Hee;Nam, Tae-Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.1
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    • pp.20-23
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    • 2011
  • Amorphous Ti-(50-x)Ni-xCu (at%) (x = 20, 25, 27, 30) alloy ribbons were prepared by melt spinning. Subsequently, the crystallization behavior of the alloy ribbons was investigated by X-ray diffraction and differential scanning calorimetry. ${\Delta}T$ (the temperature gap between $T_g$ and $T_x$) increased from 33 K to 47 K and the wavenumber ($Q_p$) decreased from 29.44 $nm^{-1}$ to 29.29 $nm^{-1}$ with increasing Cu content from 20 at% to 30 at%. The activation energy for crystallization decreased from 188.5 kJ/mol to 170.6 kJ/mol with increasing Cu content from 20 at% to 25 at%; afterwards, the activation energy remained near constant. Crystallization occurred in two-stage: amorphous-B2-$TiCu_2$ in Ti-Ni-Cu alloys with Cu content less than 25 at%, while it occurred in three-stage; amorphous-B2-TiCu-$TiCu_2$ in Ti-Ni-Cu alloys with Cu content more than 27 at%.

A Study on the Relationship between Residual Stress and Wear Peroperty in Hypereutectic Al-Si Alloys (과공정 Al-Si 합금의 마모 특성에 미치는 잔류응력의 영향에 관한 연구)

  • Kim, Heon-Joo;Kim, Chang-Gyu
    • Journal of Korea Foundry Society
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    • v.20 no.2
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    • pp.89-96
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    • 2000
  • The effects of modification processing on the refinement of primary Si and the wear behavior of hyper-eutectic Al-Si alloys have been mainly investigated. Refining effects of primary Si in Al-17%Si alloy was more efficient than that of B.390 alloy. Optimum condition of getting the finest primary Si microstructure was when AlCuP modifier is added into the melt at $750^{\circ}C$ and held it at $700^{\circ}C$ for 30 minutes. Wear loss in the specimens of as-cast condition decreases as the size of primary Si decreases, in the order of B.390 alloy, B.390 alloy with AlCuP addition, Al-17%Si alloy and Al-17%Si alloy with AlCuP addition. Wear loss in the aged condition of Al-17%Si alloy, B.390 alloy and B.390 alloy with AlCuP addition decreased due to the increase of compressive residual stress in the matrix by the aging treatment. While, wear loss increased in the aged specimens of Al-17%Si alloy with AlCuP addition and Hepworth addition in which compressive residual stress decreases by the aging treatment. Therefore, it is assumed that higher compressive residual stress in the matrix can reduce the wear loss in composite materials such as hyper-eutectic Al-Si alloys.

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A study on burr generation of laser micro-hole drilling for copper foil (Copper 박막의 레이저 미세홀 가공이 버 생성에 관한 연구)

  • Oh J.Y.;Shin B.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.873-877
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    • 2005
  • The burr of micro drilling and micro cutting on thin metal film is a major obstacle to mass production for micro PCB boards in micro technologies of personal computing and telecom explosion. As the burr affects on the assembling process, it is necessary to study continuously on control or elimination of the burr. In order to get higher valued products, it is also needed to competitive techniques with the high resolution. In this paper, we studied experimentally the burr generation that when it is processed on the copper foil by laser in micro-hole machining. Unlike mechanical machining the burr produced on substrate is a resultants of melt and re-solidification of a melten metal which was heated and treated by laser. And higher laser energy increases the size of burr. Therefor in micro-drilling with laser, it is difficult to reduce the effects of burr for very thin metal sheets. We investigated the stale of the burr and analyzed the laser ablation Cu micro machining with respect to laser intensity and processing time.

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Effects of Additional Bubbling on RH Vacuum Degassing Process with Water Model Experiment (수모델을 사용한 RH 진공 탈가스장치에서의 추가 버블링 효과)

  • Jang, Young-Hwan;Kim, Young-Tae;Yi, Kyung-Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.424-429
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    • 2010
  • In the RH process, it is possible to obtain quicker processing times by enhancing the decarburization rates at a low carbon range of steel melt through Ar gas injection into the vacuum vessel. The RH decarburization reaction was simulated through a dissolved oxygen removal reaction by injecting nitrogen into a 1/8 scale RH water model system. The gas nozzles for the N$_{2}$ injection into the vacuum vessel were located at the lowest level of the vessel's outer wall. The nitrogen bubbling in the vacuum vessel resulted in an increase in the reaction rate constant, which rose in accordance with an increase in the bubbling flow rate and number of nozzles used. However, there was almost no variation in the reaction rate constant, which depended on the horizontal positions of the bubbling nozzles.

A Study on the Effect of Primer Processing Method on the Mechanical Properties of Impact Relief Air Cushion Materials Prepared through Thermal Film Laminating (프라이머 가공 방법이 열융착 필름 라미네이팅으로 제조한 고충격 대응 에어쿠션 소재의 물성에 미치는 영향 연구)

  • Kim, Ji Yeon;Kim, Hun Min;Min, Mun Hong
    • Textile Coloration and Finishing
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    • v.34 no.3
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    • pp.173-184
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    • 2022
  • In this study, the TPU film was laminated on an aramid fabric or circular knits in order to implement an air cushion material that can respond to high impact forces in case of a fall and is easy to expand. To increase the bonding strength between the fabric layer and the film layer, a primer layer was formed in two ways: one for thermally bonding and laminating PET film and two for coating and aging hot melt type PUR adhesive. The tensile strength of the aramid air cushion was 2.5 times higher than that of the circular knits, but the tensile elongation of the aramid air cushion was very low compared to that of the circular knits. The tear strength of the aramid air cushion was about twice or more superior to that of the circular knits, the primer treatment method was good at A, and the peel strength was excellent at method A. The aramid air cushion was the lightest in weight. Summarizing the above results, it was best to combine the air cushion material with aramid woven fabric and primer treatment method A to cope with the high impact force applied when falling.

Effects of Amount of Second Cold-Reduction on Secondary Recrystallization and Texture Development in Grain-Oriented Silicon Steel

  • Yoon, Young-Ku;Lee, Taek-Dong
    • Nuclear Engineering and Technology
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    • v.3 no.3
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    • pp.129-140
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    • 1971
  • Two laboratory-melt heats of 3.25 silicon-iron were made and processed according to a normal commercial practice. Some of the important processing variables that were studied in relation to secondary recrystallization and texture development were contents of manganese and sulfur, heat-treatments after hot-rolling that were used to achieve different hot-rolled microstructures, and amounts of second cold-reduction. The main effort of the present study was directed toward elucidating the relationships among the amount of second cold-reduction, activation energies associated with secondary recrystallization and texture development. The specimens that had been cold-reduced 10% exhibited only grain growth by strain-induced grain boundary migration and did not exhibit secondary recrystallization. Secondary recrystallization did rot appear to completely occur in the 30% cold-reduced specimens, although the nucleation for secondary recrystallization was observed. The second cold-reduction in an amount of 50% was shown to be the optimun for secondary recrystallization and texture development by subsequent processing.

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Residual stresses and viscoelastic deformation of an injection molded automotive part

  • Kim, Sung-Ho;Kim, Chae-Hwan;Oh, Hwa-Jin;Choi, Chi-Hoon;Kim, Byoung-Yoon;Youn, Jae-Ryoun
    • Korea-Australia Rheology Journal
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    • v.19 no.4
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    • pp.183-190
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    • 2007
  • Injection molding is one of the most common operations in polymer processing. Good quality products are usually obtained and major post-processing treatment is not required. However, residual stresses which exist in plastic parts affect the final shape and mechanical properties after ejection. Residual stresses are caused by polymer melt flow, pressure distribution, non-uniform temperature field, and density distribution. Residual stresses are predicted in this study by numerical methods using commercially available softwares, $Hypermesh^{TM},\;Moldflow^{TM}\;and\;ABAQUS^{TM}$. Cavity filling, packing, and cooling stages are simulated to predict residual stress field right after ejection by assuming an isotropic elastic solid. Thermo-viscoelastic stress analysis is carried out to predict deformation and residual stress distribution after annealing of the part. Residual stresses are measured by the hole drilling method because the automotive part selected in this study has a complex shape. Residual stress distribution predicted by the thermal stress analysis is compared with the measurement results obtained by the hole drilling method. The molded specimen has residual stress distribution in tension, compression, and tension from the surface to the center of the part. Viscoelastic deformation of the part is predicted during annealing and the deformed geometry is compared with that measured by a three dimensional scanner. The viscoelastic stress analysis with a thermal cycle will enable us to predict long term behavior of the injection molded polymeric parts.

Eco-friendly Fabrication Process of Al-Ti-C Grain Refiner

  • Cho, Hoon;Kim, Bong-Hwan
    • Journal of Korea Foundry Society
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    • v.30 no.4
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    • pp.147-150
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    • 2010
  • An eco-friendly production technique of Al-8.6Ti-0.025C refiner was developed by melting a Al-Ti master alloy in a graphite crucible, in which the potential nucleation site, TiC effectively formed by the spontaneous in-situ reaction between excessive Ti and carbon from graphite crucible. The A3003 alloy refined by the Al-8.6Ti-0.025C showed effectively refined macrostructure and enhanced mechanical properties comparable to the commercial Al-Ti-B refiner. The effective refinement was achieved in a shorter compare to the melt-treating time commercial Al-Ti-B refiner.

Effect of Processing Parameters on Direct Fabrication of Polycrystalline Silicon Wafer (다결정 실리콘 웨이퍼 직접제조에 대한 공정변수 영향)

  • Wi, Sung-Min;Lee, Jin-Seok;Jang, Bo-Yun;Kim, Joon-Soo;Ahn, Young-Soo;Yoon, Woo-Young
    • Journal of Korea Foundry Society
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    • v.33 no.4
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    • pp.157-161
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    • 2013
  • A ribbon-type polycrystalline silicon wafer was directly fabricated from liquid silicon via a novel technique for both a fast growth rate and large grain size by exploiting gas pressure. Effects of processing parameters such as moving speed of a dummy bar and the length of the solidification zone on continuous casting of the silicon wafer were investigated. Silicon melt extruded from the growth region in the case of a solidification zone with a length of 1cm due to incomplete solidification. In case of a solidification zone wieh a length of 2 cm, on the other hand, continuous casting of the wafer was impossible due to the volume expansion of silicon derived from the liquid-solid transformation in solidification zone. Consequently, the optimal length of the solidification zone was 1.5 cm for maintaining the position of the solid-liquid interface in the solidification zone. The silicon wafer could be continuously casted when the moving speed of the dummy bar was 6 cm/min, but liquid silicon extruded from the growth region without solidification when the moving speed of the dummy bar was ${\geq}$ 9 cm/min. This was due to a shift of the position of the solid-liquid interface from the solidification zone to the moving area. The present study reports experimental findings on a new direct growth system for obtaining silicon wafers with both high quality and productivity, as a candidate for an alternate route for the fabrication of ribbon-type silicon wafers.

Effect of Laser Processing Patterns on the Bonding Interface Quality during Laser Sintering of Magnesium Alloys with Zirconia (마그네슘 합금 표면의 지르코니아 분말 레이저 소결과정에서 조사 패턴이 접합 계면 품질에 미치는 영향)

  • Yoon, Sangwoo;Kim, Joohan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.2
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    • pp.51-57
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    • 2021
  • The quality of the ceramic sintered coating on a metal surface through laser surface treatment is affected by the laser irradiation pattern. Depending on the laser irradiation pattern, the amount of residual stress and heat applied or accumulated on the surface increases or decreases, affecting the thickness attained in the ceramic sintering area. When the heat energy accumulated in the sintering area is high, the ceramic and the metal alloy melt and sufficiently mix to form a homogeneous and thick bonding interface. In this study, the thermal energy accumulation in the region sintered with zirconia was controlled using four types of laser processing patterns. The thickness of the diffusion region is analyzed by laser-induced breakdown spectroscopy of Mg-ZrO2 generated by laser sintering zirconia powder on the magnesium alloy surface. On the basis of the analysis of the Mg and Zr present in the sintered region through LIBS, the effect of the irradiation pattern on the sintering quality is confirmed by comparing and analyzing the heat and mass transfer tendency of the diffusion layer and the degree of diffusion according to the irradiation pattern. The derived diffusion coefficients differed by up to 9.8 times for each laser scanning pattern.