• Journal of the Korean Ceramic Society
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• v.53 no.3
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• pp.343-348
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• 2016

Manganese and $TiO_2$ grown on Activated Carbon Fiber (ACF) was synthesized by hydrothermal method. The prepared composites were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray (EDX). The catalytic behavior was investigated through the decomposition of methylene blue (MB) and methyl orange (MO) as standard dyes under visible light. The degradation performance of the degraded standard dye solutions was determined by UV-Vis spectrophotometry. This enhanced photocatalytic activity arises from the positive synergetic effect among the Mn, $TiO_2$ and ACF in this heterogeneous photocatalyst. The process contributes to the release of abundant photocatalytic sites of Mn and $TiO_2$ and improves the photocatalytic efficiency. The excellent adsorption and photocatalytic effect with the explanation of the synergetic mechanism are very useful not only for fundamental research but also for potential practical applications.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.1539-1542
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• 2005

Self-assembled monolayers (SAMs) formed by the adsorption of alkanethiols, $HS(CH_2)_nX$, where X is an organic functional group, onto gold surfaces have attracted widespread interest as templates for the fabrication of molecular and biomolecular microstructures. Previously photopatterning has been thought of as being restricted to the micron scale, because of the wellknown diffraction limit. So, we have explored a novel approach to nanofabrication by utilizing a femtosecond laser coupled to a near-field scanning optical microscope (NSOM).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.361-362
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• 2005

Antimony doped tin oxide(ATO) nano powders have been synthesized by homogeneous precipitation method using $SnCl_4\cdot5H_2O$ for precursor, $SbCl_3$ as doped material and urea. The hydrolysis of urea and conductive mechanism and Heat treatment was performed at the temperature from $500^{\circ}C$ to $700^{\circ}C$ in air. The ATO nano powders are characterized by means of Thermogravimetry differential thermal analyzer (TG-DTA), X-ray diffraction (XRD), Brunauer, Emmett, and Teller adsorption (BET), Scanning electron microscopy (SEM) ATO nano powders with an average size of nm and the highest surface area 129 $m^2g^{-1}$ are obtained.

• Journal of the Korean Ceramic Society
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• v.55 no.3
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• pp.261-266
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• 2018

Hollow or bumpy ZnO structures with micrometer-size features have been investigated as photocatalysts for water purification due to their high surface area available for reaction with harmful organic molecules and relatively large size for easy separation after finishing the photocatalytic reaction. In this study, selective synthesis of ZnO hollow or crumpled microspheres was performed using a simple and versatile ultrasonic spray pyrolysis process with various zinc precursors. The morphologies, phases, specific surface areas, and optical properties of the microspheres were characterized using X-ray diffraction, scanning electronic microscopy, nitrogen adsorption-desorption isotherms, and UV-vis spectroscopy. In addition, the mechanism underlying the formation of different morphologies and their photocatalytic activities were systematically investigated.

• Applied Chemistry for Engineering
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• v.4 no.2
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• pp.416-422
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• 1993

In order to prepare high performance polymeric membrane, the crosslinked chitosan(C. Chitosan)membrane was prepared, the transport and the selective separation of the metal ions through the membrane were investigated. It was observed that the transport rates of the metal ions through the membrane increased according to the decreasing of the initial pH in downstream solution. Proton pump mechanism for this transport phenomenon was suggested. The transport selectivity is dependent on the selective adsorption resulting from the complex formation of chitosan with each metal ion. The separatin factor(${\alpha}_{Cu}{^{2+}}$) for the membrane was 9.5.

• Nuclear Engineering and Technology
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• v.16 no.2
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• pp.80-88
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• 1984

The removal mechanism of air borne methyl iodide by triethylenediamine (TEDA) impregnated charcoal bed was investigated. The analysis of experimental data indicates that pore diffusion is the rate controlling step when the air velocity is over 20cm/sec, and both fore diffusion resistance and external mass transfer resistance are contributed to the overall resistance when the air velocity is 10cm/sec. The adsorption model to describe the performance of impregnated charcoal bed under dry condition where water vapors do not exist in air, is proposed. The calculated values and experimental results are well matched.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.182-183
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• 2017

This research identifies radon gas absorption mechanism by adsorption materials, replacing gypsum board with radon emissions, the density and absorption rates of magnesium were carried out using vermiculite, anthracite, powdered active carbon, bentonite, illite, diatomite as a basic study on the fire resistance type of radon Gas reduction type with absorption and decomposition. As a result of the experiment, diatomite showed the lowest density, and the highestt value was the highest. For the absorption rate, bentonite showed the highest absorption rate, and the anthracite showed the lowest absorption rate.

• Macromolecular Research
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• v.8 no.4
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• pp.153-164
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• 2000

By electrodeposition (ED) using a monomeric- and two polymeric coupling agents, the interfacial shear strength (IFSS) of carbon fiber/epoxy composites was investigated by fragmentation test. ED results were compared with the dipping and the untreated cases under dry and wet conditions. Multi-fiber composites (MFC) were used for the direct comparison for the untreated and the treated cases. Various treating conditions including time, concentration and temperature were evaluated, respectively. Under dry and wet conditions ED treatment exhibited much higher IFSS improvement compared to the dipping and the untreated cases. Monomeric- and polymeric coupling agents exhibited the comparative IFSS improvement. Adsorption mechanism between coupling agents and carbon fiber was analyzed in terms of the electrolyte molecular interactions during ED process based on to the chain mobility. The microfailure modes occurring from the fiber break, matrix and interlayer cracks were correlated to IFSS.

• Bulletin of the Korean Chemical Society
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• v.9 no.2
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• pp.81-84
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• 1988

The CO oxidation was performed on $H_2$-reduced NiO-${\alpha}-Fe_2O_3$ in the temperature range 150-$250^{\circ}C$. The kinetic study and the conductivity measurements indicate the oxidation reaction follows Langmuir-Rideal type process that is uncommon in heterogeneous catalyst$^1$. No active site is found on the catalyst surface for CO adsorption, but an oxygen vacancy adsorbs an oxygen, and this step is rate initiation. The partial orders are half for $O_2$ and first for CO, respectively. Apparent activation energy for over-all reaction is 9.05 kcal/mol.

• Applied Science and Convergence Technology
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• v.23 no.4
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• pp.169-178
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• 2014

Fluid model based numerical analysis is done to simulate a low damage etch back system for 20 nm scale semiconductor fabrication. Etch back should be done conformally with very high material selectivity. One possible mechanism is three steps: reactive radical generation, adsorption and thermal desorption. In this study, plasma generation and transport steps are analyzed by a commercial plasma modeling software package, CFD-ACE+. Ar + $CF_4$ ICP was used as a model and the effect of reactive gas inlet position was investigated in 2D and 3D. At 200~300 mTorr of gas pressure, separated gas inlet scheme is analyzed to work well and generated higher density of F and $F_2$ radicals in the lower chamber region while suppressing ions reach to the wafer by a double layer conducting barrier.