• 공업화학
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• 제34권3호
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• pp.213-220
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• 2023

혼합기질막(mixed-matrix membrane, MMM)은 고성능 충전제가 고분자 기질에 분산된 구조로, 지난 30년간 이를 이용한 기체분리 연구가 집중적으로 수행되었다. 일반적으로 MMM은 고분자 막보다 우수한 기체 분리 성능을 가지고 있으며, 다결정 막에 비해 좋은 확장성을 보인다. 그러나 이러한 잠재성에도 불구하고, MMM의 상용화는 여러 가지 어려운 문제들로 인해 지연되고 있다. MMM의 주요 문제 중 하나는 충전제와 고분자 사이의 부적절한 계면 상호작용으로 결함(즉, 개면 공극 등)이 형성될 수 있다는 것이다. 따라서 많은 MMM 연구에서 이러한 계면의 문제를 해결하기 위한 전략이 제시되었다. 하지만 계면상의 상호작용으로 MMM이 가진 문제점들을 해결하려는 과학적 접근에 비해 손쉽고 효과적으로 대면적의 MMM을 제조하기 위한 공학적 접근은 상대적으로 간과되어 왔다. 본 총설에서는 MMM의 대면적화를 위한 공학적인 접근 중 하나인 고분자 변형을 통해 가능해진 금속-유기 골격체(metal-organic framework, MOF)의 원위치 형성을 이용한 MMM 제막 방법을 소개하고자 한다. 이 새로운 제막법은 현재 MMM이 직면하고 있는 문제들을 공학적인 접근으로 효과적으로 해결하여 MMM의 상용화를 촉진시킬 수 있다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.8.2-8.2
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• 2011

This talk demonstrates diverse patterned structures utilizing in-situ self-organization and phase separation of the materials into an ordered fashion. The patterned structures in this talk include electrospun nanofibers and electrosprayed microparticles embedding small particles. The positions of the small particles are in-situ controlled during the electrohydrodynamic process by the interaction with the polymer matrix. Another topic of the talk includes selective deposition of spin-coated materials on a corrugated surface that was prepared by buckling of polymer thin films. Solution are strong tendency to be positioned in the trench area of the surface, which facilitates the fabrication of micropatterns of diverse materials.

• 한국막학회:학술대회논문집
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• 한국막학회 1995년도 제3회 심포지움 (분리막 연구의 최신동향)
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• pp.73-85
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• 1995

The asymmetric hollow fiber membranes were prepared by the wet spining of polyetherimide dope solution and the effect of hollow fiber structures on the permeation characteristics of carbon dioxide and nitrogen gases through these membrane were investigated. As the concentration of the $\gamma$-butyrolactone (GBL) in dope solution, acting as a swelling agent was increased, the structure of hollow fiber was changed from the finger to sponge type. The permeabilities of gases (CO$_{2}$, N$_{2}$) through these membrane were measured over the wide range of pressure under different temperature. The effect of water vapor on the permeabilities of gases was also investigated. The measured permeabilities showed the different characteristics depending on the structure of membranes. It was found that the flow through the pores were dominant over the polymers matrix. Blocking effect by water vapor in the pores of skin layer greatly improved the ideal separation factor of carbon dioxide/nitrogen.

• Biotechnology and Bioprocess Engineering:BBE
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• 제11권3호
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• pp.179-186
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• 2006

End-Labeled Free-Solution Electrophoresis (ELFSE) is a new technique that is a promising bioconjugate method for DNA sequencing (or separation) and genotyping by both capillary and microfluidic device electrophoresis. Because ELFSE enables high-resolution electrophoretic separation in aqueous buffer alone (i.e., without a polymer matrix), it eliminates the need to load viscous polymer networks into electrophoresis microchannels. To achieve microchannel DNA separations with high performance, ELFSE requires monodisperse perturbing entities (i.e., drag-tags), which create a large amount of frictional drag when pulled behind DNA during free-solution electrophoresis, and which have other properties suitable for microchannel electrophoresis. In this article, the theoretical concepts of ELFSE and the required characteristics of the drag-tag molecules for the ultimate performance of ELFSE are reviewed. Additionally, the merits and limitations of current drag-tags are also discussed in the context of recent experimental data of ELFSE separation (or sequencing).

• Applied Microscopy
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• 제43권2호
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• pp.98-101
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• 2013

In the present study, formation of yard and shell has been investigated in as-melt-spun $Gd_{30}Ti_{25}Al_{25}Co_{20}$ alloy using a variety of transmission electron microscopy techniques. The phase separation during cooling leads to the formation of the microstructure consisting of amorphous droplets with different size scales embedded in the amorphous matrix. Due to the interdiffusion at the interface after the first-step phase separation, ~50 nm-thick yard develops on the surface of the primary droplet particle. Due to the critical wetting phenomenon, ~5 nm thickness shell enveloping the droplet forms. The sell is enriched in Co and Ti, implying that the composition is close to that of the droplet.

• 한국정밀공학회지
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• 제15권6호
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• pp.145-152
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• 1998

This paper presents an optimum design of a rotor-bearing spindle system for a ultra centrifuge (80,000 RPM) supported by ball bearings with nonlinear stiffness characteristics. To obtain the nonlinear bearing stiffnesses, a ball bearing is modeled in five degrees of freedom and is analyzed quasi-statically. The dynamic behaviors of the nonlinear rotor-bearing system are analyzed by using a transfer-matrix method iteratively. For optimization. we use the cost function that simultaneously minimizes the weight of a rotor and maximizes the separation margins to yield the critical speeds as far from the operating speed as possible. Augmented Lagrange Multiplier (ALM) method is employed for the nonlinear optimization problem. The result shows that the rotor-bearing spindle system is optimized to obtain 9.5％ weight reduction and 21％ separation margin.

• 한국초전도ㆍ저온공학회논문지
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• 제8권3호
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• pp.41-44
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• 2006

This study introduced waste water treatment method by superconducting HGMS(High Gradient Magnetic Separation). HGMS treatment method is high efficient method for various waste water, we have surveyed superconducting magnetic separation technology. We fabricated the prototypes of magnetic matrix filter consisting of stainless steel mesh, which is a core component in the magnetic separation system. In our basic preliminary experiment using HGMS, it was made clear that the fine para-magnetic particles in the wasted water obtained from steelmaking process of POSCO can be separated with high efficiency.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2004년도 요약집 춘계학술발표대회
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• pp.377.2-377.2
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• 2004

• 약학회지
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• 제59권3호
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• pp.113-119
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• 2015

Protein phosphorylation is one of most important post-translational modifications (PTMs) and plays an important role in regulation of protein function. Here we develop a method for a global identification of phosphopeptides and phosphorylation sites using nano-LC MS/MS. We compared two separation methods, C4 and strong cation ion exchange (SCX). Before phosphopeptides enrichment with $TiO_2$, total proteins from Rat 1 cells have been separated using C4 column or tryptic peptides of proteins from the cells have been separated using SCX column. Finally, we have detected 52 phosphorylation sites on 41 proteins from SCX method and 375 phosphorylation sites on 252 proteins from C4 method, and determined the function and localization of identified phosphoproteins using DAVID software. In particular, we showed new phosphorylation sites from membrane proteins related to various cell signaling mechanisms. This method may contribute to study global signal networks induced by various signals including ligands and drugs.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2000년도 제15차 학술회의논문집
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• pp.471-471
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• 2000

This paper presents a new kurtosis-based algorithm for blind separation of convolutively mixed source signals. The algorithm whitens the signals not only spatially but also temporally beforehand. A separator is built for the whitened signals and it exists in the set of para-unitary matrices. Since the set forms a curved manifold, it is hard to treat its elements. In order to avoid the difficulty, this paper introduces the Cayley transformation for the para-unitary matrices. The transformed matrix is referred to as para-skew-Hermitian matrix and the set of such matrices forms a linear space. In the set of all para-skew-Hermitian matrices, the kurtosis-based algorithm obtains a desired separator. This paper also shows the algorithm's application to electrogastrogram datum which are observed by 4 electrodes on subjects' abdomen around their stomachs. An electrogastrogram contains signals from a stomach and other organs. This paper obtains independent components by the algorithm and then extracts the signal corresponding to the stomach from the data.