• Title/Summary/Keyword: Material substitution

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Piezoelectric and dielectric Properties for Multilayer Piezoelectric Transformer Of Modified $PbTiO_3$ system ceramics (적층 압전 변압기용 변성 $PbTiO_3$ 세라믹스의 압전 및 유전 특성)

  • Yoo, Kyung-Jin;Yoo, Ju-Hyun;Jeong, Yeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.344-345
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    • 2006
  • In this study, in order to develop low temperature sintering piezoelectric transformer, $(Pb_{0.99-x}Ca_xSr_{0.01})Ti_{0.96}(Mn_{1/3}Sb_{2/3})_{0.04}O_3$ ceramic systems were fabricated using $Na_2CO_3-Li_2CO_3$ as sintering aids and investigated with the amount of Ca substitution. The piezoelectric transformer requires high electromechanical coupling factor $k_t$ and high mechanical quality factor $Q_{mt}$ for generating high output power At the ($PbCaSr)Ti(MnSb)O_3$ ceramics with 24mol% Ca substitution sintered at $900^{\circ}C$, electromechanical coupling factor $k_t$ and mechanical quality factor $Q_{mt}$ showed the optimal values of 0.504 and 1655 respectively, for thickness vibration mode multilayer piezoelectric transformer application.

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Computational screening of electroactive indolequinone derivatives as high-performance active materials for aqueous redox flow batteries

  • Han, Young-Kyu;Jin, Chang-Soo
    • Current Applied Physics
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    • v.18 no.12
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    • pp.1507-1512
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    • 2018
  • The development of an organic-based aqueous redox flow battery (RFB) using quinone as an electroactive material has attracted great attention recently. This is because this battery is inexpensive, produces high energy density, and is environment friendly in stationary electrical energy storage applications. Herein, we investigate the redox potentials and solubilities of indole-5,6-quinone and indole-4,7-quinone derivatives in terms of the substituent effects of functional groups using theoretical calculations. Our results indicate that full-site substituted derivatives of indolequinone are more useful as active materials compared to single-site substituted derivatives. In particular, our calculations reveal that the substitution of $-PO_3H_2$ and $-SO_3H$ functional groups with multiple polar bonds is very effective in increasing the activity of the aqueous RFB. As a strategy to overcome the limitation that the aqueous solubility is intrinsically low because they are organic molecules, we suggest the substitution of functional groups with multiple polar bonds to the backbones of active organic materials. Among 180 indolequinone derivatives, 17 candidates that meet the redox potential standards ($${\leq_-}0.2V$$ or $${\geq_-}0.9V$$) and eight candidates with solubility exceeding 2 mol/L are identified. Three indolequinone derivatives that satisfy both conditions are finally presented as promising electroactive candidates for an aqueous RFB.

Development of Vacuum-Press Curing Equipment for the Substitution of Autoclave (오토클레이브 성형공정을 대체할 수 있는 진공가압식 성형장치 개발)

  • 박희관;윤영기;윤희석
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.39-42
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    • 2001
  • This paper addresses the development of VP curing equipment for the substitution of autoclave which has several limits in application. This equipment adopt vacuuming and pressurizing processes similarly to the autoclave, but has flexible pressurizing and movable system. The experiments were pursued to determine and to compare specific properties of the specimens produced by three kinds of processes; autoclave, hotpress, and VP. The results show that the VP curing equipment can produce the useful composite material with a little inferior quality to the autoclave, but better than the hotpress. Considering the movability of VP curing equipment, it can be expanded its application to the areas of composite patch-repaired structure in large objects.

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Effects of Partial Substitution of W for Ti in Titanium Dioxide

  • Lee, Eun-Seok
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.2
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    • pp.68-71
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    • 2011
  • [ $Ti_{1-x}W_xO_{2-y}$ ]solid solutions with compositions of x = 0.01(TW-1), x = 0.02(TW-2), x = 0.03(TW-3) and x = 0.04(TW-4) were prepared at 1,073 K in air under atmospheric pressure. All the solutions exhibited tetragonal symmetries. Nonstoichiometric chemical formulas have been obtained from oxidation-reduction titration and the partial substitution of $W^{6+}$ ions mainly caused the formation of $Ti^{3+}$ ion, rather than oxygen excess. Resistivities of the samples were highly dependent on humidity. The increase of the W amount resulted in an increase of $Ti^{3+}$ content, decrease of resistivity values and finally degradation of photocatalytic activities.

Physical and Mechanical Properties of Concrete Using Waste Activated Carbon (폐활성탄을 혼입한 콘크리트의 물리.역학적 성질)

  • Kang, Hyun-Soo;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.1
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    • pp.21-26
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    • 2009
  • This study was performed to evaluate the physical and mechanical properties of concrete using waste activated carbon. Materials used were ordinary portlant cement, crushed coarse aggregate, natural fine aggregate, waste activated carbon, and superplasticizer. The substitution ratios of waste activated carbon were 0,1,2,3,4,5,6,7,8,9 and 10%. The unit weight was decreased and water absorption ratio was increased with increasing the waste activated carbon content, respectively. When the substitution ratio of waste activated carbon was 3%, compressive strength, flexural strength and dynamic modulus of elastisity were more higher than that of the ordinary portland cement (OPC), and it was decreased with increasing the waste activated carbon content, respectively. The most effective contents of waste activated carbon was 2% in performance and 4% in practical use Accordingly, waste activated carbon can be used for concrete material.

Properties of Hardened Mortar Using Chlorine By-pass System Dust a Cement Substitution of Cement (CBS Dust를 시멘트 대체재로 활용하는 모르타르의 경화 특성)

  • Lee, Young-Jun;Lee, Hyuk-Ju;Hyun, Seung-Yong;Kim, Min-Sang;Lee, Dong-Joo;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.167-168
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    • 2018
  • In this study, use to CBS Dust as substitution of cement was explored. And the CBS Dust was intended to be used as a cement substitute, and the possibility as a potential water hardness stimulant for BS was investigated. Test results indicated that it can be used in with BS for a potential hydroponic stimulant.

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The effect of limestone chemical porperties and substitution amount on mechanical properties of cement mortar (석회석 혼합재의 화학특성이 시멘트 모르타르에 미치는 영향)

  • Suh, Dong-Kyun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.163-164
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    • 2022
  • Using the limestone powder as material that can substitute the clinker, it seems to get positive effect as filler and enhance workability of cement but the substitution amount and chemical properties of it can affect mechanical properties of cement. Thus, in this study, the effect limestone powder that has other properties on cement is evaluated. As a result, the workability enhancing effect was confirmed but deterioration of compressive strength was also checked. Later, with the view of workability, the experiment that the possibility of strength compensation by decreasing unit water weight of limestone powder cement is planned when the limestone powder is used.

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Preparation and Charecterization of Bromofullerenes in New Stoichiometry

  • Mehrotra, Reema;Lal, Darshan;Tripathi, V.S.;Mathur, G.N.
    • Carbon letters
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    • v.4 no.4
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    • pp.175-179
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    • 2003
  • It is well established that halogenated fullerene derivatives act as synthetic intermediates for further substitution via replacement with nucleophlies. In the present work, systematic studies were carried out on the synthesis of bromofullerenes under different experimental conditions. The effect of reaction time on the product formed was observed. We observed the formation of new compound of bromofullerenes in a different stoichiometric ratio i.e., $C_{60}Br_{14}$; in addition to previous reported bromofullerenes in the stoichiometric ratio of $C_{60}Br_6$, $C_{60}Br_8$, and $C_{60}Br_{24}$. The new derivative of bromofullerene was isolated and well characterized by various analytical techniques like FT-IR, TGA, DSC, and elemental analysis. In this paper, detail of the synthesis and characterization of the bromofullerene prepared are described. The yields obtained were better than those reported previously.

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Effect of Substitution of Chicken Breast for Alaska Pollack on Physico-chemical Characteristics and Quality in Surimi-like Materials Contained Different Cryoprotectants

  • Jin, Sang-Keun;Choi, Young-Jun;Hur, Sun-Jin
    • Food Science of Animal Resources
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    • v.31 no.2
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    • pp.215-223
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    • 2011
  • Surimi-like samples were divided into four groups (C, surimi-like material made from Alaska Pollack with all cryoprotectant ingredients; T1, surimi-like material made from chicken breast with sugar and a sorbitol-free cryoprotectant; T2, surimi-like material made from chicken breast with a sugar-free cryoprotectant; T3, surimi-like material made from chicken breast with all cryoprotectant ingredients). Water and protein content were lower in Alaska Pollack surimi-like material (C) than those in chicken breast surimi-like material. Centrifuge loss and cooking loss were higher in C than those in chicken breast surimi-like material. Lipid oxidation (thiobarbituric acid reactive substances) was lower in T3 than others during storage. In a sensory evaluation, overall acceptability was significantly higher in C than those in other samples during storage. As a result, we found that the raw material composition (Alaska Pollack or chicken breast) had a large influence on the physico-chemical characteristics and quality of surimi-like materials, whereas cryoprotectant composition may have less influence on the physico-chemical characteristics and quality of surimi-like materials.

Change of Electrochemical Characteristics Due to the Fe Doping in Lithium Manganese Oxide Electrode

  • Ju Jeh Beck;Kang Tae Young;Cho Sung Jin;Sohn Tae Won
    • Journal of the Korean Electrochemical Society
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    • v.7 no.3
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    • pp.131-137
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    • 2004
  • Sol-gel method which provides better electrochemical and physiochemical properties compared to the solid-state method was used to synthesize the material of $LiFe_yMn_{2-y}O_4$. Fe was substituted to increase the structural stability so that the effects of the substitution amount and sintering temperature were analyzed. XRD was used for the structural analysis of produced material, which in turn, showed the same cubic spinel structure as $LiMn_2O_4$ despite the substitution of $Fe^{3+}$. During the synthesis of $LiFe_yMn_{2-y}O_4$, as the sintering temperature and the doping amount of Fe(y=0.05, 0.1, 0.2)were increased, grain growth proceeded which in turn, showed a high crystalline and a large grain size, certain morphology with narrow specific surface area and large pore volume distribution was observed. In order to examine the ability for the practical use of the battery, charge-discharge tests were undertaken. When the substitution amount of $Fe^{3+}\;into\;LiMn_2O_4$ increased, the initial discharge capacity showed a tendency to decrease within the region of $3.0\~4.2V$ but when charge-discharge processes were repeated, other capacity maintenance properties turned out to be outstanding. In addition, when the sintering temperature was $800\~850^{\circ}C$, the initial capacity was small but showed very stable cycle performance. According to EVS(electrochemical voltage spectroscopy) test, $LiFe_yMn_{2-y}O_4(y=0,\;0.05,\;0.1,\;0.2)$ showed two plateau region and the typical peaks of manganese spinel structure when the substitution amount of $Fe^{3+}$ increased, the peak value at about 4.15V during the charge-discharge process showed a tendency to decrease. From the previous results, the local distortion due to the biphase within the region near 4.15V during the lithium extraction gave a phase transition to a more suitable single phase. When the transition was derived, the discharge capacity decreased. However the cycle performance showed an outstanding result.