• 제목/요약/키워드: Material Decomposition

검색결과 629건 처리시간 0.031초

Electrochemical Characterization of Electric Double Layer Capacitors Assembled with Pyrrolidinium-Based Ionic Liquid Electrolytes

  • Cho, Jinhyun;Shin, Won-Kyung;Kim, Dong-Won;Kim, Young Rae;Lee, Byung Jun;Kim, Sang-Gil
    • Journal of Electrochemical Science and Technology
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    • 제7권3호
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    • pp.199-205
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    • 2016
  • We present the electrochemical performance of electric double layer capacitors (EDLCs) assembled with pyrrolidinium (Pyr)-based ionic liquid electrolytes at 55 ℃. Cations with various alkyl chain lengths were employed in Pyr-based ionic liquids to investigate the effect of cation structure on the cycling stability of EDLCs. The EDLCs exhibited initial specific capacitances ranging from 122.4 to 131.6 F g−1 based on activated carbon material at 55 ℃. Cycling data and XPS results demonstrate that Pyr-based ionic liquid with longer alkyl chain is more effective for enhancing the cycling stability of EDLC by suppressing the reductive decomposition of pyrrolidinium cations during cycling at high temperatures.

Study on the response of circular thin plate under low velocity impact

  • Babaei, Hashem;Mostofi, Tohid Mirzababaie;Alitavoli, Majid
    • Geomechanics and Engineering
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    • 제9권2호
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    • pp.207-218
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    • 2015
  • In this paper, forming of fully clamped circular plate by using low velocity impact system has been investigated. This system consists of liquid shock tube and gravity drop hammer. A series of test on mild steel and aluminum alloy plates has been done. The effect of varying both impact load and the plate material on the deflection are described. This paper also presents a simple model to prediction of mid-point deflection of circular plate by using input-output experimental data. In this way, singular value decomposition (SVD) method is used in conjunction with dimensionless number incorporated in such complex process. The results of obtained model have very good agreement with experimental data and it provides a way of studying and understanding the plastic deformation of impact loads.

무한요소를 이용한 반무한영역의 추계론적 유한요소해석 (Stochastic FE analysis of semi-infinite domain using infinite elements)

  • 최창근;노혁천
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1998년도 가을 학술발표회 논문집
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    • pp.11-18
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    • 1998
  • In this paper the stochastic analysis of semi-infinite domain is presented using the weighted integral method, which is expanded to include the infinite finite elements. The semi-infinite domain can be thought as to have more uncertainties than the ordinary finite domain in material constants, which shows the needs of and the importance of the stochastic finite element analysis. The Bettess's infinite element is adopted with the theoretical decomposition of the strain matrix to calculate the deviatoric stiffness of the semi-infinite domains. The calculated value of mean and the covariance of the displacement are revealed to be larger than those given by the finite domain assumptions giving the rational results which should be considered in the design of structures on semi-infinite domains.

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수용성 폴리비닐알콜(PVA) 포장소재의 이용 (Review on PVA as a Water Soluble Packaging Material)

  • 이지윤;장시훈;박수일
    • 한국포장학회지
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    • 제15권1호
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    • pp.25-32
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    • 2009
  • It is now widely recognized that the disposal of packaging waste is an increasing environmental concern. Recent interest in polymer waste management of packaging materials has added incentive to the research. Poly(vinyl alcohol) is a readily biodegradable water-soluble polymer. However, this polymer cannot be processed by conventional extrusion technologies because the melting point of PVA is close to its decomposition temperature. Therefore, PVA films have been mostly prepared by solvent casting from water. Applications of PVA include sizing, binders, fibers, and films for agricultural chemicals and hospital laundry bags. A better understanding of PVA films, which also play important roles in the degradation of plastics, will expand the usage of PVA. Composite films based on PVA generally exhibit better mechanical and thermal properties than pure PVA. The aim of this review article is to review types, formation, and properties of PVA films and PVA based composite films used in packaging related researches.

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Mindlin 평판의 불확실거동에 대하여 (On the Uncertain Behavior of Mindlin Plates)

  • 노혁천;김인호
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2007년도 정기 학술대회 논문집
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    • pp.465-470
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    • 2007
  • In order to investigate the stochastic behavior of Mindlin plate under imperfection in the material and geometrical parameters, a stochastic finite element formulation is proposed. The effects of inter-correlations between random parameters on the response variability are also observed. The contribution from the random Poisson ratio is taken into account adopting a stochastic decomposition scheme. which expands the constitutive matrix into an infinite series of sub-matrices. In order to demonstrate the adequacy of the proposed scheme, a square plate with simple and fixed support is taken as an example, and the results are compared with those given in previous research in the literature as well as with the results of Monte Carlo analysis.

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수직통합 의사결정을 위한 계량분석모형 (A mathematical planning model for vertical integration)

  • 문상원
    • 경영과학
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    • 제10권1호
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    • pp.193-205
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    • 1993
  • This paper presents a mathematical model for a class of vertical integration decisions. The problem structure of interest consists of raw material vendors, components suppliers, components processing plants, final product (assembly) plants and external components buyers. Economic feasibility of operating components plants instead of keeping outside suppliers is our major concern. The model also determines assignment of product lines and production volumes to each open plant considering the cost impacts of economies of scale and plant complexity. The problem formulation leads to a concave, mixed integer mathematical program. Given the state of the art of nonlinear programming techniques, it is often not possible to find global optima for reasonably sized such problems. We developed an optimization solution algorithm within the framework of Benders decomposition for the case of a piecewise linear concave cost function. It is shown that our algorithm generates optimal solutions efficiently.

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A Study on Initiating Events Identification of the IS Process

  • Cho, Nam-Chul;Jae, Moo-Sung;Eon, Yang-Joon
    • International Journal of Safety
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    • 제5권1호
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    • pp.29-32
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    • 2006
  • There has been an increasing need for substitute energy development due to the dry up of the fossil fuel and environmental problems. Among the substitute energy under consideration, producing hydrogen from water without the accompanying release of carbon has become a promising technology. Also, Iodine-Sulfur (IS) thermochemical water decomposition is one of the promising processes that can produce hydrogen efficiently using the high temperature gas-cooled reactor (HTGR) as an energy source capable of supplying heat at over 1000. In this study, to effect an initiating events identification of the IS process, Master Logic Diagram (MLD) was used and 9 initiating events that cause a leakage of the chemical material were identified.

Stochastic finite element analysis of plate structures by weighted integral method

  • Choi, Chang-Koon;Noh, Hyuk-Chun
    • Structural Engineering and Mechanics
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    • 제4권6호
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    • pp.703-715
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    • 1996
  • In stochastic analysis, the randomness of the structural parameters is taken into consideration and the response variability is obtained in addition to the conventional (mean) response. In the present paper the structural response variability of plate structure is calculated using the weighted integral method and is compared with the results obtained by different methods. The stochastic field is assumed to be normally distributed and to have the homogeneity. The decomposition of strain-displacement matrix enabled us to extend the formulation to the stochastic analysis with the quadratic elements in the weighted integral method. A new auto-correlation function is derived considering the uncertainty of plate thickness. The results obtained in the numerical examples by two different methods, i.e., weighted integral method and Monte Carlo simulation, are in a close agreement. In the case of the variable plate thickness, the obtained results are in good agreement with those of Lawrence and Monte Carlo simulation.

Viscoelastic behavior on composite beam using nonlinear creep model

  • Jung, Sung-Yeop;Kim, Nam-Il;Shin, Dong Ku
    • Steel and Composite Structures
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    • 제7권5호
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    • pp.355-376
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    • 2007
  • The purpose of this study is to predict and investigate the time-dependent creep behavior of composite materials. For this, firstly the evaluation method for the modulus of elasticity of whole fiber and matrix is presented from the limited information on fiber volume fraction using the singular value decomposition method. Then, the effects of fiber volume fraction on modulus of elasticity of GFRP are verified. Also, as a creep model, the nonlinear curve fitting method based on the Marquardt algorithm is proposed. Using the existing Findley's power creep model and the proposed creep model, the effect of fiber volume fraction on the nonlinear creep behavior of composite materials is verified. Then, for the time-dependent analysis of a composite material subjected to uniaxial tension and simple shear loadings, a user-provided subroutine UMAT is developed to run within ABAQUS. Finally, the creep behavior of center loaded beam structure is investigated using the Hermitian beam elements with shear deformation effect and with time-dependent elastic and shear moduli.

자성 폴리스티렌-폴리이미드 Core-Shell 마이크로스피어의 합성 (Synthesis of Magnetic Polystyrene-Polyimide Core-Shell Microsphere)

  • 안병현
    • Elastomers and Composites
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    • 제47권2호
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    • pp.168-173
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    • 2012
  • 폴리아미드산을 안정제로 사용한 스티렌의 분산중합에 의해 core-shell 구조를 갖는 폴리스티렌-폴리이미드 core-shell 마이크로스피어를 얻었다. Iron pentacarbonyl을 마이크로스피어에 함침시킨 후 열분해하여 산화철 나노 입자를 갖는 자성 폴리스티렌-폴리이미드 마이크로스피어를 제조하였다. 자성 폴리스티렌-폴리이미드 마이크로스피어의 크기와 구조, 열적 특성 및 자성 특성을 조사하였는데, 자성 폴리스티렌-폴리이미드 마이크로스피어는 크기가 약 500 nm 정도로 균일하였으며 40%의 산화철 나노 입자를 가졌다. 산화철은 X선 회절시험에 의해 $Fe_3O_4$임이 확인되었다.