• Title/Summary/Keyword: Material Decomposition

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Synthesis of Non-hydrate Iron Oleate for Eco-friendly Production of Monodispersed Iron Oxide Nanoparticles

  • Kim, Do Kyung;Lee, Jae Won
    • Journal of the Korean Ceramic Society
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    • v.55 no.6
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    • pp.625-634
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    • 2018
  • In this work, we describe a novel and simple technique to produce non-hydrate surfactant complexes for the formation of highly crystalline fatty acid modified SPIONs by thermolysis of iron oleate (FeOl) complexes in a non-coordinating solvent. FeOl complexes were prepared by direct coordination of iron ions and carboxylic acid; thus, we could control the stoichiometric composition of the precursor by changing the molar ratio of fatty acid and metal ions. The discrete thermal behaviors and chemical coordination of the intermediate non-hydrated FeOl were studied by thermo-analytic techniques including differential scanning calorimetry, thermal gravimetric analysis, and Fourier transform infrared spectroscopy.

3-Dimensional Nonlinear Analysis of Low Velocity Impact On Composite Plates (복합재료 평판의 비선형 3차원 저속 충격 해석)

  • 김승조;지국현
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.38-42
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    • 2000
  • In this study, the low velocity impact behavior of the composite laminates has been described by using 3 dimensional nonlinear finite elements. To describe the geometric nonlinearity due to large deformation, the dynamic contact problem is formulated using the exterior penalty finite element method on the base of Total Lagrangian formulation. The incremental decomposition is introduced, and the converged solution is attained by Newton-Raphson Method. The Newmark's constant-acceleration time integration algorithm is used. To make verification of the finite element program developed in this study, the solution of the nonlinear static problem with occurrence of large deformation is compared with ABAQUS, and the solution of the static contact problem with indentation is compared with the Hertz solution. And, the solution of low velocity impact problem for isotropic material is verificated by comparison with that of LS-DYNA3D. Finally the contact force of impact response from the nonlinear analysis are compared with those from the linear analysis.

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OMVPE and Plasma-Assisted Doping of ZnSe with Dimethlzinc:triethylamine Adduct Source

  • Huh, Jeung-Soo;Lim, Jeong-Ok
    • Journal of Sensor Science and Technology
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    • v.5 no.2
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    • pp.55-60
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    • 1996
  • The growth and microwave plasma assisted nitrogen doping of ZnSe by low pressure organometallic vapor phase epitaxy(OMVPE) has been investigated in a vertical downflow reactor equipped with a laser interferometer for in-situ growth rate measurements. Particular emphasis is placed on understanding growth characteristics of $H_{2}Se$ and the new adduct source dimethylzinc:triethyllamine($DMZn:NEt_{3}$) as compared with those obtained with $H_{2}Se$ and DMZn. At lower temperatures ($<300^{\circ}C$) and pressures(<30Torr), growth rates are higher with the adduct source and the surface morphology is improved relative to films synthesized with DMZn. Hall measurements and photoluminescence spectra of the grown films demonstrate that DMZn and $DMZn:NEt_{3}$ produce material with comparable electronic and optical properties. Microwave plasma decomposition of ammonia is investigated as a possible approach to increasing nitrogen incorporation in ZnSe and photoluminescence spectra are compared to those realized with conventional ammonia doping.

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Hydrogen Storage Properties of Carbon Nanotube Composites (탄소나노튜브 복합재의 수소저장특성)

  • Ahn, Jung-Ho;Jang, Min-Kyu
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.188-195
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    • 2008
  • Carbon nanotube (CNT)/$Mg_2Ni$ composites were synthesized to enhance the hydrogen storage properties. The emphasis was made on the effect of different shortening methods of CNTs on the open-tip structure and the resulting properties. The use of open CNTs as a starting material resulted in an enhanced hydrogen properties of CNT/$Mg_2Ni$ composites. Among the employed methods for the shortening of CNTs, wet milling using ethanol was the most efficient, while ultrasonic acid treatment or thermal decomposition resulted in a less hydrogen storage capacity.

Utilization of Deodorized Poultry Feces with Tolura sp. CH-30

  • Choi, Moo-Young;Lee, Eun
    • Journal of Microbiology and Biotechnology
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    • v.2 no.4
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    • pp.273-277
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    • 1992
  • Treatment of poultry feces with Tolura sp. CH-30 produced a material that was significantly deodorized and showed a promotive effect on plant growth. Tolura sp. CH-30 grew on the poultry feces, deodorizing the feces by assimilation of volatile fatty acids, which are the source of the offensive odor, as a carbon source. Significant degradation of uric acid also occurred. In the treatment of feces with Tolura sp. CH-30, it was possible to deodorize feces in a short time, but reduction in the amount of urate-N was not enough. Urate-N inhibited plant growth due to an excessive nitrogen content produced as a result of rapid decomposition. Therefore, we propose a recycle-treatment plan using poultry feces treated with Tolura sp. CH-30. After the recycle-treatment, the amount of urate-N contained in the recycle-treated poultry feces was small and the recycle-treated poultry feces showed a promotive effect on plant growth when it was added at a nitrogen content of 1.6 g/600 g soil/pot.

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Coupled Analysis of Structure and Surface Ablation in Solid Rocket Nozzle (삭마반응을 고려한 고체 추진기관 노즐 조립체의 열반응 및 구조해석)

  • Kim, Yun-Chul;Doh, Young-Dae;Hahm, Hee-Cheol;Moon, Soon-Il
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.565-569
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    • 2011
  • A two-dimensional thermal response and ablation analysis code for predicting charring material ablation and shape change on solid rocket nozzle is presented. For closing the problem of thermo-structural analysis, Arrhenius' equation and Zvyagin's ablation model are used. The moving boundary problem are solved by remeshing-rezoning method. For simulation of complicated thermal protection systems, this method is integrated with a three-dimensional finite-element thermal and structure analysis code.

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Image Restoration in Dual Energy Digital Radiography using Wiener Filtering Method

  • Min, Byoung-Goo;Park, Kwang-Suk
    • Journal of Biomedical Engineering Research
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    • v.8 no.2
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    • pp.171-176
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    • 1987
  • Wiener filtering method was applied to the dual energy imaging procedure in digital radiography(D.R.). A linear scanning photodiode arrays with 1024 elements(0.6mm H 1.3mm pixel size) were used to obtain chest images in 0.7 sec. For high energy image acquisition, X-ray tube was set at 140KVp, 100mA with a rare-earth phosphor screen. Low energy image was obtained with X-ray tube setting at 70KVp, 150mA. These measured dual energy images are represented in the vector matrix notation as a linear discrete model including the additive random noise. Then, the object images are restored in the minimum mean square error sense using Wiener filtering method in the transformed domain. These restored high and low energy images are used for computation of the basis image decomposition. Then the basis images are linearly combined to produce bone or tissue selective images. Using this process, we could improve the signal to noise ratio characteristics in the material selective images.

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Preparation of Spherical Gadolinium Compound Particles (구형 가돌리늄화합물 입자 제조)

  • 김응호;최청송;정경채;박진호;장인순
    • Journal of the Korean Ceramic Society
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    • v.30 no.7
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    • pp.563-570
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    • 1993
  • Spherical, monosized gadolinium compound was prepared by the reaction of Gd(NO3)3 solution with decomposition products of urea in the solution at evaluated temperature. Chemical composition and calcination characteristics of spherical gadolinium compound prepared were investigated by X-ray IR and TG-DTA. The approximate chemical composition of the spherical particle precipitated was Gd(OH)CO3.1.5H2O. Gd(OH)CO3.1.5H2O was calcined to monoclinic type Gd2O3 at 115$0^{\circ}C$ via cubic type Gd2O3 near $600^{\circ}C$. The effects of various parameters such as pH, temperature, concentration ratio of urea to gadolinium precusor, ageing time, and others material (CCl3COOH and HOCNH2) in stead of urea as precipitating agent on the properties of the resulting precipitates were studied systematically.

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Gas Detector for Hydrogen Dissolved in Transformer Oil

  • Seo Ho-Joon;Hwang Kyu-Hyun;Rhie Dong-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.2
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    • pp.72-75
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    • 2005
  • In oil-filled equipment such as transformers, partial discharge or local overheating will precede a final shutdown. Accompanied with such problems is a decomposition of insulating material into gases, which are dissolved into the transformer oil. The gases dissolved in oil can be separated with some membranes based on the differences in permeability of membranes to different gases. This paper discuss the permeability characteristics of several membranes for separation hydrogen gas in oil. With result of this paper, it may become possible to detect fault-related gases from transformer oil and predict incipient failures in the

Association between coarse woody debris and small mammals and insectivores in managed forests

  • Lee, Sang-Don
    • Journal of Ecology and Environment
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    • v.35 no.3
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    • pp.189-194
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    • 2012
  • Coarse woody debris (CWD) is generally considered dead woody material in various stages of forest decomposition and has been hypothesized to be an important habitat feature for mammals in forests of the Pacific Northwest, USA. Sherman and pitfall trapping were conducted for 2 years on three paired sites with low and high amounts of CWD. Deer mice was the dominant species with a total capture of 605 (45.6%). Four species of insectivores were captured, including Sorex moncicolus, S. trowbridgii, S. vagrans, and Neurotrichus gibbsii. A Poisson regression model was used to test whether 11 CWD variables could predict insectivore captures. The volume of logs and mean decay were important variables for deer mice use of CWD. Mean distance from pieces of CWD to the capture point was significantly related to the total number of captures of trowbridge shrew (Sorex trowbridgii) and all insectivore species. Vagrant shrews (Sorex vagrans) were significantly associated with log volume. Retaining large size CWD should be part of a management plan for ground-dwelling insectivores in forests to secure their biodiversity.