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http://dx.doi.org/10.4191/kcers.2018.55.6.07

Synthesis of Non-hydrate Iron Oleate for Eco-friendly Production of Monodispersed Iron Oxide Nanoparticles  

Kim, Do Kyung (Department of Anatomy, College of Medicine, Konyang University)
Lee, Jae Won (Department of Material Science and Engineering, College of Aviation, Jungwon University)
Publication Information
Journal of the Korean Ceramic Society / v.55, no.6, 2018 , pp. 625-634 More about this Journal
Abstract
In this work, we describe a novel and simple technique to produce non-hydrate surfactant complexes for the formation of highly crystalline fatty acid modified SPIONs by thermolysis of iron oleate (FeOl) complexes in a non-coordinating solvent. FeOl complexes were prepared by direct coordination of iron ions and carboxylic acid; thus, we could control the stoichiometric composition of the precursor by changing the molar ratio of fatty acid and metal ions. The discrete thermal behaviors and chemical coordination of the intermediate non-hydrated FeOl were studied by thermo-analytic techniques including differential scanning calorimetry, thermal gravimetric analysis, and Fourier transform infrared spectroscopy.
Keywords
Oleic acid; Iron oxide; Nanoparticles; Thermal decomposition; Superparamagnetic;
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