• 제목/요약/키워드: Mass standards

검색결과 465건 처리시간 0.027초

식품용 폴리카보네이트 기구류 중 ICP-MS를 이용한 중금속 이행량 조사 (A Study on the Migration of Heavy Metals from Polycarbonate Food Contact Materials Using an Inductively Coupled Plasma Mass Spectrometry (ICP-MS))

  • 박세종;박소라;김미경;최재천
    • 한국포장학회지
    • /
    • 제24권3호
    • /
    • pp.107-112
    • /
    • 2018
  • 납, 카드뮴 및 비소의 폴리카보네이트 기구류에서 식품으로의 이행 수준을 ICP-MS로 조사하였다. 분석법을 확립 및 검증(검량선, 검출한계, 정량한계, 회수율, 정밀성 및 측정불확도)하고 식품모사용매(4% 초산)로 용출시켜 이행량을 분석하였다. 폴리카보네이트 재질 기구인 컵 63종, 용기 62종, 물병 55종, 스푼 9종, 국자 6종 및 집게 5종으로 총 200종의 시료를 $70^{\circ}C$$100^{\circ}C$에서 30분간 용출한 결과, 납, 카드뮴 및 비소가 각각 $ND{\sim}4.67{\mu}g/L$, $ND{\sim}0.49{\mu}g/L$$ND{\sim}2.91{\mu}g/L$수준으로 용출되었다. 또한, 온도에 따른 이행량 차이를 관찰한 결과, $70^{\circ}C$보다는 $100^{\circ}C$에서 용출되는 이행량이 다소 높았다. 결론적으로 현재 국내에 유통 중인 폴리카보네이트 기구류 중 납, 카드뮴 및 비소는 식품용 기구 및 용기 포장 공전에 명시된 용출규격 이하로서 안전하게 관리되고 있는 것으로 판단되었다.

연속흐름주입-수소화물생성-유도결합플라스마 질량분석장치를 이용한 바닷물표준시료중의 극미량 비소분석방법의 확립 (Determination of trace arsenic in seawater by flow injection-hydride generation inductively coupled plasma mass spectrometry)

  • 서정기
    • 분석과학
    • /
    • 제21권4호
    • /
    • pp.316-325
    • /
    • 2008
  • 연속흐름주입-수소화물생성-유도결합플라스마질량분석장치를 사용하여 바닷물시료중의 비소를 분석하였다. 두 종류의 바닷물표준시료인 CASS-4, NASS-5를 사용하여 측정값과 인증값을 비교함으로써 본 분석법의 정확성을 확인하였다. 분석결과 CASS-4의 경우 $1.17{\pm}0.07{\mu}g/L$ (인증값 $1.11{\pm}0.16{\mu}g/L$), NASS-5의 경우 $1.24{\pm}0.08{\mu}g/L$ (인증값 $1.27{\pm}0.12{\mu}g/L$)의 값을 얻었다. 이는 각각 독립적으로 5회 측정된 결과의 확장불확도로 표시된 결과이며 CASS-4의 경우 6.2%, NASS-5의 경우 6.8%이었으며 모두 인증값의 불확도 범위안에 있었다. 검량선의 기울기와 바탕값의 표준편차로부터 구한 $As^+$ (m/z=74.9216)의 검출한계는 0.01 ug/kg이었다. 검량선의 직선성은 매우 양호하였다. ($R^2=1$). DRC gas로 산소기체를 사용하여 $AsO^+$ (m/z=90.9165)로 검출하는 방법을 사용하여 결과를 비교하였으며 분석감도는 약 25배 정도 감소하였으나, 검량선의 직선성이 매우 잘 나타났으며, 분석결과도 $As^+$(m/z=74.9216)로 검출할 때와 동일한 결과를 얻을 수 있었다.

유통 어린이 화장품 세트의 중금속 함량에 관한 분석 (Analysis of Heavy Metals Content in Distributed Children's Cosmetic Set)

  • 이인숙;김연지;김꽃봉우리;구평태
    • 대한화장품학회지
    • /
    • 제50권1호
    • /
    • pp.77-84
    • /
    • 2024
  • 사용 연령이 만 4 세 이상부터 표시된 어린이 화장품세트 4 건을 온라인으로 구매하였으며 각 구성품 81 건을 대상으로 납, 카드뮴, 비소, 안티몬, 니켈, 코발트, 구리, 크롬 및 수은의 함량을 inductive coupled plasma-mass spectrometry (ICP - MS)로 분석하였다. 어린이 화장품의 중금속 평균값은 납 0.82 ㎍/g, 카드뮴 0.03 ㎍/g, 비소 0.97 ㎍/g, 안티몬 0.52 ㎍/g, 니켈 2.32 ㎍/g, 수은 0.01 ㎍/g으로 모든 제품에서 허용 기준보다 낮았다. 국산과 수입산의 비교 결과, 국산보다는 수입산에서 납, 안티몬, 코발트, 구리의 평균값이 높게 검출되었다(p < 0.05). 화장품 유형에 따른 중금속 평균값은 통계적으로 유의한 차이를 보였는데(p < 0.05) 아이새도에서 비소 2.47 ㎍/g, 니켈 6.36 ㎍/g, 크롬 11.06 ㎍/g으로 평균값이 가장 높게 나왔으며, 볼연지에서 납 1.20 ㎍/g, 안티몬 1.17 ㎍/g, 구리 23.60 ㎍/g으로 가장 높게 나왔다. 분석된 81 건의 어린이 화장품에 대한 코발트의 검출 수준은 불검출 ~ 5.23 ㎍/g, 구리는 불검출 ~ 379.61 ㎍/g, 크롬은 불검출 ~ 36.95 ㎍/g이었다. 브라운 색상의 화장품은 니켈과 코발트에서 평균값이 높게 검출되었으며, 퍼플 색상은 납과 크롬에서 높게 검출되었다.

중학생의 성교육 실태 및 프로그램 효과분석 (Condition and Effect of Sex Education Program for Korean Middle School Students)

  • 문인옥;윤영옥;김노을
    • 한국학교ㆍ지역보건교육학회지
    • /
    • 제8권1호
    • /
    • pp.1-11
    • /
    • 2007
  • Objectives: School must provide the proper sex education to students, thereby, the students for have right standards of sexuality and preventing from sexual crimes. This study conducted to identify the effectiveness and students' satisfaction level on Sex education program for middle school students prepared by the Ministry of Education and Human Resources. Methods: The sample size of the study was 644 students(458 female students and 186 male students) in middle school. A self reporting type of questionnaire survey was conducted from May 2 through May 27, 2005. Collected data were processed using SPSSwin 12.0; The data were analysed through t-test, stepwise multiple regression analysis. Results: Lectures and audiovisual materials were mostly used for sex education for students. Many students were satisfied with the program of physical and sexual organ development, pregnancy, contraceptive methods and sexual abuse. Many students wanted to study more on courtship, love, and marriage. The programs which the students did not understand well were sexually transmitted diseases, pregnancy and mass media and sex. Forty six percentage of the students reported that they were satisfied with the education program. Thirty three percentage of the students said that they were not satisfied with the program. The students who had earlier menstruation experience and the students whose academic achievement were higher were more satisfied with sex education program (P<.05). The students who were satisfied with the sex education CD prepared by the ministry of education were more satisfied with sex education program. (P<.001). When the CDs were appropriately used, the students were more satisfied with the education program (P<.05). The sound and pictures in the CD did not much affect the students. Audiovisual programs were more effective than lectures.

  • PDF

전북지역 영유아 보육시설의 급식관리 실태평가 (Assessment of Foodservice Management Practices in the Educare Centers in Jeonbuk Province)

  • 이영은;김향숙
    • 한국생활과학회지
    • /
    • 제7권1호
    • /
    • pp.217-233
    • /
    • 1998
  • Foodservice management practices in 52 educare centers in Jeonbuk province were evaluated in order to provide basic informations and guidelines for the standardization of foodservice management and facilities in the educare centers. The survey was conducted using the structured questionnaire. The results are summarized as follows: 1. Only 10% of the centers investigated had the stationed dietitian, therefore most of foodservice management was not conducted by a professional personnel. The average number of kitchen employees was 1.3 and significantly different with type(p<0.05) and size(p<0.001) of the centers, which was not enough to meet the regulation. 2. Menu planning was performed mostly(59.6%) by managers and teachers of educare centers. Food items were purchased(94.7%) and recieved(91.6%) by kitchen employees or center managers and teachers. Produced foods were also evaluated(97.7%) and distributed(100%) by kitchen employees or center managers and teachers depending on their experience without any supervision of the professional personnel for the mass production. 3. Among the centers studied, 84.6% of them conducted nutrition education programs regularly by teachers. About 77.3% of them evaluated that these programs did not accomplish the proper training for good food habit because of the lack of nutritional knowledge(54.5%) and educational media(27.3%). 4. In general, the hygienic maintenance was evaluated as fair state to need the improvement. 5. Kitchen facilities and equipments were similar to those of home cooking and did not meet the standards for institutional practices. Besides, automated machinery and tools for safety, sanitation and improvement of work efficiency were far short. 6. Log book for the foodservice management was not prepared properly, which made the systematic planning and operation of the foodservice facilities difficult.

  • PDF

Development of Analytical Method and Monitoring of Veterinary Drug Residues in Korean Animal Products

  • Song, Jae-Sang;Park, Su-Jeong;Choi, Jung-Yun;Kim, Jin-Sook;Kang, Myung-Hee;Choi, Bo-Kyung;Hur, Sun Jin
    • 한국축산식품학회지
    • /
    • 제36권3호
    • /
    • pp.319-325
    • /
    • 2016
  • This study was conducted to determine the residual amount of veterinary drugs such as meloxicam, flunixin, and tulathromycin in animal products (beef, pork, horsemeat, and milk). Veterinary drugs have been widely used in the rearing of livestock to prevent and treat diseases. A total of 152 samples were purchased from markets located in major Korean cities (Seoul, Busan, Incheon, Daegu, Daejeon, Gwangju, Ulsan and Jeju), including Jeju. Veterinary drugs were analyzed by liquid chromatography-tandem mass spectrometry according to the Korean Food Standards Code. The resulting data, which are located within 70-120% of recovery range and less than 20% of relative standard deviations, are in compliance with the criteria of CODEX. A total of five veterinary drugs were detected in 152 samples, giving a detection rate of approximately 3.3%; and no food source violated the guideline values. Our result indicated that most of the veterinary drug residues in animal products were below the maximum residue limits specified in Korea.

성충동약물치료 시행에 따른 소변 중 남성호르몬의 분석법 확립 (Validation of Analytical Method for Male Sex Hormone Monitoring in Urine due to the Chemical Castration)

  • 정수진;백승경;박선혜;손꽃잎;박용훈;이상기
    • 약학회지
    • /
    • 제57권5호
    • /
    • pp.330-336
    • /
    • 2013
  • "The Act on Medication Treatment of Sexual Impulse of Sex Offenders" known as chemical castration has been effective since July 2011 in Korea. According to the law, monitoring of male sex hormone in urine is enforced to request National Forensic Service more than once a month after injection of medicine designed to reduce sex impulse. We established a rapid and sensitive method for the monitoring of testosterone (T) and epitestosterone (E) in human urine by liquid chromatography with tandem mass spectrometry (LC-MS/MS). Three mL of urine was pretreated by solid-phase extraction for purification and performed enzymatic hydrolysis. The pretreated samples were extracted twice with 2 ml of ethyl acetate and n-hexane (2 : 3). The separation was applied on Thermo Hypersil GOLD C18 column ($1.9{\mu}m$, $100{\times}2.1mm$). A gradient elution of methanol and water of 0.1% formic acid were used as mobile phase and the retention time was less than 10 min. LC-MS/MS system coupled with an electrospray ionization source was performed in multiple reaction monitoring mode. The transitions of the analytes executed as following: m/z $289{\rightarrow}97$, 109 for T and E, m/z $292{\rightarrow}109$ for $T-d_3$ and $E-d_3$ as internal standards. The validation results of the method were satisfactory. The limits of detection were 0.05 ng/ml and the limits of quantification were 0.1 ng/ml. This method was successfully applied to real human urine sample. The developed method will be useful for monitoring T/E ratio in urine of sex offenders.

Effect of Moisture Content of Sawdust and Length to Diameter Ratio of a Hole in Flat-die Pelletizer on The Fuel Characteristics of Wood Pellets Produced with Quercus mongolica, Pinus densiflora, Pinus rigida and Larix kaempferi

  • Yang, In;Kim, Seong-ho;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
    • /
    • 제45권4호
    • /
    • pp.382-398
    • /
    • 2017
  • This study was conducted to identify the potential of Quercus mongolica (QUM), Pinus densiflora (PID) and Pinus rigida (PIR) as a raw material for pellet production. Larix kaempferi (LAK), which has mostly been used for pellet production in Korea, was also used as a control. All specimens contained very minimal amounts of sulfur and chlorine. Ash content of LAK was the lowest, followed by PID, PIR and QUM. For the size distribution, the mass fraction between 0.42 mm and 0.25 mm was the highest in PIR. Most fuel characteristics of the produced wood pellets improved with the use of 12% moisture content (MC) particles and the increase of the ratio of length to diameter of a hole in flat-die (L/D ratio). When the MC, bulk density and durability of QUM, PID, PIR and LAK pellets was compared with the standards of the KFRI and ISO, the use of wood particles of 12% MC and flat-die with an L/D ratio of 5.00 for PID particles are suitable for high-quality pellets in the aspects of all fuel characteristics. For PIR and QUM, further work is needed to seek the optimum conditions for the production of high-quality and durable pellets.

고령인구 비율이 높은 지역 장년, 노년층의 건강.영양상태 및 이에 영향을 미치는 인자에 관한 연구 I. 신체계측, 생화학적 영양상태 (혈청지질, 철분지표, 무기질 등) (Nutritional Status and Related Factors of Residents Aged Over 50 in Longevity AreasI. Anthropometric and Biochemical Nutritional Status)

  • 최정숙;백희영;권성옥
    • Journal of Nutrition and Health
    • /
    • 제37권9호
    • /
    • pp.825-837
    • /
    • 2004
  • Studies on the health problems of the elderly have been increased with increasing life expectancy of Koreans. To assess the health status of people over 50 years old including the elderly (678 free-living people: men (168), women (510)), anthropometric measurements and biochemical nutritional status were analyzed. General characteristics and the prevalences of specific diseases were also examined. The mean anthropometric values for males and females were heights of 162 cm and 149 cm, respectively; and weights of 59 kg and 52 kg, respectively, which were much lower than the Korean standards established in the Korean Recommended Dietary Allowances. The mean BMI, WHR (waist hip ratio), and body fat rate (%), which are obesity indices, were significantly higher in females than in males. As the age went up, height, weight, lean body mass, and mid-arm circumference decreased. Whereas, blood pressure (SBP) for women increased. Mean blood HDL-cholesterol levels of men and women were 46.0 mg/dl and 46.3 mg/dl, respectively; their triglyceride levels were 129.1 mg/d1 and 135.6 mg/dl, respectively, which were not significantly different. Total cholesterol and LDL-cholesterol levels were significantly higher in females than in males. For man there were significantly different in ${\gamma}$-GTP, Na levels by age. As the age went up for women, RBC, hemoglobin, hematocrit, HDL-cholesterol, ${\gamma}$-GTP and $Ca^{2+}$ levels significantly decreased. Levels of total protein and albumin were above the lower normal limit for the majority of the participants. Prevalence of anemia, assessed by hemoglobin using World Health Organization (WHO) definition, was 43.9% for men and 42.1% for women. Also, many of the subjects were out of the normal range in total cholesterol (women), HDL-cholesterol, TAS (total antioxidant status), APase, RBC, hemoglobin, hematocrit levels. Therefore, measures to improve the biochemical nutritional status for the people in rural area are required.d.

노인에게 발생하는 안전사고에 관한 연구 (A Study on Accidents for the Aged)

  • 박상섭
    • 한국응급구조학회지
    • /
    • 제10권1호
    • /
    • pp.41-49
    • /
    • 2006
  • Purpose: It can be said that the aged belong to the group vulnerable to safety accidents. The purpose of this study was to investigate safety accidents to old people and provide basic data to prevent them from being in a safety accident. Result : 1. The number of the aged of traffic accident fatalities per 100,000 persons was 57.8, which was significantly higher than other OECD countries. 2. trauma for the aged, falling accounted for 60.6%, which was relatively higher than other wounds, probably because of decreased capacity of movement and reduced faculty of sensation. 3. accidents to the aged at home, 43.9% occurred in a room, which shows great risk of safety accidents to the aged in a room. 4. the aged generally showed negative awareness of social safety. Suggestion : 1. it is necessary to provide regular education about accidents through the mass media and at social welfare facilities in order for aged people to consolidate safety consciousness repeatedly. 2. it is necessary to make a brief and clear guide to prevention of accidents. 3. the Ministry of Construction and Transportation and the Ministry of Health and Welfare should give priority to designing a building for aged people and authorize construction according to the standards for establishing safety facilities for the aged. 4. it is necessary to change social consciousness. since transportation accidents can be caused not by aged people's insufficient safety consciousness but by that of all the people, it is necessary to provide society-wide education programs against dangerous driving in order to guarantee aged people's safety. 5. legal procedure to secure aged people's safety should be strengthened to reinforce legal protection for them.

  • PDF