Browse > Article
http://dx.doi.org/10.5806/AST.2008.21.4.316

Determination of trace arsenic in seawater by flow injection-hydride generation inductively coupled plasma mass spectrometry  

Suh, Jung-Ki (Division of Metrology for Quality Life, Korea Research Institute of Standards and Science)
Publication Information
Analytical Science and Technology / v.21, no.4, 2008 , pp. 316-325 More about this Journal
Abstract
An inductively coupled plasma mass spectrometry (ICP-MS) instrument equipped with flow injection-hydride generation system was used for the determination of trace arsenic in seawater sample. The accuracy in this method was verified by the analysis of certified reference materials (CRM) of seawater (CASS-4, NASS-5). The analytical results agreed with certified value within the range of uncertainty. The expanded uncertainties for CASS-4 and NASS-5 in this experiment were ranged from 6.2% to 6.8% obtained from repeated analyses of the CRMs (n=5). The detection limit of $As^+$ (m/z=74.9216) in this method was confirmed about 0.01 ug/kg. Linearity obtained from calibration curve of arsenic was excellent ($R^2=1$). The detection at $As^+$ (m/z=74.9216) and $AsO^+$ (m/z=90.9165) by using oxygen reaction gas in DRC mode was compared. Sensitivity at $AsO^+$ (m/z=90.9165) was decreased about 25-fold, but the analytical results are the same that at $As^+$ (m/z=74.9216).
Keywords
ICP-MS; Flow Injection; Hydride Generation; Arsenic; CASS-4; NASS-5 reference material;
Citations & Related Records
연도 인용수 순위
  • Reference
1 W. R. Cullen and K. J. Reimer, Chem Rev 89, 713- 764(1989)   DOI
2 K. A. Francesconi and J. S. Edmonds, Adv. Inorg. Chem., 44, 147-189(1997)   DOI
3 D. Chakraborti, W. De Jonghe and F. Adams, Anal. Chim. Acta, 119, 331-340(1980)   DOI   ScienceOn
4 S. Nakashima, Fresenius', J. Anal. Chem., 341, 570-571 (1991)   DOI
5 J. Moreda-Pineiro, M. L. Cervera and M. de La Guardia, J. Anal. At. Spectrom., 12, 1377-1380(1997)   DOI   ScienceOn
6 D. C. Gregoire, Appl. Spectrosc., 41, 897(1987)   DOI   ScienceOn
7 H. Falk, R. Geerling, B. Hattendorf, K. Krengel-Rothensee and K. P. Schmidt, Fresenius J. Anal. Chem., 359(4-5), 352-356(1997)   DOI
8 J. W. McLaren, K. W. M. Sie, J. W. Lam, S. N. Willie, P. S. Maxwell, A. Palepu, M. Koether and S. S. Berman., Fresenius J. Anal. Chem., 337(6), 721-728(1990)   DOI
9 I. Vladimir, Scott Baranov and D. Tanner, J. Anal. At, Spectrom., 14(8), 1133-1142(1999)   DOI   ScienceOn
10 Sergei F. Boulyga, Hans-joachim Dietze and J. Sabine becker, Mikrochim. Acta, 137, 93-103(2001)   DOI   ScienceOn
11 A. G. Howard and S. D. W. Comber, Microchim. Acta, 109, 27-33(1992)   DOI
12 X.-P. Yan, X.-B. Yin, X.-W. He and Y. Jiang, Anal. Chem., 74, 2162-2166(2002)   DOI   ScienceOn
13 J. Jens, Eric Sloth and H. Lasen, J. Anal. At, Spectrom., 15(6), 669-672(2000)   DOI   ScienceOn
14 D. Scott Tanner, I. Vladimir Baranov and Uwe Vollkopf, J. Anal. At, Spectrom., 15(9), 1261-1269(2000)   DOI   ScienceOn
15 D. R. Bandura, V. I, Baranov, S. D. Tanner, Fresenius J. Anal. Chem., 370, 454-470, (2001)   DOI
16 I. Feldmann, N. Jakubowski and D. Stuewer, Fresenius J. Anal. Chem., 365, 415-421(1999)   DOI
17 S. Karthikeyan, T. Prasada Rao and C. S. P. Iyer, Talanta, 49, 523-530(1999)   DOI   ScienceOn
18 Committee on medical and biologic effects on environmental pollutants, Medical and Biological Effects of Environmental Pollutants, copyright 1977, the National Academy of Sciences, all rights reserved, 1977
19 S. Sri Juari, M. Hiroshige and T. Shigeru., J. Anal. At. Spectrom., 12(4), 409-415(1997)   DOI   ScienceOn
20 C. Chih-Shyue and J. Shiuh-Jen, Spectrochim. Acta, Part B, 51B(14), 1813-1821(1996)
21 K. A. Francesconi and J. S. Edmonds, Oceanogr. Mar. Biol. Annu. Rev., 31, 111-151(1993)
22 B. Welz and M. Sperling, Atomic Absorption Spectrometry, Wiley-VCH, Weinheim, pp. 672, 1675(1999)
23 J. W. McLaren, D. Beauchemin and S. S. Berman, Anal. Chem., 59, 610(1987)   DOI
24 L. Ebdon, L. Pitts and R. Cornelis 'Trace Element Speciation for Environment' Food and Health, ed. Royal Society of Chemistry, Cambridge, UK, 2002
25 L. Zhang, Y. Morita, A. Sakuragawa and A. Isozaki, Talanta, 72, 723-729(2007)   DOI   ScienceOn
26 M. R. Jekel, Removal of arsenic in drinking water treatment. In: Nriagu J.O. (Ed.) Arsenic in the Environment Part 1: Cycling and Characterization. Advances in Environmental Science and Technology, 26, John Wiley & Sons, New York, 1994
27 A. M. Featherstone, E. C. V. Butler, B. V. O'Grady and P. Michel, J. Anal. At. Spectrom., 13, 1355-1360(1998)   DOI   ScienceOn
28 J. A. Olivares and R. S. Houk, Anal. Chem., 58, 20(1986)   DOI
29 M. Grotti and R. Frache, J. Anal. At. Spectrom., 22, 1481-1487(2007)   DOI   ScienceOn
30 S. J. Santosa, H. Mokudai and S. Tanaka, J. Anal. At. Spectrom., 12, 409-415(1997)   DOI   ScienceOn
31 M. O. Andreae, Anal. Chem., 49, 820-823(1977)   DOI   ScienceOn
32 T. Kubota, T. Yamaguchi and T. Okutani, Talanta, 46, 1311-1319(1998)   DOI   ScienceOn
33 J. T. Creed, M. L. Magnuson, C. A. Brockhoff, I. Chamberlain and M. Sivaganesan, J. Anal. At. Spectrom., 11, 505-509(1996)   DOI
34 L. Romeo, P. Apostoli, M. Kovacic, S. Martini and F. Brugnone, Am J Int Med, 32, 211-6(1997)   DOI   ScienceOn
35 A. Stroh and U. Vo' llkopf, J. Anal. At. Spectrom., 8, 35-40(1993)   DOI
36 J. Goossens, L. Moens and R. Dams., J. Anal. At. Spectrom., 8(6), 921-926(1993)   DOI
37 H. E. Tayor, "Inductively Coupled Plasma Mass Spectrometry, Practices and Techniques", Chapter 10, p 152, Copyright 2001 Academic Press, USA, 2001
38 J. O. Nriagu, 'Arsenic in the Environment', Part II: Human Health and Ecosystem Effects, ed. John Wiley & Sons Inc., New York, 1994
39 K. A. Francesconi and M. Sperling, Analyst, 130, 998- 1001 (2005)   DOI   ScienceOn
40 J. Y. Cabon and N. Cabon, Fresenius' J. Anal. Chem., 368, 484-489(2000).   DOI