• Bulletin of the Korean Chemical Society
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• v.17 no.9
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• pp.794-798
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• 1996

Solid solutions of the nonstoichiometric Dy1-xSrxCoO3-y system with the compositions of x=0.00, 0.25, 0.50, 0.75, and 1.00 have been synthesized by the solid state reaction at 1000 ℃ under atmospheric air pressure. The crystallographic structures of the solid solutions are analyzed by the powder X-ray diffraction patterns at room temperature. The analyses assign the compositions of x=0.00 and 0.25 to the orthorhombic system with space group of Pbnm/D2h16, the compositions of x=0.50 and 0.75 to the tetragonal system like a typical SrCoO2.86, and the composition of x=l.00 or SrCoO2.50 to the brownmillerite type system with space group of I**a. The reduced lattice volumes increase with x value due to the larger radius of Sr2+ ion than that of Dy3+ ion. The mole ratio of Co4+ ion to total Co ion with mixed valence state between Co3+ and Co4+ ions at B sites or τ value has been determined by an iodometric titration. All the samples except for the DyCoO3 compound show the mixed valnce state and thus the composition of x=0.50 has the maximum τ value in the system. The oxygen vacancies increasing with x value are randomly distributed over the crystal lattice except for the composition of x=l.00 which have the ordering of the oxygen vacancies. The nonstoichiometric chemical formulas of the Dy1-xSrxCo3+1-τCo4+τO3-(x-τ)/2 system are formulated from the x, τ, and y values. The electrical conductivity in the temperature range of 100 to 900 K increases with τ value linearly because of positive holes of the Co4+ ions in π* band as a conducting carrier. The activation energy of the x=0.50 as Ea=0.17 eV is minimum among other compouds. Broad and high order transition due to the overlap between σ* and π* bands broadened by the thermal activation is observed near 1000 K and shows a low temperature-semiconducting behavior. Magnetic properties following the Currie-Weiss law show the low to high spin transition in the cobaltate perovskite. Especially, the composition of x=0.75 presents weak ferromagnetic behavior due to the Co3+-O2--Co4+ indirect superexchange interaction.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.74-74
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• 2015

최근 홍수의 특성과 피해 양상은 과거와는 다르게 변화하고 있으며, 급격한 도시화로 인하여 기존 하천유역의 저류 능력이 감소하였으며 이러한 한계를 극복하기 위하여 이미 외국에서는 대심도 터널을 활용한 홍수재해 관리방안이 오래전부터 활용되어 왔다. 본 연구에서는 대심도 터널의 유입구, 수직갱, 감세지, 배수터널과 같은 시설물 중 대심도 터널 설계 시 수직 유입구를 통해 유입되는 유량의 에너지를 완화하고 효과적으로 배수 할 수 있도록 중요한 역할을 하는 감세지의 효율적인 깊이 산정을 위하여 수리모형실험을 실시하였으며, 모형은 Froude 상사법칙을 사용하여 원형의 1/18크기로 제작하였다. 본 연구에서 실시한 감세지 모형의 깊이는 0.278 m(원형 5.0 m), 0.417 m(원형 7.5 m)이며, 각 감세지 깊이별 수직 유입구 3개소(저지수직구1, 저지수직구2, 고지수직구) 및 5가지의 유량 CASE에 대하여 감세지 바닥면 압력을 비교?분석 하였다. 수직 유입구 3개소의 설계조건에 따른 감세지 깊이별 바닥면 압력 분포 평가를 실시한 결과 저지수직구1의 감세지 깊이 0.278 m(원형 5.0m)에서는 최대 압력이 4번 지점에서 $0.075kg/cm^2$(원형 1.30 MPa)이 측정 되었으며, 0.417 m(원형 7.5m)에서는 최대 압력이 1번지점에서 $0.089kg/cm^2$(원형 1.54MPa)이 측정되었다. 또한 저지수직구2의 감세지 깊이 0.278 m(원형 5.0 m)에서는 최대 압력이 1번 지점에서 $0.074kg/cm^2$(원형 1.28 MPa)이 측정 되었으며, 0.417 m(원형 7.5 m)에서는 최대 압력이 2번지점에서 $0.088kg/cm^2$(원형 1.52 MPa)이 측정되었다. 고지수직구의 감세지 깊이 0.278 m(원형 5.0 m)에서는 최대 압력이 3번 지점에서 $0.082kg/cm^2$(원형 1.42 MPa)이 측정 되었으며, 0.417 m(원형 7.5 m)에서는 최대 압력이 1번지점에서 $0.092kg/cm^2$(원형 1.59 MPa)이 측정되었다. 본 연구에서 실시한 수리모형실험의 결과 저유량에서 고유량으로 갈수록 최대압력지점은 반시계방향으로 움직이는 것을 알 수 있으며, 이는 수직 유입구의 설계조건에 따른 수직갱에서의 회전수차에 의하여 발생하는 것으로 분석하였다. 따라서 적절한 감세지 깊이 산정을 위해서 대심도터널의 수직 유입구(유입구형태, 수직갱)의 평가가 함께 유기적으로 이루어져야 할 것으로 판단된다.

• Journal of the Korean Society of Propulsion Engineers
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• v.4 no.4
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• pp.50-58
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• 2000

Burning rate of the matrix propellant($r_{sb}$) and burning rate along the metal wire($r_w$) were measured and analyzed for the HTPB/AP/Al propellant embedded with Ag wire($\phi$0.15mm) according to weight % of RDX(0~20%). Variation of burning rate increment ratio($r_w$/$r_{sb}$) and pressure exponent(n) was studied for the nitramine propellant having 10% RDX embedded with three kinds of metal(Ag, Cu, and Ni-Cr) of which diameter range is between 0.1~0.6mm. Maximum burning rate increment ratio of the nitramine propellant embedded with Ag wire($\phi$0.1mm) was 5.94 at $20^{\cire}C$, 1000 psia, 16.4% faster than that of HTPB/AP propellant, it is because that autoignition temperature of the nitramine propellant was higher than that of HTPB/AP propellant. Standard deviation of absolute ($r_{wc}$/$r_{we}$)/$r_{we}$ calculated by using new empiracal equation composed of four dimensionless groups, is 6.11% less than that calculated by using original empirical equation composed of three dimensionless group. The new empiracal equation is derived from Buckingham pi theorem using the parameters such as thermal diffusivity, melting temperature. wire diameter, propellant sample diameter, frame temperature, autoignition temperature and matrix burning rate which influence on $r_w$.

• Food Engineering Progress
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• v.15 no.4
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• pp.398-403
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• 2011

A dielectric barrier discharge plasma (DBDP) treatment system was fabricated and the optimum operating conditions for the plasma generation were determined in order to explore the potential of cold plasma as a non-thermal proessing technology. The microbial inactivation performance of the system was also evaluated against Staphyloocus aureus. The system consisted of power supply, transformer, electrode assembly and sample treatment plate. The input power was 220 V single phase AC and amplified to 10.0-50.0 kV on a transformer. A pulsed sine wave of frequency 10.0-50.0 kHz was introduced to the electrode embedded in ceramic as a dielectric barrier material in order to generate plasma at atmospheric pressure. Higher currents and consequently greater power were required for the plasma generation as the frequencies increased. A homogeneous and stable plasma was generated at currents of 1.0-2.0, and frequencies of 32.0-35.3 kHz. The optimum electrode-gaps for the plasma generation were 1.85 mm without loaded samples. More power was consumed as the electrode-gaps increased. The practically optimum electrode- gap was, however, 2.65 mm when samples were treated on slide-glasses for microbial inactivation. The maximum temperature increase after 10 min treatment was less than 20$^{\circ}C$, indicating no microbial inactivation effect by heat and thereby insuring a non-thermal method. The DBDP inactivation effect against Staphyloocus aureus increased linearly with treatment time up to 5 min, but plateaued afterward. More than 5 log reduction was achieved by 10 min treatment at 1.25 A.

• Journal of Korean Dental Science
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• v.12 no.1
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• pp.13-19
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• 2019

Purpose: The aim of this study was to compare the flexural strength of provisional fixed dental prostheses which was three-dimensional (3D) printed by several build directions. Materials and Methods: A metal jig with two abutment teeth and pontic space in the middle was fabricated. This jig was scanned with a desktop scanner and provisional restoration was designed on dental computer-aided design program. On the preprocessing software, the build angles of the restorations were arranged at $0^{\circ}$, $30^{\circ}$, $45^{\circ}$, $60^{\circ}$, and $90^{\circ}$ and support was added and resultant structure was sliced to a thickness of $100{\mu}m$. Processed restorations were printed with digital light processing type 3D printer using poly methyl meta acrylate-based resin. After washing and post-curing, compressive loading was applied at a speed of 1 mm/min on a metal jig fixed to a universal testing machine. The maximum pressure at which fracture occurred was measured. For the statistical analysis, build direction was set as the independent variable and fracture strength as the dependent variable. One-way analysis of variance and Tukey's post hoc analysis was conducted to compare fracture strength among groups (${\alpha}=0.05$). Result: The mean flexural strength of provisional restoration 3D printed with the build direction of $0^{\circ}$ was $1,053{\pm}168N$; it was $1,183{\pm}188N$ at $30^{\circ}$, $1,178{\pm}81N$ at $45^{\circ}$, $1,166{\pm}133N$ at $60^{\circ}$, and $949{\pm}170N$ at $90^{\circ}$. The group with a build direction of $90^{\circ}$ showed significantly lower flexural strength than other groups (P<0.05). The flexural strength was significantly higher when the build direction was $30^{\circ}$ than when it was $90^{\circ}$ (P<0.01). Conclusion: Among the build directions $0^{\circ}$, $30^{\circ}$, $45^{\circ}$, $60^{\circ}$, and $90^{\circ}$ set for 3D printing of fixed dental prosthesis, an orientation of $30^{\circ}$ is recommended as an effective build direction for 3D printing.

• Tribology and Lubricants
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• v.35 no.1
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• pp.44-51
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• 2019

The paper presents the rotordynamic performance measurements and model predictions of a fuel cell electric vehicle (FCEV) air compressor supported on gas foil bearings (GFBs). The rotor has an impeller on one end and a thrust runner on the other end. The front (impeller side) and rear (thrust side) gas foil journal bearings (GFJBs) are located between the impeller and thrust runner to support the radial loads, and a pair of gas foil thrust bearings are located on both sides of the thrust runner to support the axial loads. The test GFJBs have a partial arc shim foil installed between the top foil and bump strip layers to enhance hydrodynamic pressure generation. During the rotordynamic performance tests, two sets of orthogonally installed eddy-current displacement sensors measure the rotor radial motions at the rotor impeller and thrust ends. A series of speed-up and coast-down tests to 100k rpm demonstrates the dominant synchronous (1X) rotor responses to imbalance masses without noticeable subsynchronous motions, which indicates a rotordynamically stable rotor-GFB system. Finite element analysis of the rotor determines the rotor free-free (bending) natural modes and frequencies well beyond the maximum rotating frequency. The predicted damped natural frequencies and damping ratios of the rotor-GFB system reveal rotordynamic stability over the speeds of interest. The imbalance response predictions show that the predicted critical speeds and rotor amplitudes strongly agree with the test measurements, thus validating the developed rotordynamic model.

• Journal of Korean Tunnelling and Underground Space Association
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• v.20 no.6
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• pp.1177-1192
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• 2018

The objective of this study is to develop the existing drainage system for catching the partial leakage of tunnel structures operating in cold region. The drainage system consists of drainage board, Hotty-gel as a waterproofing material, cover for preventing protrusion of Hotty-gel, air nailer, fixed nail, pipe for collecting ground leak, pipe for conveying ground leak, wire-mesh, and sprayed cement mortar. The drainage systems were installed in conventional concrete lining tunnels to evaluate the site applicability and constructability. The performances of waterproof and the drainage in the drainage system were evaluated by injecting 1,000 ml of red water in the back of the drainage system at 7 days, 14 days, 21 days, 28 days, 2 months, 3 months, 4 months, 5 months, 6 months, 7 months and 8 months. During 8 months of field test, the average daily temperature of the tunnel site was measured from $-16.0^{\circ}C$ to $25.6^{\circ}C$. The daily minimum temperature was $-21.3^{\circ}C$ and the daily maximum temperature was $30.8^{\circ}C$. There was no problem in waterproof and drainage performance of the drainage board in the drainage system. However, the pipe for conveying ground leak had the leakage problem from 14 days. It is considered that the leakage of the pipe for conveying ground leak was caused by the deformation of the pipe of the flexible plastic material having a thickness of 0.2 cm by using the high pressure air nailer and the fixing pin and the insufficient thickness and width of the hotty-gel for preventing the leakage.

• Fire Science and Engineering
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• v.32 no.6
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• pp.34-39
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• 2018

In this paper, the architecture of a safe stove with an automatic fire suppression function using a sound wave fire extinguisher has been proposed and developed for the first time. A microcontroller connected to a fire sensor detects and suppresses a fire by driving a fire extinguisher. The sound wave fire extinguisher is composed of a speaker and collimator, and is driven by a driver module including an audio amplifier. The attenuation of the sound wave is reduced by preventing the sound diffusion with an enclosure surrounding a stove. The frequency of the sound wave is set to 50 Hz, and the sound pressure of 93 dBA is measured at the distance of 0.5 m. It takes maximum 8 and 15 seconds to suppress the flame from 7-cc and 14-cc flammable liquid, respectively, which corresponds to 24% and 42% of the natural extinguishing time. Since the proposed safe stove is non-toxic and leaves no residues over the conventional ones, it would combine with various home appliances to suppress early-stage fires and prevent fire expansion.

• 한국체육학회지인문사회과학편
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• v.58 no.6
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• pp.449-459
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• 2019

The purpose of this study is to identify how postural mechanics affects postural control on balance and stability by using frequency analysis technique from the kinematic data acquired during the one leg standing posture. For this purpose, the experimental group consisted of two groups, the normal group (n=6) and the national Gymnastics group (n=6). Displacement data of CoP were analyzed by frequency analysis of rambling (RM) and trembling (TR) by FFT signal processing. As a results, there was a significant difference in evaluating the stabilization index between the two groups with the eyes open and closed one leg stnading (p <.05). The cause of the difference was found to be the output of the maximum amplitude of RM (f1) and TR (f2) (p <.05). In particular, in the low frequency RM of 8-9 Hz, which is a natural frequency of signal wave involved in postural feedback feedback, the main frequency appeared to be performs the exercise mechanism of stable brain posture control. And in the high frequency TM of 120-135 Hz, it is considered that the adaptation of the reflective muscle response is minimized to minimize posture shaking. In conclusion, this study provides evidence for the intrinsic main frequencies according to the postural control ability which affects the CNS in one leg standing.

• Journal of Korean Society of Water and Wastewater
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• v.34 no.6
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• pp.393-402
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• 2020

In the membrane process, it is important to improve water treatment efficiency to ensure water quality and minimize membrane fouling. In this study, a pilot study of membrane process using reservoir water was conducted for a long time to secure high flux operation technology capable of responding to influent turbidity changes. The raw water and DAF(Dissolved Air Flotation) treated water were used for influent water of membrane to analyze the effect of water quality on the TMP (Trans Membrane Pressure) and to optimize the membrane operation. When the membrane flux were operated at 70 LMH and 80 LMH under stable water quality conditions with an inlet turbidity of 10 NTU or less, the TMP increase rates were 0.28 and 0.24 kPa/d, respectively, with minor difference. When the membrane with high flux of 80 LMH was operated for a long time under inlet turbidity of 10 NTU or more, the TMP increase rate showed the maximum of 43.5 kPa/d. However, when the CEB(Chemically Enhanced Backwash) cycle was changed from 7 to 1 day, it was confirmed that the TMP increase rate was stable to 0.23 kPa/d. As a result of applying pre-treatment process(DAF) on unstability water quality conditions, it was confirmed that the TMP rise rates differed by 0.17 and 0.64 kPa/d according to the optimization of the coagulant injection. When combined with coagulation pretreatment, it was thought that the balance with the membrane process was more important than the emphasis on efficiency of the pretreatment process. It was considered that stable TMP can be maintained by optimizing the cleaning conditions when the stable or unstable water quality even in the high flux operation on membrane process.