• 제목/요약/키워드: M-essential spectra

검색결과 25건 처리시간 0.03초

A SIGNATURE OF CHROMOSPHERIC ACTIVITY IN BROWN DWARFS: A RECENT RESULT FROM NIRLT MISSION PROGRAM

  • Sorahana, Satoko;Suzuki, Takeru K.;Yamamura, Issei
    • 천문학논총
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    • 제32권1호
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    • pp.131-133
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    • 2017
  • We present the latest results from the Mission Program NIRLT (PI: I.Yamamura), the near-infrared spectroscopy of brown dwarfs using the AKARI/IRC grism mode with the spectral resolution of ~ 120. The near-infrared spectra in the wavelength range between 2.5 and $5.0{\mu}m$ are especially important to study the brown dwarf atmospheres because of the presence of major molecular bands, including $CH_4$ at $3.3{\mu}m$, $CO_2$ at $4.2{\mu}m$, CO at $4.6{\mu}m$, and $H_2O$ around $2.7{\mu}m$. We observed 27 sources, and obtained 16 good spectra. Our model fitting reveals deviations between theoretical model and observed spectra in this wavelength range, which may be attributed to the physical condition of the upper atmosphere. The deviations indicate additional heating, which we hypothesize to be due to chromospheric activity. We test this effect by modifying the brown dwarf atmosphere model to artificially increase the temperature of the upper atmosphere, and compare the revised model with observed spectra of early- to mid-L type objects with $H{\alpha}$ emission. We find that the chemical structure of the atmosphere changes dramatically, and the heating model spectra of early-type brown dwarfs can be considerably improved to match the observed spectra. Our result suggests that chromospheric activity is essential to understand early-type brown dwarf atmospheres.

GC/MS와 data system을 이용한 한국산 향끽미종 잎담배의 정유성분 분석 (Analysis of Essential Oils from Korean Aromatic Tobacco Varieties by GC/MS and data system.)

  • 박진우;이운철;김용태;허일
    • 한국연초학회지
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    • 제4권1호
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    • pp.61-66
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    • 1982
  • Essential oil components were isolated from Korean aromatic tobaccos by using a simultaneous distillation and extraction apparatus. The essential oils were analyzed by GC/M S and date system. Forty-two volatile components were identified on the basis of their mass spectra. Determination of contents of essential oil components from Hyangcho and Sohyang was achieved by pseudo-multiple ion selection (Ml S) technique. Varietal differences were detected from the quantitative comparison of the MIS data.

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PET 열일렉트렛트의 열자극전류 (Thermally stimulated current of polythylene terephthalate thermoelectret)

  • 이덕출;진경시
    • 전기의세계
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    • 제30권8호
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    • pp.517-524
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    • 1981
  • Thermally stimulated currents have been obtained from five kinds of polymer electrets. The peak current (I$_{m}$) and the peak temperature (T$_{m}$) of the TSC, particularly at PET thermoelectret, were found to depend on the forming field and the forming temperature. From these experimental results, the TSC spectra can be easily explained by the consideration of the disorientation of dipoles related with glass transition temperature. The obtained results can suggest that the forming field and the forming temperature plays an essential role for charge stability in PET thermoelectrets.ets.

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Non-Essential Activation of Co2+ and Zn2+ on Mushroom Tyrosinase: Kinetic and Structural Stability

  • Gheibi, N.;Saboury, A.A.;Sarreshtehdari, M.
    • Bulletin of the Korean Chemical Society
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    • 제32권5호
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    • pp.1500-1506
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    • 2011
  • Tyrosinase is a widespread enzyme with great promising capabilities. The Lineweaver-Burk plots of the catecholase reactions showed that the kinetics of mushroom tyrosinase (MT), activated by $Co^{2+}$ and $Zn^{2+}$ at different pHs (6, 7, 8 and 9) obeyed the non-essential activation mode. The binding of metal ions to the enzyme increases the maximum velocity of the enzyme due to an increase in the enzyme catalytic constant ($k_{cat}$). From the kinetic analysis, dissociation constants of the activator from the enzyme-metal ion complex ($K_a$) were obtained as $5{\times}10^4M^{-1}$ and $8.33{\times}10^3M^{-1}$ for $Co^{2+}$ and $Zn^{2+}$ at pH 9 and 6 respectively. The structural analysis of MT through circular dichroism (CD) and intensive fluorescence spectra revealed that the conformational stability of the enzyme in these pHs reaches its maximum value in the presence of each of the two metal ions.

도계육 표면 내장 잔유물 오염 검사를 위한 형광 조사 및 방출파장 선정에 관한 연구 (Study on Fluorescence Excitation and Emission Bands for Detection of Fecal Residue on Poultry Carcasses)

  • 조병관;김문성
    • Journal of Biosystems Engineering
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    • 제33권2호
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    • pp.136-141
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    • 2008
  • Fecal contaminations on poultry carcasses, not easily discemable by human eyes, are potential harbor sites of pathogenic Escherichia Coli (E. coli O157:H7). Development of sensitive detection methods for fecal contamination is essential to ensure safe production of poultry products. Fluorescence has been shown to be very sensitive in detecting fecal and other biological substances that can harbor pathogens. In this study, fluorescence excitation-emission spectra of poultry fecal matter were compared with spectra for poultry skin and meat. Results indicated that the combinations of fluorescence intensities at the wavelength of 520 nm, 579 nm, 625 nm, and 635 nm with 411 nm excitation showed above 97% accuracy for differentiation of the contaminants from poultry tissues. Excitation and emission bands determined could be used for constructing a real-time fluorescence imaging device for detection of harmful residues on poultry carcasses.

보배광산에서 산출하는 열수변질 기원 녹염석의 분광학적 특성: 적외선 및 뫼스바우어 연구 (FTIR and M ssbauer Spectroscopic Studies on the Hydrothermal Epidote from the Bobae Clay Deposit, Pusan, Korea)

  • 추창오;김수진
    • 한국광물학회지
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    • 제9권2호
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    • pp.55-63
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    • 1996
  • Epidote occurs as veinlets in the propylitic alteration zone of the Bobae clay deposit, Pusan, Korea. Its cell parameters apparently decrease with the contents of Al, Fe, and Ca. Fourier transform infrared (FTIR) spectra show one hydrosyl environment related to AlM2 at 3357-3358 cm-1. In the mid-infrared region, the peaks at 950 and 1030 cm-1 sharper with increasing Al shifting to higher energy region. The peak at 885 cm-1 shifts slightly to a lower energy region with a decreasing intensity as the Fe content increases. In the far-IR region, epidote exhibits absorption bands at 120 and 140 cm-1, which are related to the Ca-O bonds in A-sites.M ssbauer spectra of epidote show that the isomer shifts of Fe3+ range from 0.36-0.37 at the M3 site and from 0.35-0.44 at M1 site. Fe2+ shows the isomer shift ranging from 1.11 to 1.13. Quadrupole splitting is 2.04 for Fe3+M3, 0.52-0.70 for Fe3+M1, and 2.61-2.70 for Fe2+M3. Calculation shows Fe3+M386-90.7%, Fe3+M12.5-3.6%, and Fe2+M35.8-11.4% of total iron, showing preferential distribution of Fe3+ in the M3 site. The Fe3+M3 content is between 0.486 and 0.513 per formula unit. in the Fe-rich epidote, less Fe3+ and more Fe2+ are accommodated in the M1 and M3 sites. Hence, the overall disorder increases as total Fe content increase. The ordering parameter of the Bobae epidote is 0.93-0.95, suggesting a disequilibrium state below 200$^{\circ}C$. The constant temperature over a long period may be essential for the transition from disordered state to equilibrium state, despite the possible variation in flux and composition of the hydrothermal fluid.

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개비자나무 Cephalotaxus koreana Nakai 잎의 성분 연구 (I) (Studies on Chemical Components of Cephalotaxus koreana Nakai)

  • 육창수;정진환;이종일
    • 한국자원식물학회지
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    • 제13권2호
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    • pp.89-94
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    • 2000
  • Cephalotaxus koreana Nakai is endemic species of Korea. Since old days, the fruits have been used as a parasiticide and leaves have been used for a pierced wound by insects. The essential oil components from its aerial parts and stem bark by steam distillation were investigated. Several compounds were characterized by GC-Mass spectra. It was found that the leaves, stembark and flowers contain the compounds of essential oils, 1-octene-3-ol, hexadecanoic acid; $\alpha$-pinene, $\Delta^3$-carene mainly, linalylacetate, $\beta$-cubebene, 3,4-octadine-7-methyl , ferruginol(stem bark) and $\alpha$-pinene mainly, $\beta$-pinene , cyclopropane-1,1-dimethyl-2-(3-methyl-1,3-butadienyl), etc. This Cephalotaxus spp. contains the first components of ferruginol(M.W.286.03, $C_{20}H_{30}O)$ which belong to diterpene.

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Low-Frequency Ultrasonic Relaxation of β-Cyclodextrin and Adenosine 5'-Monophosphate in Aqueous Solution

  • Bae, Jong-Rim;Lee, Chang-Woo
    • Bulletin of the Korean Chemical Society
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    • 제30권1호
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    • pp.145-148
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    • 2009
  • Nucleotides are the building blocks of nucleic acids and essential for many cellular functions. In this study, ultrasonic absorption spectra of $\beta$-cyclodextrin ($\beta$-CD) and adenosine 5'-monophosphate (AMP) in aqueous solution were measured over the broad frequency range 0.1-40 MHz with emphasis on the low-frequency range below 1 MHz. Here we show that the interaction of $\beta$-CD and AMP complies with a typical spectrum of a single relaxation process. We determined reliable rate (kb) and equilibrium (K) constants and a standard volume change ($\Delta$V) of the reaction. They are $k_b=2.3{\times}{{10^{-6}}_s}^{-1},\;K=89M^{-1},\;and\;{\Delta}V=13.8(10^{-6}m^3mol^{-1})$, respectively.