• Title/Summary/Keyword: M-S2X

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Synthesis and Characterization of Group 13 Compounds of 2-Acetylpyridine Thiosemicarbazone. Single-Crystal Structure of $(iC_4H_9)-2Al(NC_5H_4C(CH_3)$NNC(S)NHPh)

  • 강영진;강상옥;고재정;손정인
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.65-68
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    • 1999
  • Novel mononuclear group 13 metal complexes with the formula (R2M){NC5H4C(CH3)NNC(S)NH(C6H5)} (M=Al, R=iC4H9 (1); M=Ga, R=iC4H9 (2); M=Al, R=CH2SiMe3 (3); M=Ga, R=CH2SiMe3 (4)) result when 2-acetyl pyridine 4-phenyl-thiosemicarbazone ligand is mixed with trialkyl aluminum or trialkylgallium. These compounds 1-4 are characterized by microanalysis, NMR (1H, 13C) spectroscopy, mass spectra, and singlecrystal X-ray diffraction. X-ray single-crystal diffraction analysis reveals that 1 is mononuclear metal compound with coordination number of 5 and N, N, S-coordination mode.

Studies on Effect of S/Se Ratio on the Properties of Cu2ZnSn(SxSe1-x)4 (CZTSSe) Thin Films by Sulfo-Selenization of Stacked Precursor Thin Films (열처리 시 S/Se 분말 비율에 따른 Cu2ZnSnSe4 (CZTSSe) 박막의 합성 및 특성 평가)

  • Gang, Myeng Gil;He, Ming Rui;Hong, Chang Woo;Kim, Jin Hyeok
    • Current Photovoltaic Research
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    • v.2 no.4
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    • pp.177-181
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    • 2014
  • $Cu_2ZnSn(S_xSe_{1-x})_4$ (CZTSSe) absorber thin films were prepared on Mo coated soda lime glass substrates by sulfo-selenization of sputtered stacked Zn-Sn-Cu precursor thin films. The Zn-Sn-Cu precursor thin films were sulfo-selenized inside a graphite box containing S and Se powder using rapid thermal processing furnace at $540^{\circ}C$ in Ar atmosphere with pre-treatment at $300^{\circ}C$. The effect of different S/Se ratio on the structural, compositional, morphological and electrical properties of the CZTSSe thin films were studied using XRD (X-ray diffraction), XRF (X-ray fluorescence analysis), FE-SEM (field-emission scanning electron microscopy), respectively. The XRD, FE-SEM, XRF results indicated that the properties of sulfo-selenized CZTSSe thin films were strongly related to the S/Se composition ratio. In particular, the CZTS thin film solar cells with S/(S+Se)=0.25 shows best conversion efficiency of 4.6% ($V_{oc}$ : 348 mV, $J_{sc}$ : $26.71mA/cm^2$, FF : 50%, and active area : $0.31cm^2$). Further detailed analysis and discussion for effect of S/Se composition ratio on the properties CZTSSe thin films will be discussed.

SOME ALGORITHMS OF THE BEST SIMULTANEOUS APPROXIMATION

  • Rhee, Hyang J.
    • Journal of the Chungcheong Mathematical Society
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    • v.22 no.2
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    • pp.141-148
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    • 2009
  • We consider various algorithms calculating best onesided simultaneous approximations. We assume that X is a compact subset of $\mathbb{R}^{m}$ satisfying $X=\overline{intX}$, S is an n-dimensional subspace of C(X), and $\mu$ is any 'admissible' measure on X. For any l-tuple $f_1,\;{\cdots},\;f_{\ell}$ in C(X), we present various ideas for best approximation to F from S(F). The problem of best (both one and two-sided) approximation is a linear programming problem.

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The study of X-ray detection using II-VI group photoconductor (II-VI족 광도전체를 사용한 X-선량 검출에 대한 연구)

  • Nam, S.H.;Cho, S.Y.;Choi, J.Y.;Kang, Y.S.;Eun, C.K.
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.05
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    • pp.27-30
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    • 1997
  • As the fundamental study of designing x-ray dosimeter , we measured the voltage variation of CdS, II-VI group semiconductor compound, by mAs variation. We obtained data in the condition of 50, 70 kVp, by increasing the tube current as 1, 2, 2.5, 3.2, 4, 5, 10, 20, 32, 50 and 80 mAs. The output time of CdS was increased as mAs increased. We figured the slope value of 50kVp as 0.0088 and 0.0081 of 70 kVp. And by regression method, we obtained the standard deviation of time, Y axis, at 50 and 70kVp as 0.00268 and 0.00333. The result of this ssudy is so important to design x-ray dosimeter.

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THE TEMPERATURE DEPENDENCE OF THE MAGNETIZATION OF THE AMORPHOUS $Co_{80+x}TM_{12}B_{8-x}$ (TM = Ti, Zr, Hf, Nb) ALLOYS

  • Han, Seung-Man;Yu, Seong-Cho;Kim, Kwang-Youn;Noh, Tae-Hwan;Kim, Hi-Jung
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.496-499
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    • 1995
  • Amorphous $Co_{80+x}TM_{12}B_{8-x}$ (TM = Ti, Zr, Hf, Nb and x = 0, 2, 4 at%) alloys were prepared by single roll melt spinning technique. Saturation magnetization of the amorphous ribbons was measured by SQUID and vibrating sample magnetometer from 5 to 800 K under applied fields up to 10 kOe. Typical thermo-magnetization curves were observed and the average values of the spectroscopic splitting g factor were estimated from the ferromagnetic resonance curve. For all the amorphous alloys studied here the saturation magnetization in the temperature range 5 K up to about $0.3T_{c}$ can be described by the Bloch relation: $M_{s}(T)\;=\;M_{s}(0)(1-BT^{3/2}-CT^{5/2})$. From the values of $M_{s}(0)$, B and spectroscopic splitting g factor the spin wave stiffness constants were calculated.

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Magnetic Properties of Melt-spun Fe-Nd-C Alloys (급속응고에 의해 제조된 Fe-Nd-C 합금의 자기적 특성)

  • Jang, T.S.;Lim, K.Y.;Cho, D.H.
    • Korean Journal of Materials Research
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    • v.7 no.12
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    • pp.1063-1069
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    • 1997
  • For me1t-spun Fe-Nd-C alloys, variation of phase development and magnetic properties with the variety of alloy compositions and production conditions were investigated. To find out whether hard magnetic $Fe_{14}Nd_2C$ is crystallized direct1y from the melt by rapid quenching, the phase development of the as-spun ribbons spun at various speed was a1so studied. For the ribbons spun at 10m/s, ${\alpha}-Fe$ was the primary crystallization phase followed by the secondary $Fe_{17}Nd_2C$. At 20m/s ${\alpha}-Fe$ was suppressed so that the primary $Fe_{17}Nd_2C$ coexisted with the secondary ${\alpha}-Fe$ and the amorphous phase. Above 30m/s the ribbons were a1most amorphous, and the amorphization was complete at 40m/s. $Fe_{14}Nd_2C$ therefore was not found in as-spun state but obtained after heat treating the ribbons. The effective temperature range ($700{\sim}900^{\circ}C$) in which $Fe_{14}Nd_2C$ can be obtained was wider than that of a cast alloy. An alloy made with the wheel speed of 20 or 30m/s yielded higher coercivities after heat treatment. In iron-rich Fe-Nd-C, the composition range in which a high coercivity (more than 10kOe) is expected is narrow, i.e., 77~78 Fe and 7~8 C(at.%).

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COMMUTING STRUCTURE JACOBI OPERATOR FOR SEMI-INVARIANT SUBMANIFOLDS OF CODIMENSION 3 IN COMPLEX SPACE FORMS

  • KI, U-Hang;SONG, Hyunjung
    • East Asian mathematical journal
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    • v.38 no.5
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    • pp.549-581
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    • 2022
  • Let M be a semi-invariant submanifold with almost contact metric structure (𝜙, 𝜉, 𝜂, g) of codimension 3 in a complex space form Mn+1(c), c≠ 0. We denote by S and R𝜉 be the Ricci tensor of M and the structure Jacobi operator in the direction of the structure vector 𝜉, respectively. Suppose that the third fundamental form t satisfies dt(X, Y) = 2𝜃g(𝜙X, Y) for a certain scalar 𝜃(≠ 2c) and any vector fields X and Y on M. In this paper, we prove that M satisfies R𝜉S = SR𝜉 and at the same time R𝜉𝜙 = 𝜙R𝜉, then M is a Hopf hypersurface of type (A) provided that the scalar curvature s of M holds s - 2(n - 1)c ≤ 0.

Application of Exchange Equations for NH4-K NH4-Ca Equilibria (NH4-K 와 NH4-Ca 평형에 대한 양이온 치환식의 적용)

  • Chung, Jong-Bae;Sa, Tong-Min
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.3
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    • pp.218-226
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    • 1995
  • Ion exchange equilibria in bulk and rhizosphere soil collected from peach seedlings were studied to find exchange equations that could be used in chromatographic models dealing with movement and distribution of fertilizer ammonium and exchangeable cations in soil profiles. Soil samples were equilibrated with mixtures of $NH_4Cl$, KCI, and $CaCl_2$ solutions and then extracted with $Sr(NO_3)_2$ solution to determine exchangeable cation compositions at equilibrium. Exchange data were fitted to Vanselow's, Gapon's, and Kerr's equations, but those formulations did not adequately describe the equilibria. An empirical equation of the form : ${\frac{\alpha_i^m}{a_j^n}}=K{\frac{(iX)^{mPi}}{(jX)^{nPj}}}$ which has an exponent on each of the exchangeable cation concentrations could describe the equilibria very well over the range of treatments. In this equation ${\alpha}^i$ and ${\alpha}^j$ are activities of cation i and j with valences m and n respectively. (iX) and (jX) are concentrations of exchangeable cations. Mole or equivalent fractions can be considered as the exchangeable ion concentration unit. Arbitrary constants $P_i$ and $P_j$, and distribution coefficient K can be found with multiple regression for the logarithmic form of the equation.

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A Reconfigurable Multiband FMCW Radar for Multipurpose Application (다목적활용을 위한 재구성이 가능한 다중대역 FMCW 레이다)

  • Kim, Byungjoon;Koo, Jong-seop;Kim, Duksoo;Nam, Sangwook
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.26 no.12
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    • pp.1112-1115
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    • 2015
  • Recently, there have been advancements in radar related material technology, circuit design techniques and architecture design techniques. These have led to developments in radars' performance while decreasing the costs. Many studies have been carried out to apply radars to multipurpose application. In this study, a reconfigurable S-/X- band radar structure for multipurpose application is proposed and implemented. This radar measures a $51.2cm{\times}50.6cm$ target for 10 times from 2 m to 6 m range with 0.25 m distance step. The measured results show that this radar has 26.40 cm maximum range error, 5.63 cm average range error, and 0.24 cm range error variance at S-band while it has 8.53 cm maximum range error, 2.52 cm average range error, and 0.04 cm range error variance at X-band.

Precise Rates in Complete Moment Convergence for Negatively Associated Sequences

  • Ryu, Dae-Hee
    • Communications for Statistical Applications and Methods
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    • v.16 no.5
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    • pp.841-849
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    • 2009
  • Let {$X_n$, n ${\ge}$ 1} be a negatively associated sequence of identically distributed random variables with mean zeros and positive finite variances. Set $S_n$ = ${\Sigma}^n_{i=1}\;X_i$. Suppose that 0 < ${\sigma}^2=EX^2_1+2{\Sigma}^{\infty}_{i=2}\;Cov(X_1,\;X_i)$ < ${\infty}$. We prove that, if $EX^2_1(log^+{\mid}X_1{\mid})^{\delta}$ < ${\infty}$ for any 0< ${\delta}{\le}1$, then $\lim_{{\epsilon}\downarrow0}{\epsilon}^{2{\delta}}\sum_{{n=2}}^{\infty}\frac{(logn)^{\delta-1}}{n^2}ES^2_nI({\mid}S_n{\mid}\geq{\epsilon}{\sigma}\sqrt{nlogn}=\frac{E{\mid}N{\mid}^{2\delta+2}}{\delta}$, where N is the standard normal random variable. We also prove that if $S_n$ is replaced by $M_n=max_{1{\le}k{\le}n}{\mid}S_k{\mid}$ then the precise rate still holds. Some results in Fu and Zhang (2007) are improved to the complete moment case.