• Korean Chemical Engineering Research
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• 제59권1호
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• pp.85-93
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• 2021

For accurate and reliable process design for phenol oxidation in a plug flow reactor with supercritical water, modeling can be very insightful. Here, the velocity and density distribution along the reactor have been predicted by a numerical model and variations of temperature and phenol mass fraction are calculated under various flow conditions. The numerical model shows that as we proceed along the length of the reactor the temperature falls from above 430 ℃ to approximately 380 ℃. This is because the generated heat from the exothermic reaction is less that the amount lost through the walls of the reactor. Also, along the length, the linear velocity falls to less than one-third of the initial value while the density more than doubles. This is due to the fall in temperature which results in higher density which in turn demands a lower velocity to satisfy the continuity equation. Having a higher oxygen concentration at the reactor inlet leads to much faster phenol destruction; this leads to lower capital costs (shorter reactor will be required); however, the operational expenditures will increase for supplying the needed oxygen. The phenol destruction depends heavily on the kinetic parameters and can be as high as 99.9%. Using different kinetic parameters is shown to significantly influence the predicted distributions inside the reactor and final phenol conversion. These results demonstrate the importance of selecting kinetic parameters carefully particularly when these predictions are used for reactor design.

• 한국산학기술학회논문지
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• 제20권11호
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• pp.527-536
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• 2019

본 연구에서는 PTT BCF의 열과 자외선에 의한 취화거동과 분산염료의 열 및 자외선에 의한 퇴색거동을 연구하였다. 염료의 퇴색과 PTT BCF의 취화를 억제시킬 수 있는 첨가제를 방사과정에서 첨가하여 그 효과를 알아보았다. PTT BCF의 열처리 이후 취화거동은 열처리 온도와 노출시간이 증가할수록 취화현상이 가속화되어 시료의 인장강도 저하가 두드러졌다. 시료가 120℃까지의 온도에 노출하였을 때는 인장강도의 저하가 크지 않으나 그 이상의 온도인 150℃에서는 노출시간에 비례하여 급격한 인장강도 저하를 보였다. 열에 의한 취화는 산화방지 첨가제가 높은 온도에서는 그 효과가 안정적이지 않으며 산화반응이 급격하였다. 열처리 이후 시료의 퇴색은 열처리 온도가 증가할수록 K/S 값이 감소하였고, 노출시킨 시간이 증가할수록 퇴색되는 경향이 강하게 나타났다. 특히 고온으로 갈수록 열에 의한 퇴색 거동이 급격하게 증가하였으며 열퇴색 억제제가 그 효과를 발휘하지 못했다. 자외선 조사 이후 PTT BCF의 취화거동과 퇴색거동을 인장강도 변화와 K/S 값 변화로 각각 살펴보았다. 자외선 조사에 따른 취화는 열처리 시의 취화보다 더 크게 나타났으며, 특히 장시간 동안 노출된 경우 인장강도의 저하가 급격하였다. 또한 K/S 값의 변화 역시 온도와 노출시간이 증가할수록 퇴색거동이 강하게 나타났다. 시료의 취화거동과 퇴색거동은 자외선 조사의 경우가 더 가혹하게 나타났다. 열 및 자외선 모두가 분산염료의 퇴색에 영향을 주며, 자외선 조사는 같은 온도에서 노출했을 때에 비해 아주 높은 퇴색 속도를 보였다. 결론적으로 열과 자외선에 의한 퇴색과 취화는 특정 산화방지제와 자외선흡수제에 의해 다소 억제되어 저하되었다.

• 한국식품과학회지
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• 제16권2호
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• pp.206-210
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• 1984

느타리버섯 통조림의 관형별 및 살균온도에 따른 충전고형량별 열침투특성을 측정하고 이에 따른 제반 살균조건을 검토하였다. 고형량비가 감소함에 따라 $f_h$값은 급격히 감소하다가 관형에 따른 특정 고형량비, 즉, 4호관의 경우 고형량비3/5, 버섯 4온스관의 경우 고형량비 2/5, 휴대관의 경우 고형량비 1/5 이하부터 안정된 값을 나타냈고 온도의 영향으로는 높은 가열온도에서 낮은 $f_h$값으로 열전달이 약간 빠른 경향을 보여 주고 있었다. $f_h$값으로 본 경향으로는 관형의 L/D 값이 클수록 높은 고형량비에서 전도에서 대류로 열전달형태가 바뀌어지고 있었고 $j_h$값은 고형량비가 감소함에 따라 1.0에 가까와 지고 있었다. 열침투특성에 의해 결정되는 살균시간면에서는 품질보존을 고려하여 고형량비는 3/5이하로 관리되어야 하는 것으로 나타났다. 단위고형물당 살균시간으로 비교할 때 큰 관형일수록 작은 값을 보여 주고 고형량비 2/5이상에서 안정된 작은 값을 나타내고 고형량비 3/5에서 가장 작은 값을 나타내었다. 단위고형물당 살균에너지소비 측면에서는 고형량비 3/5이상이 경제적이었다. 위의 제반 살균조건면에서 전체적으로 고려할 때 관형에 관계없이 고형량비 3/5으로 조정하여 살균 가공함이 최적조건이었다.

• KIEAE Journal
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• 제17권2호
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• pp.5-12
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• 2017

Purpose: Under the purpose of presenting the adequate remodeling period for the improvement of thermal insulation performance of external walls in deteriorated buildings, the change in external wall and residential environment problem(dew condensation) due to aged deterioration after the apartments were constructed in Korea were analyzed. Method: Temperature Difference Ratio Outside(TDRo) and Heat Flow Meter(HFM) were used as measurement methods to evaluate the thermal insulation performance of deteriorated buildings. For TDR evaluation, thermo-graphic camera was used to measure and analyze the surface temperature of external wall. Also, dew condensation evaluation was analyzed using the Temperature Difference Ratio Inside(TDRi). Result: As a result of analyzing thermal performance through TDRo, the first decline point of thermal insulation performance began after 14-16 years have passed since construction was completed, and after 20 years have passed the decline point of thermal insulation performance reappeared. As a result of analyzing U-value with HFM measurement method, the decline rate of external wall's thermal insulation performance is lower than 2% in average at around 5 years after completion, and 8.7% in average at 10-15 years, and over 10.2% in average at 20 years.

• 한국재료학회지
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• 제14권9호
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• pp.642-648
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• 2004

The microstructure and crack tip opening displacement (CTOD) of deposit weld metal were investigated for a 30 mm- thick plate welded with flux cored arc welding (FCAW) and submerged arc welding (SAW) processes. The CTOD test was carried out both as welded condition and as stress-relieved specimen by local compression. The crack growth rates in FCAW were faster than those in a SAW, and the acicular ferrite content by the SAW process was increased relatively more than that by the FCAW process. The fatigue crack growth rate in a welded specimen was faster than that in locally compressed specimen. The CTOD value of locally compressed specimens was lower than that of as welded specimen. Furthermore, the CTOD value tested with the SAW process was higher than that tested with the FCAW process.

• 한국철도학회논문집
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• 제9권2호
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• pp.237-243
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• 2006

Deicing system is to melt frost or ice freezed in catenary line when the temperature is lower than $0^{\circ}C$ in winter. The principle of deicing system is to melt frost or ice by Joule heat of catenary impedance. The performance of deicing is dependant of deicing current determined by the length of deicing section, deicing impedance and current division ratio of catenary line and messenger line. So, we present technique for estimating deicing current and process for determination of deicing section in the conventional line. Deicing impedance is estimated using Carson-Pollaczek equation, and current division ratio of catenary line and messenger line is estimated using voltage drop, and deicing current is estimated using power system data of deicing system. For the determination of the final deicing section, we verified estimated value comparing with experiment value of deicing impedance and current division ratio of catenary line and messenger line using low voltage experiment. Finally, we verified the validity of estimation technique and process using a simulated test data of real deicing system operation in the Chungju Substation, Chungbuk line.

• 한국태양에너지학회 논문집
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• 제32권2호
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• pp.58-63
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• 2012

As the exterior of building has been considered one of th important parts, the use of glass that is suitable to express various appearances gets raised. However, windows have 6~7times lower insulating performance than insulated walls. Lately, highly efficient windows are required as the needs for reduction of energy consumption come to the force. Therefore, Nowadays more people use cooling systems in summer, more the use of Low-E glazing is increasing. Because it is good to block Solar Radiant Energy which can cause much of heat loss while cooling system is working. This study measures U-value of the double Low-E glazing window and commonly used single Low-E glazing window. And then the effect of each window on the efficiency rating has been analyzed applying to the certification system of the building energy efficiency rating which has implemented.

• 콘크리트학회논문집
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• 제16권2호
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• pp.283-291
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• 2004

Recently, the construction of underwater structures has been gradually increased, but underwater concrete got some problems of quality deterioration and water contamination around cast-in-situ of construction. In addition, massive underwater structures such as LNG tank, underwater concrete structures of large and continuous high- strength subterranean wall under water are being demanded lower heat of hydration. In this paper, the mechanical properties of high-strength antiwashout underwater concrete (HAWC) containing with two kinds of mineral admixtures respectively were investigated. On the basis of these results, the pH value and suspended solids of HAWC manufactured in the mock-up test were 10.0$\Box$11.0 and 51 mg/${\iota}$ at 30 minutes later, respectively, initial and final setting time were about 30,37 hours, and the slump flow was 530$\pm$20Tm. In the placement at a speed of $27 m^3/hr$, there was no large difference in flowing velocity with or without reinforcing bar, and flowing slope was maintained at horizontal level. Compressive strength and elastic modulus of the cored specimen somewhat decreased as flowing distance was far; however, those of central area showed the highest value.

• 비파괴검사학회지
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• 제35권5호
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• pp.314-320
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• 2015

본 연구에서는 펨토초의 펄스폭을 갖는 극초단 레이저를 이용하여 나노 스케일 초전도 재료의 열전도율을 측정하였다. 95 nm 두께의 이트륨바륨구리산화물($YBa_2Cu_3O_7-x$)을 티탄산스트론튬($SrTiO_3$) 기판 위에 펄스레이저 증착법으로 적층하여 시편을 제작하였으며, 유한차분법으로 1차원 과도 열전도 방정식의 해를 구하여 측정결과와 비교하였다. 곡선맞춤을 통하여 1.2 W/mK의 열전도율을 얻었으며, 이는 동일 재료의 벌크(bulk) 물성치에 비하여 낮은 값으로 확인된다. 본 연구는 마이크로/나노소자의 열설계를 위한 초전도 나노재료의 특성을 규명한다.

• 대한가정학회지
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• 제38권11호
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• pp.105-114
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• 2000

The purpose of this study was to investigate the wearing satisfaction of highschool girls’summer uniforms, and to evaluate the comfort-related properties of fabrics used in the uniforms. The subjects were 441 female high school students attending three different schools in Chongju city. The data was collected using self-administered questionnaires to measure the wearing satisfaction of summer school uniforms. Factor analysis, t-test, and F-test were used for data analysis. The heat and moisture transfer properties and air permeable properties of their fabrics were evaluated to measure as comfort-related properties. 1. Most students were wearing blouses made of polyester/rayon blended fabrics and skirts made of 50% wool and 50% polyester blended fabrics. 2. Clothing care and management, and appearance of summer school uniform were assessed positively, while style and design, and the level of comfort were assessed negatively. 3. The subfactors of wearing satisfaction varied according to school, style and design, and fabrics of high school girls’summer uniforms. 4. PET fabrics were rated as having a lower value of thermal retention and a higher value of air permeability than other blouse fabrics. 5. There were not differences significantly in thermal properties according to skirt materials.