• Transactions of the Korean hydrogen and new energy society
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• v.34 no.3
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• pp.297-306
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• 2023

The frequency of fatal accidents that can occur at hydrogen refueling station was compared with the risk criterion for the general public suggested by the health and safety executive. If hydrogen refueling station meets the accident prevention facility standards presented in KGS Code FP216/217, it was confirmed that the risk of hydrogen refueling station was not at an unacceptable (intolerable) risk level. However, the risk of hydrogen refueling station due to small leak was analyzed as low as reasonably practicable. Therefore, methods for improving the safety instrumented function of hydrogen refueling station were reviewed. It was confirmed that the risk of hydrogen refueling station can be affected by the number of installed safety instrumentation system components, redundant architecture, mission time, proof test interval, etc. And methods for maintaining the risk of hydrogen refueling station at an acceptable risk level have been proposed.

• Journal of the Korean institute of surface engineering
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• v.56 no.6
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• pp.412-419
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• 2023

Anion exchange membrane electrolysis is considered a promising next-generation hydrogen production technology that can produce low-cost, clean hydrogen. However, anion exchange membrane electrolysis technology is in its early stages of development and requires intensive research on electrodes, which are a key component of the catalyst-system interface. In this study, we optimized the pressure conditions of the hot-pressing process to manufacture cobalt oxide electrodes for the development of a high uniformity and high adhesion electrode production process for the oxygen evolution reaction. As the pressure increased, the reduction of pores within the electrode and increased densification of catalytic particles led to the formation of a uniform electrode surface. The cobalt oxide electrode optimized for pressure conditions exhibited improved catalytic activity and durability. The optimized electrode was used as the anode in an AEMWE single cell, exhibiting a current density of 1.53 A cm^-2 at a cell voltage of 1.85 V. In a durability test conducted for 100 h at a constant current density of 500 mA cm^-2, it demonstrated excellent durability with a low degradation rate of 15.9 mV kh^-1, maintaining 99% of its initial performance.

• Journal of Energy Engineering
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• v.28 no.4
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• pp.29-34
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• 2019

In this study, a quantitative risk assessment was carried out for a hydrogen complex station. The complex fueling station to be evaluated was hydrogen-LPG, and the components of each station were analyzed and the risk was evaluated. The final risk is assessed by individual and societal risks, taking into account the impact of damage and the frequency of accidents. As a result of individual risk calculation for the hydrogen-LPG fueling station that is the subject of this study, the hydrogen-LPG type fueling station does not show the unacceptable hazardous area (> 1 × 10E-3) proposed by HSE. The level of individual risk for both the public and the worker is within acceptable limits. In societal risk assessment, the model to be interpreted shows the distribution of risks in an acceptable range(ALARP, As Low As Reasonably Practicable). To ensure improved safety, we recommend regular inspections and checks for high-risk hydrogen reservoirs, dispensers, tube trailer leaks, and LPG vapor recovery lines.

• Journal of the Korean Society of Combustion
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• v.18 no.1
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• pp.27-33
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• 2013

Hydrogen-dimethy ether(DME) partially premixed compression ignition(PCCI) engine combustion was investigated in a single cylinder compression ignition engine. Hydrogen and DME were used as low carbon alternative fuels to reduce green house gases and pollutant. Hydrogen was injected at the intake manifold with an injection pressure of 0.5 MPa at fixed injection timing, $-210^{\circ}CA$ aTDC. DME was injected directly into the cylinder through the common-rail injection system at injection pressure of 30 MPa. DME inejction timing was varied to find the optimum PCCI combustion to reduce CO, HC and NOx emissions. When DME was injected early, CO and HC emissions were high while NOx emission was low. As the DME injection was retarded, the CO and HC emissions were decreased due to high combustion efficiency. NOx emissions were increased due to the high in-cylinder temperature. When DME were injected at $-30^{\circ}CA$ aTDC, reduction of HC, CO and NOx emissions was possible with high value of IMEP.

• Journal of the Korean Electrochemical Society
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• v.17 no.1
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• pp.18-25
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• 2014

A Pt nanoparticle-decorated multiwall carbon nanotube (Pt-MWNT) electrode was prepared on Nafion by a hot-pressing at relatively low temperature. This electrode exhibited an intricate entangled, nanoporous structure as a result of gathering highly anisotropic Pt-MWNTs. Individual Pt nanoparticles were confirmed to have a polycrystalline face-centered cubic structure with an average crystal size of around 3.5 nm. From the cyclic voltammograms for hydrogen redox reactions, the Pt-MWNT electrode was found to have a similar electrochemical behavior to polycrystalline Pt, and a specific electrochemical surface area of $2170cm^2mg^{-1}$. Upon exposure to hydrogen analyte, the Pt-MWNT/Nafion electrode demon-strated a very high sensitivity of $3.60{\mu}A\;ppm^{-1}$ and an excellent linear response over the concentration range of 100-1000 ppm. Moreover, this electrode was also evaluated in terms of response and recovery times, reproducibility, and long-term stability. Obtained results revealed good sensing performance in hydrogen detection.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.4
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• pp.302-310
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• 2013

As an initial step to develop a liquid hydrogen pump of piston type operated under cryogenic and high pressure, leakage and piston head shape for the piston pump were discussed with temperature and pressure. As the results, the leakage depended on correlation among density, viscosity, clearance area by the low temperature. In order to reduce the leakage, it was found that the air-tightness can be improved by minimizing contact surface between piston and cylinder, and also increasing pressure in-cylinder can reduce piston clearance. Among the proposed piston shapes, D type piston shape had the most air-tightness. D type piston had smaller contact surface than other piston shape and easier expansion of cup shape by pressure. The leakage of D type piston shape was found about 7%, compared with A type piston shape. But it was required that analyze about vapor lock by friction and wear resistance.

• Korean Journal of Materials Research
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• v.30 no.12
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• pp.655-659
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• 2020

Hydrogen isotopes (i.e. deuterium and tritium) are supplied to the tokamak in the International Thermonuclear Experimental Reactor (ITER) fuel cycle. One important part of the ITER fuel cycle is the recycling of unused fuel back to the tokamak, as almost 99 % of fuel is unburned during fusion reaction. For this, cryogenic distillation has been used in the isotope separation system (ISS) of ITER, but this technique tends to be energy-intensive and to have low selectivity (typically below 1.5 at 24 K). Recently, efficient isotope separation by porous materials has been reported in the so-called quantum sieving process. Hence, in this study, hydrogen isotope adsorption behavior is studied using chemically stable ZIF-11. At low temperature (40 K ~ 70 K), the adsorption increases and the sorption hysteresis becomes stronger as the temperature increases to 70K. Molar ratio of deuterium to hydrogen based on the isotherms shows the highest (max. 14) ratio at 50 K, confirming the possibility of use as a potential isotope separation material.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.3
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• pp.242-248
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• 2013

The purpose of this study is to obtain low-emission and high-efficiency by hydrogen enriched LPG fuel in LPG engine and is to clarify the effects of hydrogen enrichment in LPG fuelled engine on exhaust emission and performance. An experimental study was carried out to obtain fundamental data for performance and emission characteristics of hydrogen enrichment in LPG engine. The research was held by changing the hydrogen ratio to 0, 5, 10, 20% in 1500rpm, bmep 2 and 4bar. The result turned out that the combustion duration was shortened due to fast flame propagation of hydrogen. And the amount of Carbon dioxide and Hydrocarbon decreased. However, the amount of NOX increased, which is thought to be the result of high adiabatic flame temperature of hydrogen. It has been confirmed that this phenomenon has changed by the Hydrogen mixing ratio.

• Korean Journal of Materials Research
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• v.22 no.3
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• pp.159-167
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• 2012

Hydrogen is in the spotlight as an alternative next generation energy source for the replacement of fossil fuels because it has high specific energy density and emits almost no pollution, with zero $CO_2$ emission. In order to use hydrogen safely, reliable storage and transportation methods are required. Recently, solid hydrogen storage systems using metal hydrides have been under extensive development for application to fuel cell vehicles and fuel cells of MCFC and SOFC. For the practical use of hydrogen on a commercial basis, hydrogen storage materials should satisfy several requirements such as 1) hydrogen storage capacity of more than 6.5wt.% $H_2$, moderate hydrogen release temperature below $100^{\circ}C$, 3) cyclic reversibility of hydrogen absorption/desorption, 4) non toxicity and low price. Among the candidate materials, Li based metal hydrides are known to be promising materials with high practical potential in view of the above requirements. This paper reviews the characteristics and recent R&D trends of Li based complex hydrides, Li-alanates, Li-borohydrides, and Li-amides/imides.

• Transactions of the Korean hydrogen and new energy society
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• v.16 no.2
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• pp.199-207
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• 2005

Hydrogen is getting more attention owing to the seriousness of air pollution and dependance on oil import, UNCCC(United Nations Convention on Climate Change) for reducing the emission of $CO_2$. This fact is not confined in a certain country but global recognition and several countries initiated R&D competition for commercializing the hydrogen fuel cell vehicle. Within 20${\sim}$30 years cost effective hydrogen production can be possible using fossil fuels because so much research is carried out up to now. But it is so far to produce the most of the hydrogen using renewable resources considering the present status of R&D and cost effectiveness. Several automobile companies planed for mass production of hydrogen vehicle by 2010 but changed or canceled the plan owing to the difficulty of R&D and the low status of infrastructure penetration. This paper surveyed the hydrogen energy policy, R&D program and commercialization strategy of advanced country, international agency, automobile and energy company to analyze the global status of R&D and policy. And the survey of R&D program is focused on the part of hydrogen production, storage, delivery and fuel cell.