• Ecology and Resilient Infrastructure
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• 제10권4호
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• pp.107-115
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• 2023

고 탁도의 원수는 정수장 운영 및 수 생태 환경에 부정적인 영향을 줄 수 있어 관리가 필요한 수질 인자이며, 하천의 탁도 예측을 통해 고 탁도의 원수의 효율적 관리를 수행하기 위해 관련분야에 대한 연구가 지속되고 있다. 본 연구에서는 대표적인 앙상블 머신러닝 알고리즘 중 하나인 LightGBM (light gradient boosting machine)을 이용하여 탁도를 예측하는 다중 분류 모형을 구축하였다. 모형의 구축을 위해 입력자료를 탁도값에 따라 탁도가 낮은 경우부터 높은 경우까지 4개의 class로 구분하였으며, class 1 - 4에 속하는 자료수는 각각 945개, 763개, 95개, 25개로 분류되었다. 구축한 모형의 class 1 - 4에 대한 정밀도 (Precision) 각각 0.85, 0.71, 0.26, 0.30 재현율 (Recall)은 각각 0.82, 0.76, 0.19, 0.60로 데이터 수가 적은 소수 class에서 상대적으로 모형이 성능이 낮은 경향을 보였다. 데이터 불균형을 해소하기 위해 over-sampling알고리즘 중 SMOTE를 적용한 결과 개선된 모형의 class 1 - 4에 대한 정밀도 및 재현율은 각각 0.88, 0.71, 0.26, 0.25 및 0.79, 0.76, 0.38, 0.60으로 데이터 불균형 해소를 통해 모형의 재현율이 크게 개선되는 것을 확인할 수 있었다. 또한 데이터 구성비율이 모형성능에 미치는 영향에 대한 확인을 위하여 입력자료의 구성비를 다양하게 하고 각각의 자료로 구축된 모형의 결과를 비교하여 입력자료 구성비에 따른 모형성능의 차이를 분석하였으며, 모형 입력자료의 구성비의 적정한 산정을 통해 모형의 성능을 향상시킬 수 있음을 확인하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.441-441
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• 2009

Dye-sensitized solar cells (DSSCs) have been widely investigated as a next-generation solar cell because of their simple fabrication process and low coats. The cells use a porous nanocrystalline TiO2 matrix coated with a sensitizer dye that acts as the light-harvesting element. The photo-exited dye injects electrons into the $TiO_2$ particles, and the oxide dye reacts with I- in the electrolyte in regenerative cycle that is completed by the reduction of $I_3^-$ at a platinum-coated counter electrode. Since $TiO_2$ porous film plays a key role in the enhancement of photoelectric conversion efficiency of DSSC, many scientists focus their researches on it. Especially, a high light-to-electricity conversion efficiency results from particle size and crystallographic phase, film porosity, surface structure, charge and surface area to volume ratio of porous $TiO_2$ electrodes, on which the dye can be sufficiently adsorbed. Effective treatment of the photoanode is important to improve DSSC performance. In this paper, to obtain properties of surface and dispersion as nitric acid treated $TiO_2$ photoelectrode was investigate. The photovoltaic characteristics of DSSCs based the electrode fabricated by nitric acid pre-treatment $TiO_2$ materials gave better performances on both of short circuit current density and open circuit voltage. We compare dispersion of $TiO_2$ nanoparticles before and after nitric acid treatment and measured Ti oxidized state from XPS. Low charge transfer resistance was obtained in nitric acid treated sample than that of untreated sample. The dye-sensitized solar cell based on the nitric acid treatment had open-circuit voltage of 0.71 V, a short-circuit current of 15.2 mAcm-2 and an energy conversion efficiency of 6.6 % under light intensity of $100\;mWcm^{-2}$. About 14 % increases in efficiency obtained when the $TiO_2$ electrode was treated by nitric acid.

• Journal of the korean society of oceanography
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• 제31권4호
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• pp.196-206
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• 1996

Vertical profiles of the chlorophyll ${\alpha}$, phytoplankton abundance, nutrients and sigma-t were compared with the vertical distribution of phytoplankton species in conjunction with $^{14}$C primary production in the Southern Waters of the East Sea, Korea. In the upper mixed layer the water column was only weakly stratified and ambient nitrogenic nutrient concentrations were markedly depleted. Dissolved silicate seemed to be another limiting nutrient in the surface layer. The occupation of different water depths by several dominant diatom species was well explained by the degree of silicification of each cell and the silicate concentration of ambient seawater. Subsurface chlorophyll maxima were continuously observed in the lower parts of the euphotic layer and the depth coincided with nutricline, supporting our view that chlorophyll maximum was sustained partially by enhancement of in situ growth of phytoplankton and partially by increase of cellular chlorophyll content. The persistence of chlorophyll maximum layer was attributed to the physiological adaptation of the phytoplankters to low light intensities and to the utilization of regenerated nutrients. Integrated water column production of organic matter by photosynthesis appeared to be better related to phytoplankton cell division than to the cell growth in terms of biosynthesis of pigments and other intracellular components.

• ALGAE
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• 제29권3호
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• pp.217-225
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• 2014

Land-based seaweed (Gracilaria) cultivation systems may provide products with high quality and biosafety for human consumption, as well as for other high value applications. However, a limitation for this land based system is high management costs. The objective of this study was to determine if the management costs for Gracilaria cultivation can be reduced without a decrease in productivity by using $CO_2$ injection along with a high stocking density and high photosynthetically active radiation (PAR), and commercially available fertilizers. When Gracilaria tikvahiae was cultivated at a high stocking density and high PAR, coupled with $CO_2$ enhancement, the productivity was significantly higher than that at a lower stocking density, low light without $CO_2$ injection. We also found that G. tikvahiae grown in a medium of commercially available fertilizer (Jack's Special, JS) showed a similar growth rate and productivity to that grown in von Stosch's enriched (VSE) seawater, while the cost for JS media is only 2% of the cost for VSE. These results suggest that $CO_2$ injection and commercial fertilizer may be a potential way to provide sustainability in land-based Gracilaria cultivation systems.

• 수산해양기술연구
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• 제42권4호
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• pp.228-233
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• 2006

The transmittance properties of fishing lamp of the squid jigging vessel was investigated during nighttime operations in the Northwest Pacific on 21 and 29 September 2005. The metal halide lamps of white color($2.0kW{\times}168$) in the air and metal halide lamp of white color($10.0kW{\times}1$) in the underwater were used as a fishing lamp for gathering squids. The relative irradiance of metal halide lamp in the air showed peak in 850nm of wave length. The relationship between underwater illuminance(Y) and water depth(X) of metal halide lamp light in the observation areas is represented, $Y=84.137e^{-0.1105X},\;R^2=0.9974$. The distribution of underwater illuminance of measure points St. 1-5 showed low value of 0.11x in 80m depth.

• 한국분말재료학회지
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• 제21권6호
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• pp.441-446
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• 2014

In this study, we synthesize silica-core gold-satellite nanoparticles (SGNPs) for the surface-enhanced Raman scattering (SERS) based sensing applications. They consist of gold satellite nanoparticles (AuNPs) fixed on the silica core nanoparticles, which sizes of AuNPs can be tunned by varying the amount of reactants (growth solution and reducing agent). Their surface plasmon resonance (SPR) properties were characterized by using UV-vis spectroscopy, showing that the growth of AuNPs on silica cores leads to the light absorption in the longer wavelength region. Furthermore, the size increase of AuNPs exhibited the dramatic change in SERS activity due to the formation of hot spots. The optimized SGNPs showing enhancement factor ${\sim}3.8{\times}10^6$ exhibited a detection limit of rhodamine 6G (R6G) as low as $10^{-8}M$. These findings suggest the importance of size control of SGNPs and their SPR properties to develop highly efficient SERS sensors.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.149-150
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• 2006

We describe a novel method of scanning probe nanofabrication using a AFM(atomic force microscopy) tip with assistance of Femtosecond laser pulses to enhance fabrication capability. Illumination of the AFM tip with ultra-short light pulses induces a strong electric field between the tip and the metal surface, which allows removing metal atoms from the surface by means of field evaporation. Quantum simulation reveals that the field evaporation is triggered even en air when the induced electric field reaches the level of a few volts per angstrom, which is low enough to avoid unwanted thermal damages on most metal surfaces. For experimental validation, a Ti: sapphire Femtosecond pulse laser with 10 fs pulse duration at 800 nm center wavelength was used with a tip coated with gold to fabricate nanostructures on a thin film gold surface. Experimental results demonstrate that fine structures with critical dimensions less than ${\sim}10nm$ can be successfully made with precise control of the repetition rate of Femtosecond laser pulses.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.336-336
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• 2011

Over the past decades, organic semiconductors have been investigated intensely for their potential in a wide range of optoelectronic device applications since the organic materials have advantages for very light, flexible and low cost device fabrications. In this study, we fabricated small-molecule organic solar cells (OSCs) based on chloro[subphthalocyaninato]boron(III) (SubPc) as an electron donor and $C_{60}$ as an electron acceptor material. Recently SubPc, a cone-shaped molecule with $14{\pi}$-electrons in its aromatic system, has attracted growing attention in small-molecule OSC applications as an electron-donating material for its greater open-circuit voltage (VOC), extinction coefficient and dielectric constant compared to conventional planar metal phthalocyanines. In spite of the power conversion efficiency (PCE) enhancement of small-molecule OSC using SubPc and $C_{60}$, however, the study on the interface between donor-acceptor heterojunction of this system is limited. In this work, SubPc thin films at various thicknesses were deposited by organic molecular beam deposition (OMBD) and the evolution of surface morphology was observed using atomic force microscopy (AFM) and field emission scanning electron microscopy (FE-SEM). We also investigated the influence of film thickness and surface morphology on the PCE of small-molecule OSC devices.

• 한국전기전자재료학회논문지
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• 제16권9호
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• pp.812-815
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• 2003

In this study, the MgO thin-film passivation layer was adopted to protect passive matrix organic light emitting diode(PMOLED) with the cathode separator from moisture and oxygen. Using the substrate rotate and tilt technique during the deposition, the organic and cathode layers were perfectly covered with MgO. And then, we analyzed the difference of the current-voltage and luminescence characteristics between passivated OLED of the MgO and non-passivated OLED. It was found that the number of dark spot generated from the degradated pixel was decreased owing to the Mgo thin-film passivation layer using the tilt ＆ rotate technique. And the half-life time passivated OLED was improved two times more. Thus, the MgO could be vaccum-deposited under the low temperature and had a merit that the organic layer was not much affected. We can consider that MgO thin film passivation method can be adopted to protect the OLED from moisture and oxygen and can offer the enhancement of lifetime.

• 전기전자학회논문지
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• 제15권4호
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• pp.313-318
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• 2011

10 GHz 고조파 모드잠금 고리형 반도체 광섬유 레이저의 외부 CW 광주입 효과를 연구하였다. 선폭 ~ 100 KHz의 코히어런트 외부 광주입에 의해 40 dB가 넘는 스펙트럼 빗살의 골짜기와 30 dB가 넘는 슈퍼모드 비팅 잡음 억제효과를 얻을 수 있었다. 저가의 주입광원을 이용할 수 있는지를 조사하기 위해 주입광을 대략 10 MHz의 선폭을 갖는 DFB 레이저로 교체하였다. 그 결과, 스펙트럼 빗살의 골짜기는 유사한 특성을 보였으나, 슈퍼모드 비팅 잡음은 억제되기보다는 오히려 증가하는 것으로 관측되었다.