• Title/Summary/Keyword: Low $O_2$ concentration

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Boron Diffusion of Low Concentration through Poly $Poly{\cdot}Si-SiO_2$ ($Poly{\cdot}Si-SiO_2$를 통한 저농도 붕소확산)

  • Kim, Jung-Hoe;Ju, Byeong-Kwon;Kim, Chul-Ju
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.24 no.2
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    • pp.248-253
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    • 1987
  • Boron diffusion into silicon through poly\ulcorneri-SiO2 was carried out for the diffusion with low concentration using CVD-BN. The result of direct boron diffusion from BN into silicon and that of boron diffusion through SiO2 from BN into silicon was compared with the result of boron diffusion through poly-Si-SiO2 from BN into silicon. In the case of boron diffusion through poly Si-SiO2, the low concentration diffusion was obtained, that is the boron surface concentration in silicon Cs=10**16 Cm**-3, and the glassy compounds were not seen.

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Oxygen Permeability Measurement of $ZrO_2-TiO_2-YB_2O_3$ Mixed Conductor

  • Hitoshi Naito;Kim, Hitoshi ishima;Toru Takahashi;Hiroo Yugami
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.124-128
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    • 2000
  • Electrical properties of $ZrO_2-TiO_2Yb_2O_3$mixed conductor (Ti-YbSZ) were investigated. This mixed conductor can be applied as a membrane for gas separation at high temperatures. The total conductivity decreased with increasing the $TiO_2$concentration. At high temperatures, the rate of the conductivity degradation became smaller than that at low temperatures. From the oxygen partial pressure dependence of the total conductivity of Ti-YbSZ, the electronic conductivity increased with increasing $TiO_2$concentration at low oxygen partial pressures and at high temperatures. Both 15 and 20 mol% $TiO_2$doped YbSZ showed high oxygen permeability. Mixed conductors, which has high $TiO_2$concentration in YbSZ, are promising materials for using as a membrane for gas separation at high temperatures.

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Characteristics of air pollution concentration on Dongsamdong, Pusan (부산 동삼동 지역의 대기오염농도 특성)

  • 전병일
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.281-286
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    • 1999
  • This study was conduced to examine the monthly and seasonal variation of $SO_2$, TSP, $O_3$ concentration in Dongsamdong, Pusan coastal area. And the characteristics of air pollution of this area was compared to Kwangbokdong in Pusan and Taehadong in Ullungdo. Monthly mean concentration of $SO_2$ and TSP showed lower than Kwangbokdong, $O_3$ was higher than Kwangbokdong. In case of $SO_2$, seasonal variation of Dongsamdong was remarkabler thn Kwangbokdong and the concentration difference of early morning and daytime was higher than Kwangbokdong. Taehadong showed very lower concentration as background area. In case of TSP, Dongsamdong was lower concentration and smaller diurnal change than Kwangbokdong, Taehadong showed very lower concentration as backgound area. In case of $O_3$, Dongsamdong was 10ppb higher than Kwangbokdong at daytime maximum concentration, diurnal change of concentration was higher, too. In case of frequency distribution of concentration, $SO_2$, and TSP at Dongsamdong showed higher frequency in low concentration class and $O_3$ showed in high concentration class as compared with Kwangbokdong.

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On-line Measurement of $H_2$O/LiBr Concentration using Electric Conductivity (전기 전도도를 이용한 $H_2$O/LiBr 용액의 실시간 농도의 측정)

  • 박찬우;김정환;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.12
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    • pp.1078-1083
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    • 2002
  • The objectives of this paper are to measure the concentration of $H_2$O/LiBr solution by measuring the electrical conductivity and to study the effect of the solution temperature and the concentration on the electrical conductivity of the solution. The solution temperature ranges $20^{\circ},\;40^{\circ},\;and\; 60^{\circ}$ for a fixed concentration during the experiment. The valid ranges of the concentration are two regions, low concentration region (1~20% of LiBr) and high concentration region (55~66% of LiBr). The results show that the conductivity of the solution increases linearly with increasing the solution temperature while it increases without creasing the concentration lower than about 35% of LiBr and decreases with increasing the concentration higher than 35%. This paper proposes experimental correlations for the concentration as functions of the solution temperature and the concentration with error band of $\pm7$% for the low concentration region and $\pm1$% for the high concentration region, respectively. The experimental correlation can be practically used in the on-line measurement without any sampling of solution from the closed system.

Characteristics of Phenol Degradation by using UV/TiO2 Photocatalysis (UV/TiO2 광촉매반응에 의한 페놀의 분해 특성)

  • Shin, In-Soo;Choi, Bong-long;Lee, Seung-Mok
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.488-493
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    • 2004
  • The effects were examined from several conditions of $TiO_2$ photocatalysis reaction to phenols degradation by changing it's reacting conditions such as phenol concentration, pH, $TiO_2$ concentration, $H_2O_2$ concentration, flow rate, and intensity of ultraviolet rays. Phenol degradation was more efficient in low concentration of phenol, neutral pH. Phenol degradation appeared to increase as concentration of $TiO_2$ photocatalyst, that of $H_2O_2$ and intensity of ultraviolet rays increased. As $TiO_2$ dosage increased, initial rate constant k linearly increased. When $H_2O_2$ was injected more than optimum, phenol removal rate didn't increase in proportional to the change of $H_2O_2$ concentration as OH radicals was being consumed. When flow rate is less than $4.75m^3/m^2$ day, phenol removal efficiency appeared to decrease as ultraviolet rays transmission rate becomes low by $TiO_2$ suspension coated in photo reaction column. Meanwhile, initial rate constant according to light intensity change in less than $25mW/cm^2$ appeared to be in proportion to light intensity ($mW/cm^2$) Removal efficiency decreased about 12% after 180 minutes of reaction time while showed stable removal efficiency of 100% after 300 minutes when using regenerated $TiO_2$.

Effects of dynamic oxygen concentrations on the development of mouse pre- and peri-implantation embryos using a double-channel gas supply incubator system

  • Lee, Seung-Chan;Seo, Ho-Chul;Lee, Jaewang;Jun, Jin Hyun;Choi, Kyoo Wan
    • Clinical and Experimental Reproductive Medicine
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    • v.46 no.4
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    • pp.189-196
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    • 2019
  • Objective: We aimed to evaluate the effects of different oxygen conditions (20% [high O2], 5% [low O2] and 5% decreased to 2% [dynamic O2]) on mouse pre- and peri-implantation development using a novel double-channel gas supply (DCGS) incubator (CNC Biotech Inc.) to alter the oxygen concentration during in vitro culture. Methods: The high-O2 and low-O2 groups were cultured from the one-cell to the blastocyst stage under 20% and 5% oxygen concentrations, respectively. In the dynamic-O2 group, mouse embryos were cultured from the one-cell to the morula stage under 5% O2 for 3 days, followed by culture under 2% O2 to the blastocyst stage. To evaluate peri-implantation development, the blastocysts from the three groups were individually transferred to a fibronectin-coated dish and cultured to the outgrowth stage in droplets. Results: The blastocyst formation rate was significantly higher in the low-O2 and dynamic-O2 groups than in the high-O2 group. The total cell number was significantly higher in the dynamic-O2 group than in the low-O2 and high-O2 groups. Additionally, the apoptotic index was significantly lower in the low-O2 and dynamic-O2 groups than in the high-O2 group. The trophoblast outgrowth rate and spread area were significantly higher in the low-O2 and dynamic-O2 groups than in the high-O2 group. Conclusion: Our results showed that a dynamic oxygen concentration (decreasing from 5% to 2%) had beneficial effects on mouse pre- and peri-implantation development. Optimized, dynamic changing of oxygen concentrations using the novel DCGS incubator could improve the developmental competence of in vitro cultured embryos in a human in vitro fertilization and embryo transfer program.

Effect of Deposition Parameters on the Morphology and Electrochemical Behavior of Lead Dioxide

  • Hossain, Md Delowar;Mustafa, Chand Mohammad;Islam, Md Mayeedul
    • Journal of Electrochemical Science and Technology
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    • v.8 no.3
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    • pp.197-205
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    • 2017
  • Lead dioxide thin films were electrodeposited on nickel substrate from acidic lead nitrate solution. Current efficiency and thickness measurements, cyclic voltammetry, AFM, SEM, and X-ray diffraction experiments were conducted on $PbO_2$ surface to elucidate the effect of lead nitrate concentration, current density, temperature on the morphology, chemical behavior, and crystal structure. Experimental results showed that deposition efficiency was affected by the current density and solution concentration. The film thickness was independent of current density when deposition from high $Pb(NO_3)_2$ concentration, while it decreased for low concentration and high current density deposition. On the other hand, deposition temperature had negative effect on current efficiency more for lower current density deposition. Cyclic voltammetric study revealed that comparatively more ${\beta}-PbO_2$ produced compact deposits when deposition was carried out from high $Pb(NO_3)_2$ concentration. Such compact films gave lower charge discharge current density during cycling. SEM and AFM studies showed that deposition of regular-size sharp-edge grains occurred for all deposition conditions. The grain size for high temperature and low concentration $Pb(NO_3)_2$ deposition was bigger than from low temperature and high concentration deposition conditions. While cycling converted all grains into loosely adhered flappy deposit with numerous pores. X-ray diffraction measurement indicates that high concentration, high temperature, and high current density favored ${\beta}-PbO_2$ deposition while ${\alpha}-PbO_2$ converted to ${\beta}-PbO_2$ together with some unconverted $PbSO_4$ during cycling in $H_2SO_4$.

Effective Thermal Conductivities $Al_2O_3$ Nanoparticles Suspended in Water with Low Concentration (1%미만의 부피비를 가지는 알루미나 나노유체의 유효 열전도도)

  • Lee, Byeong-Ho;Kim, Jun-Ho;Kong, Yu-Chan;Jang, Seok-Pil;Koo, Ja-Ye
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2177-2181
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    • 2007
  • In this paper, effective thermal conductivities of water-based $Al_2O_3$-nanofluids with low concentration from 0.01 vol. % to 0.3 vol. % are experimentally obtained by transient hot wire method (THWM). The water-based $Al_2O_3$-nanofluids are manufactured by two-step method which is widely used. To examine suspension and dispersion characteristics of the water-based $Al_2O_3$-nanofluids, Zeta potential as well as transmission electron micrograph (TEM) is observed. We confirm the manufactured $Al_2O_3$-nanofluids have good suspension and dispersion. The effective thermal conductivities of the water-based $Al_2O_3$-nanofluids with low concentration are enhanced up to 1.64% compared with that of DI water at $21^{\circ}C$. In addition, experimental results are compared with theoretical results from Jang and Choi model.

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Effects of Reactive Oxygen Species on Motility in Human Spermatozoa (반응성 산소족이 사람 정자의 운동성에 미치는 영향)

  • Kang, Hee-Gyoo;Kim, Dong-Hoon;Han, Sung-Won;Kim, Myo-Kyung;Kwon, Hyuck-Chan;Lee, Ho-Joon;Kim, Moon-Kyoo
    • Clinical and Experimental Reproductive Medicine
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    • v.27 no.4
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    • pp.393-403
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    • 2000
  • Objective: To investigate the effects of ROS on kinematic parameters in human spermatozoa. To verify the changes in above parameters, human spermatozoa were incubated with xanthine-xanthine oxidase (X-XO), $H_2O_2$, sodium nitroprusside (SNP) or lymphocyte. Otherwise, spemlatozoa were incubated under low $O_2 (5%) condition. Methods: CASA was employed to analyze sperm motion parameters. Results: Under $H_2O_2 treatment, all kinematic parameters of spermatozoa were dramatically increased during 30 min, but gradually decreased thereafter. Under the low concentration of $H_2O_2 (125 ${\mu}M$ and 250 ${\mu}M$), the movement velocity (VAP, VCL, VSL) decreased, but forward movement increased. Under the 1mM $H_2O_2, sperm showed reduced kinematic parameters except during first 30 min of incubation. In the cases of X-XO and SNP treatment, the movement velocity increased but the forward movement reduced. After incubation for 3 hr treatment, the kinematic parameters gradually decreased in high concentration of X-XO. However these parameters maintained or increased in low concentration of X-XO. There was no obvious changes in the above parameters in the high concentration of SNP. In the presence of high concentration of lymphocytes, all parameters decreased. Under the 5% $O_2 condition, the parameters of the movement velocity and movement pattern increased, but forward movement decreased. Taken togethers, it suggested that ROS increased the movement velocity but decreased the forward movement and lateral head replacement. $H_2O_2, X-XO, SNP and lymphocyte treatment significantly increased capacitated spermatozoa within I h of incubation. There was no significant difference in capacitation between low- and high $O_2 group. Conclusion: The early onset of capacitation in the presence of ROS suggest that ROS might be a positive regulator of sperm capacitation and hyperactivation. These results demonstrate that low concentration ROS facilitates the movement velocity but high concentration ROS was inhibitory.

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Effect of KHCO3 Concentration Using CuO Nanowire for Electrochemical CO2 Reduction Reaction

  • Kanase, Rohini Subhash;Kang, Soon Hyung
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.11-17
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    • 2020
  • Copper has been proved to be the best catalyst for electrochemical CO2 reduction reaction, however, for optimal efficiency and selectivity, its performance requires improvements. Electrochemical CO2 reduction reaction (RR) using CuO nanowire electrode was performed with different concentrations of KHCO3 electrolyte (0.1 M, 0.5 M, and 1 M). Cu(OH)2 was formed on Cu foil, followed by thermal-treatment at 200℃ under the air atmosphere for 2 hrs to transform it to the crystalline phase of CuO. We evaluated the effects of different KHCO3 electrolyte concentrations on electrochemical CO2 reduction reaction (RR) using the CuO nanowire electrode. At a constant current (5mA), low concentrated bicarbonate exhibited a more negative potential -0.77 V vs. Reversible Hydrogen Electrode (RHE) (briefly abbreviated as VRHE), while the negative potential reduced to -0.33 VRHE in the high concentration of bicarbonate solution. Production of H2 and CH4 increased with an increased concentration of electrolyte (KHCO3). CH4 production efficiency was high at low negative potential whereas HCOOH was not influenced by bicarbonate concentration. Our study provides insights into efficient, economically viable, and sustainable methods of mitigating the harmful environmental effects of CO2 emission.