• Title/Summary/Keyword: Local oxidation

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A Study on Laser Assisted Machining for Silicon Nitride Ceramics (IV) - Mechanism and Application of LAM for Silicon Nitride Ceramics - (질화규소 세라믹의 레이저 예열선삭에 관한 연구 (IV) - 질화규소 세라믹의 레이저예열선삭 메커니즘 및 적용 -)

  • Kim, Jong-Do;Lee, Su-Jin;Park, Seo-Jeong;Lee, Jae-Hoon
    • Journal of Welding and Joining
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    • v.28 no.6
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    • pp.40-44
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    • 2010
  • Laser assisted machining (LAM) has been researched in order to machine the silicon nitride ceramics economically and effectively. LAM is an effective machining method by local heating of the cutting part to the softening temperature of the silicon nitride using laser beam. When silicon nitride ceramics is heated using a laser beam, the surface of silicon nitride ceramic is softened, oxidized and decomposed. And then surface hardness is decreased. Through machining in low viscosity and hardness conditions, silicon nitride was machined effectively and the life span of tool was increased. The plastic deformation was occurred due to softening of amorphous YSiAlON above $ 1,000^{\circ}C$. Transgranular fracture of ${\beta}-Si_3N_4$ was occurred when YSiAlON was not softened, but mostly intergranular fracture was occurred by the plastic deformation of softened YSiAlON.

Chlorine Effect on Thermal Aging Behaviors of BR and CR Composites

  • Choi, Sung-Seen;Kim, Jong-Chul
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2613-2617
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    • 2010
  • Chloroprene is a chlorine substituent of 1,3-butadiene. Butadiene rubber (BR) and chloroprene rubber (CR) composites were thermally aged at 60, 70, 80, and $90^{\circ}C$ for 2 - 185 days in a convection oven and changes of the crosslink densities by the accelerated thermal aging were investigated. The crosslink densities increased as the aging time elapsed and as the aging temperature became higher. Degrees of the crosslink density changes of the BR composite were on the whole larger than those of the CR one except the short-term thermal aging at 60 and $70^{\circ}C$. The crosslink densities abnormally increased after themal aging at high temperatures for a long time. Activation energies for the crosslink density changes of the rubber composites tended to increase with increase of the aging time and the variation showed a local minimum. The activation energies of the CR composite were lower than those of the BR one. The experimental results were explained with a role of ligand of chlorine atom of CR in a zinc complex, steric hindrance by chlorine atom of CR, and oxidation of rubber chain.

CORROSION BEHAVIOR OF NI-BASE ALLOYS IN SUPERCRITICAL WATER

  • Zhang, Qiang;Tang, Rui;Li, Cong;Luo, Xin;Long, Chongsheng;Yin, Kaiju
    • Nuclear Engineering and Technology
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    • v.41 no.1
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    • pp.107-112
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    • 2009
  • Corrosion of nickel-base alloys (Hastelloy C-276, Inconel 625, and Inconel X-750) in $500^{\circ}C$, 25MPa supercritical water (with 10 wppb oxygen) was investigated to evaluate the suitability of these alloys for use in supercritical water reactors. Oxide scales formed on the samples were characterized by gravimetry, scanning electron microscopy/energy dispersive spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The results indicate that, during the 1000h exposure, a dense spinel oxide layer, mainly consisting of a fine Cr-rich inner layer ($NiCr_{2}O_{4}$) underneath a coarse Fe-rich outer layer ($NiFe_{2}O_{4}$), developed on each alloy. Besides general corrosion, nodular corrosion occurred on alloy 625 possibly resulting from local attack of ${\gamma}$" clusters in the matrix. The mass gains for all alloys were small, while alloy X -750 exhibited the highest oxidation rate, probably due to the absence of Mo.

Methylene Blue (메틸렌 블루)

  • You, Ji-Young
    • Journal of The Korean Society of Clinical Toxicology
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    • v.8 no.1
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    • pp.1-6
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    • 2010
  • Methylene blue is a very effective reducer of drug-induced methemoglobinemia. It has dose-dependent oxidation or reduction properties. In most cases, a dose of 1 to 2 mg/kg IV given over 5 minutes and immediately followed by a 15- to 30-mL fluid flush to minimize the local pain is both effective and relatively safe. The onset of action is quite rapid, and the effects are usually seen within 30 minutes. The dose may be repeated after 30 to 60 minutes and then every 2 to 4 hours as needed. The total dose should not exceed 7 mg/kg as a single dose or 15 mg/kg within 24 hours. Repeated treatment may be needed for treating compounds that have prolonged elimination or those compounds that undergo enterohepatic recirculation (e.g., dapsone). Methylene blue can cause dose-related toxicity. At high doses, methylene blue can also induce an acute hemolytic anemia and rebound methemoglobinemia. The reasons for treatment failure with methylene blue include ineffective GI decontamination, the existence of other forms of hemoglobin (e.g., sulfhemoglobin), a low or high dose of methylene blue and the toxicokinetics of some agents, such as aniline, benzocaine or dapsone.

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Influence of Driving Pattern on Regeneration Performance of Continuously Regenerating Diesel Particulate Filter (연속재생 DPF의 재생 성능에 미치는 차량 운행패턴의 영향)

  • Hwang, Jin-Woo;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.5
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    • pp.358-364
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    • 2009
  • This paper is to investigate the influence of driving patterns of slow and high speed vehicles on the performance of continuously regenerating diesel particulate filter(DPF) system matched with operating conditions in field application. The DPF performance test for field application was carried out for two identical DPFs installed to slow and high speed vehicles. A slow speed vehicle was selected among local buses which have driving patterns to repeat running and stop frequently, while a high speed vehicle was prepared to have long route of high speed over 60km/h like inter-city buses. In this test, the regeneration performance on the DPF of slow speed vehicle deteriorated because of high soot load index(SLI) in spite of same balance point temperature(BPT) distribution for high speed vehicle. The DPF of slow speed vehicle melted in the end because the rapid increase of back pressure caused high temperature over $1200^{\circ}C$ in the ceramic wall of DPF. The PM components like ash collected to the filter in the DPF were analyzed in order to investigate the cause of the defect and provide an operation performance of DPF system. In the result of the analysis, high levels of lubrication oil ash(Ca, Mg, P, Zn) were detected.

Aging Effect of Magnetic Properties in Amorphous $Fe_{78}B_{13}Si_9$ Alloy (비정질 $Fe_{78}B_{13}Si_9$ 합금의 자기적 특성의 경년 열화)

  • Kim, Ki-Uk;Min, Bog-Ki;Song, Jae-Sung;Hong, Jin-Wan;Cho, Hyun-Jin;Lee, Dong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.05a
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    • pp.49-51
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    • 1988
  • The heat treatment condition and aging behavior of melt spun amorphous $Fe_{78}B_{13}Si_9$(Metglas 26058-2) were studied with investigating its magnetic properties, i.e., Br, $B_l$, Hc. The optimum heat treatment condition was $400^{\circ}C$, 1 hour under the external field of 200e, and aging was due to the surface oxidation and the appearance of local CSRO (chemical short lange order) with time and temperature. In addition. we investigated the effects of the thickness of the amorphous ribbons on the magnetic properties and aging effect of them.

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Electrical characteristics of lateral poly0silicon field emission triode using LOCOS process

  • Lee, Jae-Hoon;Lee, Myoung-Bok;Park, Dong-Il;Ham, Sung-Ho;Lee, Jong-Hyun;Lee, Jung-Hee
    • Journal of Korean Vacuum Science & Technology
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    • v.3 no.1
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    • pp.38-42
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    • 1999
  • Using the LOCOS process, we have fabricated the lateral type polysilicon field emission triodes with poly-Si/oxide/Si structure and investigated their current-voltage characteristics for three biasing modes of operation. The fabricated devices exhibit excellent electrical performances such as a relatively low turn-on anode voltage of 14 V at VGC = 0V, a stable and high emission current of 92${\mu}$A/triode over 90 hours, a small gate leakage current of 0.23 ${\mu}$A/triode and an outstanding transconductance of 57${\mu}$S/5triodes at VGC = 5V and VAC = 26V. these superior electrical operation is believed to be due to a large field enhancement effect, which is related to the sharp cathode tips produced by the LOCOS process as well as the high aspect ratio (height /radius ) of the cathode tip end.

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Corrosion Behavior of Ni 200 and Ni-base Alloys in Hot Lithium Molten salt (고온 리튬용융염에서 Ni 200 및 Ni-base 합금의 부식거동)

  • Cho Soo-Hang;Lim Jong-Ho;Yun Ki-Seok;Park Seung-Won
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.251-259
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    • 2004
  • In the development of the advanced spent fuel management process based on the molten salt technology, it is essential to choose the optimum material for the process equipment handling molten salt. Corrosion behavior of Ni 200 and Ni-base alloys in molten salt of LiCl-$Li_2$O under oxidation atmosphere was investigated in the temperature range of $650~800^{\circ}C$ for 24~312 hrs. The order of corrosion rate was Ni 200 > Inconel 690 > Inconel 601 > Inconel 600. Inconel 600 alloy showed the highest corrosion resistance among the examined alloys, but Ni 200 exhibited the highest corrosion rate. Corrosion products of Inconel 600 and Inconel 601 were $Cr_2$$O_3$ and $NiFe_2$$O_4$. In case of Inconel 690, a single layer of $CrO_2$$O_3$ was formed in the early stage of corrosion and an outer layer of $NiFe_2$O$_4$ and inner layer of $Cr_2$$O_3$ were formed with increase of corrosion time. Inconel 600 showed local corrosion behavior and Inconel 601, 690 showed uniform corrosion behavior.

The Effect of Lidocaine and Procainamide on the Hepatic Aldehyde Oxidase Activity (알데히드 옥시다제의 활성에 미치는 리도카인 및 프로카인아미드의 영향)

  • Huh, Keun;Kim, Jin-Sook;Jin, Da-Qing;Ha, Eun-Pil;Lee, Sang-Il;Yong, Chul-Soon
    • YAKHAK HOEJI
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    • v.43 no.6
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    • pp.756-761
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    • 1999
  • Lipid peroxidation mediated by hydroxyl radicals which are generated during myocardial ischermia has suggested as a possible mechanism of ischemic myocardial damage. Recently, it has been reported that anti-arrhythmic action of lidocaine, a local anesthetic, is attributed to its "membrane-stabilizing" properties through scavenging free radicals, thus, inhibiting lipid peroxidation. Aldehyde oxidase and xanthine oxidase which catalyze the oxidation of many purine, pyrimidine and pteridine derivatives are known as free radical generating systems. In this experiment, we studied the effect of lidocaine and procainamide on the hepatic aldehyde and xanthine oxidase activity and antioxidative activities. It was found that lidocaine and procainamide inhibited both NADPH-dependent and independent lipid peroxidation. Both of tested compounds were found to be ineffective in inhibiting xanthine oxidase. Lidocaine and procainamide, however, inhibited aldehyde oxidase activity in vitro as well as in vivo. Based on the above results, lidocaine and procainamide could be employed as a therapeutic agent for aldehyde oxidaserelated disease.d disease.

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The Technology of Sloped Wall SWAMI for VLSI and Analysis of Leakage Current (고집적 회로를 위한 경사면 SWAMI 기술과 누설전류 분석)

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    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.15 no.3
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    • pp.252-259
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    • 1990
  • This paper present new scheme for a Side Wall Masked Isolation(SWAMI) technology which take all the advatages provided by conventional LOCOS process. A new SWAMI process incorporates a sloped sidewall by reactive ion etch and a layer of thin nitride around the side walls such that both intrinsic nitride stress and volume expansion induced stress are greatly reduced. As a fabricate results, a defect-free fully recessed zero bird's beak local oxidation process can be realized by the sloped wall anisotropic oxide isolation. No additional masking step is required. The leakage current of PN diodes of this process were reduced than PN diode of conventional LOCOS process. On the other hand, the edge junction part was larger than the flat juction part in the density of leakage current.

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