• Proceedings of the KIPE Conference
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• 2017.07a
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• pp.453-454
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• 2017

본 논문에서는 환경 시험 중 한가지 방법인 진동 시험(Vibration test) 프로파일을 적용하여 고출력 리튬이온18650 셀(cell)에 물리적인 진동을 가하고 진동 시험 전 후 고출력 리튬이온 18650 셀의 전기적 특성 기반 내부 파라미터를 추출하였다. 통계적 기법인 상관 관계 및 대응 표본 t 검정을 적용하여 내부 파라미터인 방전 용량(discharged capacity), 방전 저항(discharged resistance), OCV(open circuit voltage) 간의 관계 및 변화를 비교 분석하였다.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.6
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• pp.608-614
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• 2004

The gel polymer electrolyte was prepared by radical polymerization using tetra(ethylene glycol) diacrylate and tri(ethylene glycol) dimethacrylate to investigate affect of the number of ethylene oxide. The gel polymer electrolyte showed good electrochemical stability up to 4.5 V vs. Li/Li and high ionic conductivity at various temperatures. The lithium-ion polymer batteries with the gel polymer electrolyte, tetra(ethylene glycol) diacrylate- and tri(ethylene glycol) dimethacrylate-based, also represented good electrochemical performances such as rate capability, low-temperature performances and cycleability. However, the cell with tri(ethylene glycol) dimethacrylate, which has three ethylene oxide, showed better electrochemical performance.

• Journal of the Korean Chemical Society
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• v.67 no.3
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• pp.165-174
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• 2023

The development of all-solid-state batteries (ASSBs) has been gaining attention in recent years due to their potential to offer higher energy densities, improved safety, and longer cycle life compared to conventional lithium-ion batteries. However, several challenges must be addressed to achieve the practical application of ASSBs, such as the development of high-performance solid-state electrolytes, stable electrode-electrolyte interfaces, and cost-effective manufacturing processes. In this review paper, we present an overview of the current state of ASSB research, including recent progress in solid-state electrolyte and cathode/anode materials, and cell architecture. We also summarize the recent advancements and highlight the remaining challenges in ASSB research, with an outlook on the future of this promising technology.

• Journal of Satellite, Information and Communications
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• v.8 no.3
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• pp.15-19
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• 2013

Lithium-ion batteries have been used for high density energy storage system due to the features such as low self-discharge rate. And the unit cell battery with the voltage less than 4V is recommended to use the series connections for a high voltage charger. When batteries are charged or discharged with series connection, there may be an explosion or degradation of unit cell battery owing to undistributed internal resistance of cell battery. therefore, the voltages of unit cell batteries should be monitored to prevent an overcharging and a deep discharging. This paper introduces the implementation of CVM (Cell Voltage Monitoring) system that can transmit the 12 channel's information including voltages and temperatures with the 12-bits resolutions and the transmission speed of 192 kbps.

• Journal of the Korean Electrochemical Society
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• v.17 no.1
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• pp.49-56
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• 2014

As an electrolyte additive, the effects of lithium bis(oxalate)borate (LiBOB) on the electrochemical properties of a carbon-coated silicon monoxide (C-coated SiO) negative electrode are investigated. The used electrolyte is 1.3M $LiPF_6$ that is dissolved in ethylene carbonate (EC), fluoroethylene carbonate (FEC), and diethyl carbonate (DEC) (5:25:70 v/v/v) with or without 0.5 wt. % LiBOB. In the LiBOB-free electrolyte, the film resistance is not so high in the initial period of cycling that lithiation is facilitated to generate the crystalline $Li_{15}Si_4$ phase. Due to repeated volume change that is caused by such a deep charge/discharge, cracks form in the active material to cause a resistance increase, which eventually leads to capacity fading. When LiBOB is added into the electrolyte, however, more resistive surface film is generated by decomposition of LiBOB in the initial period. The crystalline $Li_{15}Si_4$ phase does not form, such that the volume change and crack formation are greatly mitigated. Consequently, the C-coated SiO electrode exhibits a better cycle performance in the later cycles. At an elevated temperature ($45^{\circ}C$), wherein the effect of film resistance is less critical, the alloy ($Li_{15}Si_4$ phase) formation is comparable for the LiBOB-free and added cell to give a similar cycle performance.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1993.05a
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• pp.79-84
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• 1993

This paper describes the development of lithium rechargeable cell. $LiCoO_2$ is recently recognized as a suitable cathode active material of a high voltage, high energy lithium rechargeable batteries because $Li^+$ ion can be electrochemically deintercalated/intercalated from/to $Li_xCoO_2$. The transition metal oxide of $LiCoO_2$ was investigated for using as a cathode active material of 4V class Li rechargeable cell. $LiCoO_2$ cathode was prepared by using a active material of 85 wt%, graphite powder of 12 wt% as a conductor and poly-vinylidene fluoride of 3 wt% as a binder. The electrochemical and charge/discharge properties of $LiCoO_2$ were investigated by cyclic voltammetry and galvanostatic charge/discharge. The open circuit voltage of prepared $LiCoO_2$ electrode exhibited approximately. potential range between 3.32V and 3.42V. During the galvanostatic charge/discharge, $LiCoO_2/Li$ cell showed stable cycling behavior at scan rate of 1mV/sec and potential range between 3.6V and 4.2V. Also its coulombic efficiency as function of cycling was 81%~102%. In this study the $LiCoO_2/Li$ cell showed the available discharge capacity of 90.1 mAh/g at current density of $1mA/cm^2$ and cell discharge voltage range between 3.6V~4.2V.

• Korean Journal of Materials Research
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• v.20 no.12
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• pp.669-675
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• 2010

One of the greatest challenges for our society is providing powerful electrochemical energy conversion and storage devices. Rechargeable lithium-ion batteries and fuel cells are among the most promising candidates in terms of energy and power density. As the starting material, $TiCl_4{\cdot}YCl_3$ solution and dispersing agent (HCP) were mixed and synthesized using ammonia as the precipitation agent, in order to prepare the nano size Y doped spherical $TiO_2$ precursor. Then, the $Li_4Ti_5O_{12}$ was synthesized using solid state reaction method through the stoichiometric mixture of Y doped spherical $TiO_2$ precursor and LiOH. The Ti mole increased the concentration of the spherical particle size due to the addition of HPC with a similar particle size distribution in a well in which $Li_4Ti_5O_{12}$ spherical particles could be obtained. The optimal synthesis conditions and the molar ratio of the Ti 0.05 mol reaction at $50^{\circ}C$ for 30 minutes and at $850^{\circ}C$ for 6 hours heat treatment time were optimized. $Li_4Ti_5O_{12}$ was prepared by the above conditions as a working electrode after generating the Coin cell; then, electrochemical properties were evaluated when the voltage range of 1.5V was flat, the initial capacity was 141 mAh/g, and cycle retention rate was 86%; also, redox reactions between 1.5 and 1.7V, which arose from the insertion and deintercalation of 0.005 mole of Y doping is not a case of doping because the C-rate characteristics were significantly better.

• Journal of the Korean Ceramic Society
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• v.50 no.2
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• pp.168-172
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• 2013

This work presents the effects of binders on the electrochemical performance of Si-C composites as the anode of lithium ion batteries. PAI (polyamide-imide) was used as an organic binder, and PAN (polyacrylonitrile), PAA (polyacrylic acid) and CMC + SBR (carboxymethyl cellulose + styrene-butadiene rubber) were used as aqueous binders. As a result, stabilization time for the cell with a Si-C composite anode synthesized using aqueous binders became shorter than an organic binder. Particularly in the case of the cell using PAA binder, better performance was observed in terms of adhesion strength, initial efficiency, the volume expansion ratio, Coulombic efficiency, and capacity retention.

• Journal of IKEEE
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• v.24 no.1
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• pp.333-338
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• 2020

This paper proposes a method of estimating the SOC(State of Charge) of a battery cell using a neural network algorithm. To this, we implement a battery SOC estimation simulator and derive input and output data for neural network learning through charge and discharge experiments at various temperatures. Finally, the performance of the battery SOC estimation is analyzed by comparing with the experimental value by Ah-counting using Matlab/Simulink program and confirmed that the error rate can be reduced to less than 3%.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.7
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• pp.515-520
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• 2018

A large number of lithium-ion batteries are arranged in series and parallel in battery packs, such as those in electric vehicles or energy storage systems. As battery packs age, their output power and energy density drop because of voltage deviation, constant and non-uniform exposure to abnormal environments, and increased contact resistance between batteries; this reduces application system efficiency. Despite the balancing circuit and logic of the battery management system, the output of the battery pack is concentrated in the most severely aged unit cell and the output is frequently limited by power derating. In this study, we implemented a cell imbalance detection algorithm and selected parameters to detect a sudden decrease in battery pack output. In addition, we propose a method to increase efficiency by applying the measured testing values considering the operating conditions and abnormal conditions of the battery pack.