• Journal of the Korean Society of Safety
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• v.20 no.3 s.71
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• pp.71-77
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• 2005

This study aims to find the safe vent area to prevent a destruction of building by gas explosion in a building. Explosion vessel which used in this experiment is 1/5 scale down model of simple livingroom and its dimension is 100cm in length 60cm in width and 45cm in height. Liquified petroleum gas(LPG) was injected to the vessel to the concentration of 4.5vol%, and injection rate were varied in 1L/min or 4L/min. Gas mixture was ignited by the 10kV electric spark. For analysis the characteristics of vented explosion pressure according to the vent size and vent shape, its size and shape were varied. From the experiment, it was found that explosion pressure in the vented explosion :in affected by the gas injection rate, vent area and vent shape. And the vent area to volume ratio(S/V) to prevent the building destruction by explosion pressure, it is recommended that the design of vent area happened by the explosion should be above 1/500cm in S/V. And if the vent area has complicate structure in same area, vented explosion pressure will be higher than a single vent, and possibility of building destruction will increase. Therefore to effectively vent the explosion pressure for protect a building and residents from the gas explosion hazards, the same vent area should have a singular and constant shape in the cross-sectional area of the vessel.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.328-333
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• 2012

In this study, CFD simulation was performed with commercial CFD code FLUENT for the 3D mixing tank model (1 m in a diameter and 2.5 m in a height) of DME-Propane liquified fuels. Initial condition set-up with existence of DME 146 l at the upper side of mixing tank and Propane 770 l at the lower side of mixing tank. Characteristics of mixture and fluid flow were observed for 34 hours simulation. Two liquid fuel were uniformly mixed within range of 3 mol% after 24 hours, and range of 1 mol% after 34 hours. The simulation result following 4 hours was verified with KOGAS experimental data.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.1
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• pp.108-121
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• 1998

Using gas chromatography, the light hydrocarbon emissions were analyzed from SI engine fueled with methane and liquified petroleum gas(LPG), and the effects of fuel and engine operating condition were discussed. For this purpose, 14 species of light hydrocarbon including 1, 3-butadiene were separated, calibrated with standard gas, and measured from undiluted emissions. The brake specific hydrocarbon emission(BSHC) and ozone forming potential(BSO)3 were calculated and discussed with the changes of fuel, engine speed, load, fuel/air equivalence ratio, coolant temperature, and spark timing. As a result, exhaust emission was composed of mainly fuel composed of mainly fuel comp- onent and other olefin components of similar carbon number. The olefin components such as ethylene and propylene determine most of the ozone forming potential. The fraction of fuel component in total hydrocarbon emission was bigger with methane fuel than with LPG fuel. Also fuel fraction increased at high speed or high speed or high temperature of exhaust gas, and to lesser extent with high coolant temperature and retarded spark. However, the effect of equivalence ratio had different tendency according to fuels.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.1637-1641
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• 2003

Korea Gas Corporation(KOGAS) is a Liquified Natural Gas(LNG) supplier through out the Korea. LNG, which is imported wholly from foreign countries, is compressed 1/600 for easy transportation and is stored in a liquid state in the storage tanks at Incheon, Pyeongtaek and Tongyeong. At LNG receiving terminals, LNG is vaporized to natural gas before supplying to City Gas Consumer of Power Plant. The secondary pump is a equipment which compress LNG from 1- kgf/cm2 to 70 kgf/cm2. The secondary pump at Tongyeong LNG receiving terminal is consisted of two pumps in one underground PIT, and is connected to supporting structures. It is therefore expected that there is a vibration problem whit the pump and was found that high level vibration was occurred in a low frequency band($5^{\sim}10Hz$). In this paper, the vibration of secondary pump was analyzed, and the main cause of vibration was found out.

• Journal of the Korean Chemical Society
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• v.7 no.2
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• pp.128-132
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• 1963

A study has been made on the applicability of gas-liquid partition chromatography to the qualitative and quantitative analysis of complex mixture of gaseous hydrocarbons. While phthalate columns are widely used for this $purpose^9$, they separates neither saturated hydrocarbons from the unsaturated nor n-butane from isobutene or butene-1, therefore combined columns such as phthalate and dimethylsulfolane have been used for the perfect separation of gaseous hydrocarbons. It is shown by this study, however, that hydrocarbons having $C_1$ through $C_4$ can be separated with a 2-meters tetraethyleneglycol dimethylether column except ethane from ethylene, and trans-from cis-2-butene especially operated at $15^{\circ}C$$ using helium as the carrier gas. The column effluents were in order of methane, (ethane, ethylene), propane, propylene, isobutane, n-butane, isobutylene, butene-1, (trans-& cis-2-butene, isopentane), (butadiene-1, 3, n-pentane). Two kinds of liquified petroleum gases in market are analysed qualitatively and quantitatively. The results indicate that use of this 2-meters TEGDE column permits the separation and identification of all the commonly encountered aliphatic gaseous hydrocarbons.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.686-686
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• 2009

가스하이드레이트는 수소결합을 하는 물분자의 고체상 격자(Lattice)내에 포집되어 들어가는 기체분자로 구성된 결정화합물로서 외형적인 형태는 얼음과 거의 유사하다. 천연가스 하이드레이트 기술의 최대장점으로는 액화천연가스(LNG)는 초저온인 $-162^{\circ}C$의 저장조건이 필요하지만 천연가스하이드레이트(NGH)기술은 비교적 온화한 조건인 $-15^{\circ}C$에서 천연가스를 고체상태로 저장/이용할 수 있다는 것이다. 천연가스를 $-162^{\circ}C$에서 액화시킨 LNG상태로 생산, 수송, 저장하는 경우보다 고체상태인 NGH(Natural Gas Hydrate)로 만들어서 생산, 수송, 저장할 경우 천연가스의 생산, 수송, 저장, 재가스화 등의 일련의 공정과 비교해볼 때 LNG방법보다 약 24%이상의 경비를 절감을 할 수 있다고 보고되어지고 있다. 따라서, 천연가스의 수송 및 저장기술에서의 탁월한 경제성으로 인해 선진국에서는 가스하이드레이트에 대한 활발한 연구가 진행되고 있다. 특히 일본은 5Ton/Day용량의 NGH 생산플랜트를 건설하여 시운전 중에 있다. NGH기술의 주요 활용분야는 대용량의 가스매장량을 요구하여 LNG공정기술을 적용할 수 없는 중소형가스전 또는 한계가스전에 경제적으로 적용하는 해양수송분야와 천연가스 공급망이 갖춰져 있지 못한 지역에 NGH Pellet형태로 수송/재기화하여 활용하는 내륙운송이 분야가 있다. 국내에서는 지식경제부 국책과제인 ETI(Energy Technology Innovation)사업을 시작으로 국가경쟁력 제고 차원에서 이러한 기술의 기반구촉 및 실증화 사업이 진행되고 있다. 주요 내용으로는 NGH Process Flow, Overall NGH Process concept diagram, NGH Carrier outline, NGH Land Transportation chain 등이 포함되어 있다.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.20 no.3
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• pp.257-262
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• 2011

A low capacity generator converted to high capacity of 40m3 is designed and developed in order to use the hydroxy gas in the steel manufacturing process. For efficient design, it is increased from 8 electrode tubes to 10 electrode tubes as well as expanding the diameter of cell integument up to two times bigger, which can increase the amount of hydrogen occurrence per a cell significantly. In addition, circulating pump and pipe, heat exchanger of affiliated SUS material have been used in the circulation of electrolysis catalyst, and circulating cooling section and piping design are also developed. The flame trap is designed into all-in-one suitable check valve in the flow rate of 28-35m3/h and its application is possibly applied in work operation. It is found that the efficiency of generator developed is enhanced substantially up to 84%. It is expected that the application in this field can be expanded significantly by this study.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.25-32
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• 2019

In many mass-consumption gas facilities, natural gas is not supplied through the pipeline of the gas corporation. LNG is supplied from the gas corporation through the tank lorry to be vaporized. In order to prevent human or property damage due to gas leakage at these facilities, a study was conducted to analyze the concentration of odorant injected at the initial and consumption points. An analysis was performed to confirm the change in odorant concentration according to the pipe position in the gas facility when a constant flow rate flowed. For this study the gas samples were taken with aluminium cylinders(4.5 L) which were created a vacuum at the pressure regulator in which the odorants was injected and the points using the gas. Odorant levels of the samples were analyzed by Gas chromatography(Main Body : Agilent 7890A, Detector : ANTEC 7090).We suggest that the small facilities using LNG need to make the management system by the types of facilities for maintaining the odorization system.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.5
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• pp.589-601
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• 2014

Natural gas hydrate (NGH) is emerging as a new eco-friendly source of energy to replace fossil fuels in the 21st century. It is well known that the Natural Gas Hydrate contains large amount of natural gas about 170 times as much as its volume and it is easy to be stored and transported safely at about $-20^{\circ}C$ under atmospheric pressure due to so called "self-preservation effect". The option of gas transport by gas hydrate pellets carrier has been investigated and developed in various industry and academy. The natural gas hydrate pellet carrier is on major link in a potential gas hydrate process chain, starting with the extraction of natural gas from the reservoir, followed by the production of hydrate pellets and the transportation to an onshore terminal for further processing or marketing. In recent years, Korean project team supported by Korean Government has been working on the development of NGH total systems including novel NGH carrier since 2011. In order to increase the knowledge on the NGH pellet carrier developed and to understand the major hazards that could have significant impact on the safety of the vessel, this paper presents and evaluates the pros and cons of cargo holds, loading and unloading systems through the analysis of current patent technology. Based on the proven and well-known technologies as well as potential measures to mitigate sintering and minimize mechanical stress on the hydrate pellet in the self-preservation state, this study presents the conceptual and basic design for NGH carrier.

• Journal of the Korean Institute of Gas
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• v.22 no.6
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• pp.109-122
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• 2018

Domestic LPG meters are being tested for LPG quantification in accordance with the "Measures Act". The LPG meter is re-tested every three years in accordance with the "Enforcement Decree of the Measures Act". The maximum permissible error within the test is within ${\pm}1.0%$, and the tolerance is within ${\pm}1.5%$. For the quantitative measurement of LPG, a hydrometer for LPG, a balance, and a pressure vessel are used. The volume of LPG varies in depending on the temperature and pressure. The current quantitative measurement method of LPG requires the measurement of temperature, pressure and density in order to determine the volume of LPG, respectively, and some equipments are needed accordingly. Coriolis mass flowmeter, on the other hand, measure the mass flow, density and temperature at the same time, and can be converted and calculated to the required values using a computer program, also it is widely applied in the industrial field. In this study, the volume of LPG was measured using a Coriolis mass flowmeter as a basic study of LPG quantitative measurement. In addition, it is shown that it is possible to apply for the LPG quantitative measurement using the Coriolis mass flowmeter by comparing it with the conventional LPG quantitative measurement method.