• Title/Summary/Keyword: Liquid structure

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Isolation and Analysis of Micro-Regions Having Possibly Higher Tc in Oxide Superconductors (산화물계 초전도체의 고변이 송도부근의 곡출과 이의 성분 분석에 관한 연구)

  • 이규용
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.25 no.3
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    • pp.143-153
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    • 1989
  • In conclusion, a high-Tc superconducting YBa sub(2) Cu sub(3) O sub(y) phase with zero resistance at about 90K was successfully prepared by nitrate solution method with densed micro structure. The result of the EDAX analysis on the isolated particles using the microscopic meissner effect showed that the particles were isolated at higher temperature due to the differences in O vacances rather than the differences in chemical compositions. The composition of the isolated particles were almost identical to the starting compositions on the samples prepared by the solid reaction and nitrate solution method but the Ba-rich composition were seen in the coprecipitated sample. The isolation process on Bi system was not successful due to the weak dimagnetism even though its high Tc above the liquid nitrogen temperature.

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Improved Breakdown Voltage Characteristics of $In_{0.5}Ga_{0.5}P/In_{0.22}Ga_{0.78}As/GaAs$ p-HEMT with an Oxidized GaAs Gate

  • I-H. Kang;Lee, J-W.;S-J. Kang;S-J. Jo;S-K. In;H-J. Song;Kim, J-H.;J-I. Song
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.3 no.2
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    • pp.63-68
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    • 2003
  • The DC and RF characteristics of $In_{0.5}Ga_{0.5}P/In_{0.22}Ga_{0.78}As/GaAs$ p-HEMTs with a gate oxide layer of various thicknesses ($50{\;}{\AA},{\;}300{\;}{\AA}$) were investigated and compared with those of a Schottky-gate p-HEMT without the gate oxide layer. A prominent improvement in the breakdown voltage characteristics were observed for a p-HEMT having a gate oxide layer, which was implemented by using a liquid phase oxidation technique. The on-state breakdown voltage of the p-HEMT having the oxide layer of $50{\;}{\AA}$was ~2.3 times greater than that of a Schottky-gate p-HEMT. However, the p-HEMT having the gate oxide layer of $300{\;}{\AA}$ suffered from a poor gate-control capability due to the drain induced barrier lowering (DIBL) resulting from the thick gate oxide inspite of the lower gate leakage current and the higher on-state breakdown voltage. The results for a primitive p-HEMT having the gate oxide layer without any optimization of the structure and the process indicate the potential of p-HEMT having the gate oxide layer for high-power applications.

Thermal and structural analysis of a cryogenic conduction cooling system for a HTS NMR magnet

  • In, Sehwan;Hong, Yong-Ju;Yeom, Hankil;Ko, Junseok;Kim, Hyobong;Park, Seong-Je
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.59-63
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    • 2016
  • The superconducting NMR magnets have used cryogen such as liquid helium for their cooling. The conduction cooling method using cryocoolers, however, makes the cryogenic cooling system for NMR magnets more compact and user-friendly than the cryogen cooling method. This paper describes the thermal and structural analysis of a cryogenic conduction cooling system for a 400 MHz HTS NMR magnet, focusing on the magnet assembly. The highly thermo-conductive cooling plates between HTS double pancake coils are used to transfer the heat generated in coils, namely Joule heating at lap splice joints, to thermal link blocks and finally the cryocooler. The conduction cooling structure of the HTS magnet assembly preliminarily designed is verified by thermal and structural analysis. The orthotropic thermal properties of the HTS coil, thermal contact resistance and radiation heat load are considered in the thermal analysis. The thermal analysis confirms the uniform temperature distribution for the present thermal design of the NMR magnet within 0.2 K. The mechanical stress and the displacement by the electromagnetic force and the thermal contraction are checked to verify structural stability. The structural analysis indicates that the mechanical stress on each component of the magnet is less than its material yield strength and the displacement is acceptable in comparison with the magnet dimension.

Meridional Circulations in a Sliced Cylinder (기울어진 회전 원판에 의한 원통형 용기내의 자오면 유동의 크기에 관한 연구)

  • KIM Jae Won;LIM Hong Sick
    • 한국전산유체공학회:학술대회논문집
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    • 1996.05a
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    • pp.52-57
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    • 1996
  • Mixing is most important for developing an electric washer which transforms angular momentum from rotating solid wall to laundry clothes inside it. For magnification of this mixing effect, some inventions are introduced to washing machine system, i. e., washing plate, washing rod, and even for washing cap in a model of a Korean manufacture. However, the previous efforts show dissatisfaction up till now. In this paper, a triumph to enhance mixing effects to increase washing performance is presented and verified by numerical investigation. The present model to simulate a washing tub is the simple circular cylinder with two endwall disks which is completely filled with a viscous liquid. The present improvement is to change mounting position of a bottom disk of the model cylinder. Therefore, the aim of this work just proposes a new idea, which is numerically inspected, to a producer of washing machine, In detail, this invention is alternating the mounting position of a rotating bottom disk. Actually skewed pulsator is placed in steady of a flat disk, so the two endwall disks at top and bottom are not in parallel. The angle between an inclined bottom disk and the horizontal plane is fixed as 5 degree and physical domain to consider poses a sliced cylinder. Flow fields in both a right circular cylinder and the present improved model are fully depicted by numerical integration on a body fitted nonorthogonal regular uniform grid system. Numerical data to explain flow structure are plotted for understanding of the effects of the inclined disk. Also enhanced mixing effects by the inclined rotating disk are gauged by accurate numerical data used in this work.

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Purification of Oxytocin-related Peptide, Isotocin from the Brain of Conger Eel Conger myriaster (붕장어(Conger myriaster)의 뇌로부터 Oxytocin-related Peptide, Isotocin의 정제)

  • GO Hye-Jin;KIM Chan-Hee;KIM Eun Jung;KIM In Hae;AN Sang Hyun;SOHN Hee-Young;PARK Jin-IL;PARK HEE Yun;YOON Ho Dong;PARK Nam Gyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.38 no.5
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    • pp.286-290
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    • 2005
  • Oxytocin (OT)-related peptide, isotocin was purified from the brain extract of conger eel (Conger myriaster) using reverse-phase, ion-exchange and size exclusion high performance liquid chromatography (HPLC). The sequence of the peptide, with a molecular weight of 967.30 Da, was determined as Cys-Tyr-Ile-Ser-Asn­Cys-Pro-Ile-Gly-$NH_2$, where the Cys between 1st and 6th residues made an intramolecular disulfide bridge by the automated amino acid sequence analysis and MALDI-TOF mass spectrometry. The sequence was confirmed by identical elution with the purified and synthetic peptide using the HPLC system. As a result of homology investigation, the primary structure of this peptide was the same as that of OT -superfamily member, isotocin. The synthetic peptide showed a contractile activity at a minimal effective concentration of $10^{-7}M$ on the intestinal smooth muscle of goldfish (Carassius auratus).

The Changes of Capsaicin Contents in Fresh and Processed Red Peppers (생고추와 고추 가공시의 Capsaicin 함량 변화)

  • Chung, Byung-Sun;Kang, Kun-Og
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.4
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    • pp.409-418
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    • 1985
  • The contents of capicin according to the growth of fresh red peppers (Capsicum annum) and to-brewing of 'kochujang' (fermented hot peper-soybean paste) and 'kimchi' (a group of Korean seasoned pickles) were quantified by High Pressure Liquid Chromatography. Colors of the peppers were evaluated by Hunter Value and quantity of capsanthin. The content and chemical structure of capsaicin after heat treatment were traced by HPLC, GCMS, UV and NMR. It was found that the capsaicin content of red peper was highest 6 to 7 weeks after flowering and that peppers with high Hunter Value contained higher level of capsanthin. The content of capsaicin of kochujang and kimchi declined by 20% and 17% respectively, as they are brewed. Capsaicin content was decreased by heating. However, change in its chemical strtcure was not occurred.

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Genetic and biochemical evidence for redundant pathways leading to mycosporine-like amino acid biosynthesis in the cyanobacterium Sphaerospermopsis torques-reginae ITEP-024

  • Geraldes, Vanessa;de Medeiros, Livia Soman;Lima, Stella T.;Alvarenga, Danillo Oliveira;Gacesa, Ranko;Long, Paul F.;Fiore, Marli Fatima;Pinto, Ernani
    • ALGAE
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    • v.35 no.2
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    • pp.177-187
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    • 2020
  • Cyanobacteria have been widely reported to produce a variety of UV-absorbing mycosporine-like amino acids (MAAs). Herein, we reported production of the unusual MAA, mycosporine-glycine-alanine (MGA) in the cyanobacterium Sphaerospermopsis torques-reginae ITEP-024 using a newly developed UHPLC-DAD-MS/HRMS (ultra-high performance liquid chromatography-diode array detection-high resolution tandem mass spectrometry) method. MGA had previously been first identified in a red-algae, but S. torques-reginae strain ITEP-024 is the first cyanobacteria to be reported as an MGA producer. Herein, the chemical structure of MGA is fully elucidated from one-dimensional / two-dimensional nuclear magnetic resonance and HRMS data analyses. MAAs are unusually produced constitutively in S. torques-reginae ITEP-024, and this production was further enhanced following UV-irradiance. It has been proposed that MAA biosynthesis proceeds in cyanobacteria from the pentose phosphate pathway intermediate sedoheptulose 7-phosphate. Annotation of a gene cluster encoded in the genome sequence of S. torques-reginae ITEP-024 supports these gene products could catalyse the biosynthesis of MAAs. However, addition of glyphosate to cultures of S. torques-reginae ITEP-024 abolished constitutive and ultra-violet radiation induced production of MGA, shinorine and porphyra-334. This finding supports involvement of the shikimic acid pathway in the biosynthesis of MAAs by this species.

Study on Validity of 1-D Spherical Model on Aqua-plasma Power Estimation With Electrode Structure

  • Yun, Seong-Yeong;Jang, Yun-Chang;Kim, Gon-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.74-74
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    • 2010
  • The aqua-plasma is the non-thermal plasma in electrical conductive electrolyte by generates the vapor film layer on the immersed metal electrode surface. This plasma can generate the hydroxyl radical by dissociate the water molecule with the plasma electron. To develop the plasma discharge device for high efficiency in the hydroxyl radical generation, proper model for estimation of plasma power is necessary. In this work, the 1-D spherical model was developed, considering temperature dependence material constants. The relation between the plasma power and hydroxyl generation was also studied by the comparison between the optical emission intensity from the hydroxyl radical using monochromator and estimated plasma power. First, the thickness of vapor layer thickness was estimated using the Navier-Stokes fluid equation in order to calculate the discharge E-field inside vapor layer. Using the E-field magnitude and power balance on the plasma generation, it was possible to estimate the plasma power. The plasma power was assumed to uniformly fill the vapor layer and the temperature of vapor layer was fixed in the boiling temperature of electrolyte, 375K. In the experiment, the aqua-plasma was discharged in the saline by applied the voltage on the bipolar electrode. The range of applied voltage was 234 to 280V-rms in the frequency of 380 kHz. Two type electrodes were produced with two ${\Phi}0.2$ tungsten. The plasma power was estimated from the V-I signal from the two high voltage probes and current probe. The estimated plasma power agreed with the profile of emission intensity when the plasma discharged between the metal electrode and vapor layer surface. However, when the plasma discharged between the metal electrodes, the increasing rate of emission intensity was lower than the increase of plasma power. It implies that the surface reaction is more sufficient rather than the volume reaction in the radical generation, due to the high density of water molecule in the liquid.

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Comparison of Pervaporation and Vapor Permeation Separation Processes for MTBE-methanol System

  • Kim, Youn-Kook;Lee, Keun-Bok;Rhim, Ji-Won
    • Korean Membrane Journal
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    • v.2 no.1
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    • pp.36-47
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    • 2000
  • This paper deals with the separation of MTBE-methanol mixtures using crosslinked Poly(vinyl alcohol)(PVA) membranes with sulfur-succinic acid(SSA) as a crosslinking agent by pervaporation and vapor permeation technique. The operating temperatures, methanol concentration in feed mixtures, and SSA concentrations in PVA membranes were varied to investigate the separation performance of PVA/SSA membranes and the optimum separation characteristics by pervaporation and vapor permeation. And also, for PVA/SSA membranes, the swelling measurements were carried out to study the transport phenomena. The swelling measurements were carried out for pure MTBE and methanol, and MTBE/methanol=90/10, 80/20 mixtures using PVA/SSA membranes with varying SSA compositions. There are two factors of the membrane network and the hydrogen bonding. In pervaporation separation was also carried out for MTBE/methanol=90/10, 80/20 mixtures at various temperatures. The sulfuric acid group in SSA took an important role in the membrane performance. The crosslinking effect might be over the hydrogen bonding effect due to the sulfuric acid group at 3 and 5% SSA membranes, and this two factors act vice versa on 7% SSA membrane. In this case, the 5% SSA membrane shows the highest separation factor of 2,095 with the flux of 12.79g/㎡$.$hr for MTBE/methanol=80/20 mixtures at 30$^{\circ}C$ which this mixtures show near the azeotopic composition. Compared to pervaporation, vapor permeation showed less flux and similar separation factor. In this case, the flux decreased significantly because of compact structure and the effect of hydrogen bonding. In vapor permeation, density or concentration of methanol in vaporous feed is lower than that of methanol in liquid feed, as a result, the hydrogen bonding portion between the solvent and the hydroxyl group in PVA is reduced in vapor permeation. In this case, the 7% SSA membranes shows the highest separation factor of 2,187 with the flux of 4.84g/㎡$.$hr for MTBE/methanol=80/20 mixtures at 30$^{\circ}C$.

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Development of a Quantitative Induction Method for Chondromyces crocatus Fruiting Body Formation (Chondromyces crocatus 자실체 형성의 정량적 유도 방법 개발)

  • Lee, Chayul;Shin, Hyejin;Cho, Kungyun
    • Korean Journal of Microbiology
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    • v.50 no.3
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    • pp.173-178
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    • 2014
  • We have developed a method for the preparation of dispersed cell suspensions of Chondromyces crocatus, which is essential for quantitative studies of fruiting body formation. Cells of C. crocatus have a tendency to aggregate in liquid, hindering quantitative studies. However, cells grown on casitone-yeast extract agar plates, containing 3% agar, allowed the preparation of well-dispersed cell suspensions. Cell suspensions at a concentration of $2{\times}10^8cells/ml$, obtained by using this method, developed typical C. crocatus fruiting bodies when placed as $20{\mu}l$ spots on agar plates with no nutrient supplementation. The addition of nutrients such as casitone altered or inhibited fruiting body formation. Fruiting body branch formation increased with increasing agar content. Under optimum conditions, the formation of fruiting body structure in C. crocatus KYC2823 was completed within 24 h.