• Title/Summary/Keyword: Liquid structure

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Effects of Physicochemical and Environmental Factors on Spatial and Temporal Variations in Phytoplankton Pigment and its Community Composition in Jinhae Bay (진해만에서 물리화학적 환경요인이 식물플랑크톤 색소 및 군집조성의 시공간적 변화에 미치는 영향)

  • Na, Sujin;Lee, Jiyoung;Kim, Jeong Bae;Koo, Jun-Ho;Lee, Garam;Hwang, Hyunjin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.2
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    • pp.340-354
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    • 2021
  • The aim of this study was to investigate the spatial and temporal distribution of phytoplankton biomass and community composition in Jinhae Bay on the southern coast of Korea. Phytoplankton pigment analysis was conducted using ultra performance liquid chromatography (UPLC) were conducted from April to December 2019 at seven stations. Temperature, salinity, and dissolved oxygen (DO) and inorganic nutrients (dissolved nitrogen, dissolved phosphorus, and orthosilicic acid) were measured to investigate the environmental factors associated with the structure of phytoplankton community. Phytoplankton biomass (Chl-a) was the highest in July (mean 15.4±4.3 ㎍/L) and the lowest in December (mean 3.5±0.6 ㎍/L). Fucoxanthin was the most abundant carotenoid and showed a similar variation pattern to Chl-a, peridinin, and Chl-b. Phytoplankton community composition analysis showed that diatoms were a predominant group with an average abundance of 70 % whereas chlorophytes, cryptophytes, and dinoflagellates often appeared with lower averages. Further, the dominance of diatoms was closely correlated with water temperature and N:P ratio, which might be influenced by high temperatures in the summer and nutrient loading from the land. Additionally, freshwater and nutrient input by rainfall was estimated to be the most important environmental factor. Hence, the spatial and temporal variations in the composition of phytoplankton pigments and phytoplankton community were correlated with physicochemical and environmental parameters.

17O Solid-State NMR Study of the Effect of Organic Ligands on Atomic Structure of Amorphous Silica Gel: Implications for Surface Structure of Silica and Its Dehydration Processes in Earth's Crust (유기 리간드와 비정질 실리카겔의 상호 작용에 대한 17O 고상핵자기공명 분광분석 연구: 실리카 표면 구조 및 지각의 탈수반응에 대한 의의)

  • Kim, Hyun Na;Lee, Sung Keun
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.271-282
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    • 2012
  • We explore the effect of removal of organic ligand on the atomic configurations around oxygen in hydroxyl groups in amorphous silica gel (synthesized through hydrolysis of $SiCl_4$ in diethyl-ether) using high resolution $^{17}O$ solid state NMR spectroscopy. $^1H$ and $^{29}Si$ MAS NMR spectra for amorphous silica gel showed diverse hydrogen environments including water, hydroxyl groups (e.g., hydrogen bonded silanol, isolated silanol), and organic ligands (e.g., alkyl chain) that may interact with surface hydroxyls in the amorphous silica gel, for instance, forming silica-organic ligand complex (e.g., Si-$O{\cdots}R$). These physically and chemically adsorbed organic ligands were partly removed by ultrasonic cleaning under ethanol and distilled water for 1 hour. Whereas $^{17}O$ MAS NMR spectra with short pulse length ($0.175{\mu}s$) at 9.4 T and 14.1 T for as-synthesized amorphous silica gel showed the unresolved peak for Si-O-Si and Si-OH structures, the $^{17}O$ MAS NMR spectra with long pulse length ($2{\mu}s$) showed the additional peak at ~0 ppm. The peak at ~0 ppm may be due to Si-OH structure with very fast relaxation rate as coupled to liquid water molecules or organic ligands on the surface of amorphous silica gel. The observation of the peak at ~0 ppm in $^{17}O$ MAS NMR spectra for amorphous silica gel became more significant as the organic ligands were removed. These results indicate that the organic ligands on the surface of amorphous silica gel interact with oxygen atoms in Si-OH and provide the information about atomic structure of silanol and siloxane in amorphous silica gel. The current results could enhance the understanding of dehydration mechanism of diverse silicates, which is known as atomic scale origins of intermediate depth (approximately, 70~300 km) earthquakes in subduction zone.

Implementation of Capacitor and Inductor Applied LCP Substrate for 35-GHz frequency band (35 GHz 대역을 위한 LCP 기판 적용된 커패시터 및 인덕터 구현)

  • Lee, Jiyeon;Ryu, Jongin;Choi, Sehwan;Lee, Jaeyoung
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.67-75
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    • 2020
  • In this paper, by applying LCP substrate, the capacitor and inductor are implemented with a variety of value that can be used in 35 GHz circuits. Depending on how to apply it to the circuit, it is required high value by designing the basic structures such as electrode capacitor and spiral inductor. However they are not available in high-frequency domain, because their SRF(Self-Resonant Frequency) is lower than the frequency of 35-GHz. By finding the limit, this paper devised classifying passive devices for the DC and the high-frequency domain. The basic structure is suitable for DC and microstrip λ/8 length stub structure can be used for high-frequency. The open and short stub structure operate as a capacitor and inductor respectively in the frequency of 35 GHz. If their impedance is known, it is possible to extract the value through the impedance-related equation. By producing with the permittivity 2.9 LCP substrate, the basic structure which are available in the DC constituted a library of capacitance of 1.12 to 13.9 pF and inductance of 0.96 to 4.69 nH, measured respectively. The stub structure available in the high-frequency domain were built libraries of capacitance of 0.07 to 2.88 pF and inductance of 0.34 to 1.27 nH, calculated respectively. The measurements have proven how to diversify value, so libraries can be built more variously. It is possible to integrate with the operation circuit of TRM(Transmit-Receive Module) for the frequency 35-GHz, it will be an alternative to the passive devices that can be properly utilized in the circuit.

Permeability Aftereffect in FeCuNbSiB Alloy (FeCuNbSiB 합금의 투자율 여효)

  • Lee, Yong-Ho;Sin, Yong-Dol;No, Tae-Hwan;Gang, Il-Gu
    • Journal of the Korean Magnetics Society
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    • v.2 no.3
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    • pp.216-221
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    • 1992
  • Annealing effects on the permeability aftereffect(disaccommodation) of liquid quenched single strip $Fe_{73.5}Cu_1Nb_3Si_{16}B_{6.5}$ alloys were investigated with pulse method. The initial susceptibility X, $B_{10},$ (the flux density at 10 Oe) and disaccommodation intensity D (D = [X(1 s)-X(64 s)]/X(1 s), where X(1 s) and X(64 s) are the susceptibility of 1 and 64 s of rest time after A. C. demagnetization) were about 800, 0.8 T and 16 %, respectively. The soft magnetic properties were improved with isothermal annealing for 1 hour at $300{\sim}600^{\circ}C.$ X, $B_{10},$ and D at $570^{\circ}C$ of optimum annealing temperature were 15000, 1.2 T and 1.1 %, respectively. The origin of the change of characteristics were examined with fine crystalline structure and magnetostriction.

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Composition of Phytoplankton in Gamak Bay by CHEMTAX Analyses (CHEMTAX 활용한 가막만 식물플랑크톤 군집조성)

  • Oh, Hyun-Taik;Kim, Da-Jung;Lee, Won-Chan;Jung, Rae-Hong;Hong, Suk-Jin;Kang, Yang-Sun;Lee, Yang-Woo;Tilburg, Charles
    • Journal of Environmental Science International
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    • v.17 no.10
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    • pp.1155-1167
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    • 2008
  • Chlorophyll a (chl a) has been used as an indicator for phytoplankton biomass in pelagic ecosystems due to the relative ease of measurement and selectivity for autotrophs in mixed plankton assemblages. However, the use of chi a as an indicator for phytoplankton biomass is restricted due to its inability to resolve taxonomic differences of phytoplankton and the highly variable relationship of chi a with phytoplankton. Here, we describe the analysis of High-Performance Liquid Chromatography (HPLC) photosynthetic pigment data using CHEMTAX, which is a matrix factorization program that uses chemical taxonomic indices (phytoplankton carotenoids) to quantify the abundance of phytoplankton groups. Compared to direct microscopic counting that can distinguish species within broad groups, the resolution of taxonomic groups by CHEMTAX is generally coarse. It can only distinguish between diatoms, dinoflagellates, cryptophytes, cyanobacteria, chlorophytes, prasinophytes, and haptophytes. However, CHEMTAX analysis is much faster and less expensive than microscopic counting methods. HPLC pigment observations were taken in the spring, summer, fall, and winter in$ 2005\sim2006$ within Gamak Bay, South Korea. CHEMTAX results revealed that diatoms were the dominant taxonomic group in Gamak Bay. In inner Gamak Bay, the ratio between diatoms and cryptophytes was $75\sim80%$, and the ratio between dinoflagellates and cryptophytes was $10\sim15%$. In outer Gamak Bay, the ratio between diatoms and cryptophytes was $85\sim90%$, and the ratio between dinflagellates and cryptophytes was only $1\sim5%$. The population structure was seasonal. Relative diatom populations were less in the summer than the winter season.

Study about the In-situ Synthesis and Structure Control of Multi-walled Carbon Nanotubes and their Nanocomposites (다중벽 탄소나노튜브와 다양한 나노입자 복합체의 In-situ 합성법개발 및 구조제어연구)

  • Park, Ho Seok
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.729-732
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    • 2012
  • Herein we report the in-situ synthesis and direct decoration of chalcogenide naoparticles (NPs) onto multiwalled carbon nanotubes (MWCNTs) through an ionic liquid-assisted sonochemical method (ILASM). The as-obtained MWCNT/$BMimBF_4$/CdTe, MWCNT/$BMimBF_4$/ZnTe and MWCNT/$BMimBF_4$/ZnSe nanocomposites were characterized by TEM images and EDS spectra. In particular, the morphologies of nanocomposites such as bump-like, rough, and smooth core-shell structures were strongly influenced by the type of precursors and the interactions with MWCNT. This synthetic strategy opens a new way to directly synthesize and deposit semiconducting NPs (s-NPs) onto CNTs, which consist of binary components obtained from two precursors with different reaction rates.

Method for Measurement of Complex Relative Permittivity of Semi-Solid Materials Using Novel Cavity Resonator Design (캐비티 공진기를 이용한 반고체 상태 물질의 복소 비유전율 측정 방법)

  • Park, Rae-Seoung;Jang, Jihyun;Park, Byungdeok;Kim, Junhwan;Park, Sangbok;Chung, Young-Seek;Cheon, Changyul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.25 no.8
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    • pp.872-878
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    • 2014
  • This paper proposes a measurement method of the complex relative permittivity of semi-solid materials using a new cavity structure. Semi-solid materials are positioned in the proposed cavity where an aperture exists on each corner of the upper part and a ground plane is separated. In order to show the validation of the proposed method, we measured the complex relative permittivity of distilled water and 0.9 % saline by sensing a shift of resonant frequency and using Critical-Points Method, and compared the results with those derived from the Cole-Cole equation.

An Efficiency Improvement of the OLEDs due to the Thickness Variation on Hole-Injection Materials (정공주입물질 두께 변화에 따른 유기발광다이오드의 효율 개선)

  • Shin, Jong-Yeol;Guo, Yi-Wei;Kim, Tae-Wan;Hong, Jin-Woong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.5
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    • pp.344-349
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    • 2015
  • A new information society of late has arrived by the rapid development of various information & communications technologies. Accordingly, mobile devices which are light and thin, easy and convenient to carry on the market. Also, the requirements for the larger television sets such as fast response speed, low-cost electric power, wider visual angle display are sufficiently satisfied. The currently most widely studied display material, the Organic Light-emitting Diodes(OLEDs) overwhelms the Liquid Crystal Display(LCD), the main occupier of the market. This new material features a response speed of more than a thousand times faster, no need of backlight, a low driving voltage, and no limit of view angle. And the OLEDs has high luminance efficiency and excellent durability and environment resistance, quite different from the inorganic LED light source. The OLEDs with simple device structure and easy produce can be manufactured in various shapes such as a point light source, a linear light source, a surface light source. This will surely dominate the market for the next generation lighting and display device. The new display utilizes not the glass substrate but the plastic one, resulting in the thin and flexible substrate that can be curved and flattened out as needed. In this paper, OLEDs device was produced by changing thickness of Teflon-AF of hole injection material layer. And as for the electrical properties, the four layer device of ITO/TPD/$Alq_3$/BCP/LiF/Al and the five layer device of ITO/Teflon AF/TPD/$Alq_3$/BCP/Lif/Al were studied experimentally.

The evaluation of performance and flow characteristics due to the length of throat and diffuser for ship's ejector (선박용 Ejector의 직관부와 디퓨저 길이 변화에 따른 성능비교 및 유동특성에 관한 연구)

  • Lee, Young-Ho;Kim, Mun-Oh;Kim, Chang-Goo;Kim, You-Taek
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.1
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    • pp.31-38
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    • 2014
  • Ejector is a simple device which can transport a low-pressure secondary flow by using a high-pressure primary flow. The efficiency of the ejector system is relatively very low, compared to other fluid transport devices driven mainly by the forces acting on the normal direction. However, its major advantage is a simple structure with no moving parts, and it transports a large amount of fluid with a small driving energy. In this study, the performance of side-type liquid ejector commonly used in ships; is analyzed by using experimental and CFD methods under steady and incompressible flow condition by varying the length of the throat and diffuser, the flow pattern and suction phenomenon were studied in detail.

Structure Analysis and Design Optimization of Stiffeners in LNG Tanks (LNG 저장탱크 보강재의 구조해석 및 최적설계)

  • Jin, Cheng-Zhu;Jin, Kyo-Kook;Ha, Sung-Kyu;Seo, Heung-Seok;Yoon, Ihn-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.3
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    • pp.325-330
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    • 2012
  • This paper describes the structural analysis and optimization of stiffeners used in inner tanks for liquid natural gas (LNG) storage, so that the costs can be minimized while the critical buckling load of the inner tank still exceeds the external pressure exerted by the perlite. The original calculation of perlite pressure applied to the inner tank was based on Zick's code, which led to the overestimation of the external pressure, and consequently, an oversized stiffener. In this study, the effects of the material properties of perlite on the external pressure distribution are scrutinized, and the optimum dimensions of a single stiffener are finally obtained through a series of parametric studies. A 15% decrease in the cost of the stiffener compared with the original design is achieved.